具有均匀壳层的纳米功能材料：构筑与应用

doi:10.13208/j.electrochem.151247

电化学（中英文） ›› 2016, Vol. 22 ›› Issue (3): 260-270. doi: 10.13208/j.electrochem.151247

• 电化学获奖人优秀论文专辑 • 上一篇下一篇

具有均匀壳层的纳米功能材料：构筑与应用

段舒怡^1,2，张伟^1,2，朴俊宇^1,2，曹安民¹*，万立骏¹*

1. 北京分子科学国家实验室，中国科学院分子纳米结构与纳米技术重点实验室，中国科学院化学研究所，北京 100190； 2. 中国科学院大学，北京 100049

收稿日期:2016-02-01 修回日期:2016-02-28 出版日期:2016-06-28 发布日期:2016-03-07
通讯作者: 曹安民，万立骏 E-mail:anmin_cao@iccas.ac.cn; wanlijun@iccas.ac.cn
基金资助:
This work was supported by the major State Basic Research Program of China (973 program: 2013CB934000), the National Natural Science Foundation of China (Grant No. 21373238)

Uniform Nanoshells for Functional Materials：Constructions and Applications

DUAN Shu-y^1,2i, ZHANG Wei^1,2, PIAO Jun-yu^1,2, CAO An-min¹*, WAN Li-jun¹*

1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Science (CAS), Beijing 100190, P. R. China; 2. University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received:2016-02-01 Revised:2016-02-28 Published:2016-06-28 Online:2016-03-07
Contact: CAO An-min, WAN Li-jun E-mail:anmin_cao@iccas.ac.cn; wanlijun@iccas.ac.cn
Supported by:
This work was supported by the major State Basic Research Program of China (973 program: 2013CB934000), the National Natural Science Foundation of China (Grant No. 21373238)

摘要/Abstract

摘要：

表面修饰是一种重要的材料处理手段，被广泛应用于催化、光化学、电化学等领域。本文阐述了通过表面均匀包覆构建具有特定功能核壳结构的意义，并分析了构筑均匀包覆层的典型合成方法。同时，针对锂离子电池电极材料这一特定应用对象，综述了进行电极材料表面均匀包覆处理的途径，强调了电极材料核壳结构的构筑对于电极材料表面稳定、电化学性能优化等意义。

关键词: 表面控制, 电极材料, 核-壳结构, 异相成核生长, 锂离子电池

Abstract:

As a significant protocol for materials treatment, surface modification has found broad applications in different fields including catalyst, photochemistry, and electrochemistry. Herein, we introduced the representative synthetic methodologies for the constructions of different functional materials with a focus on their core-shell structures. By taking the electrode materials in lithium ion batteries as an example, we demonstrated the importance of surface modification on the electrode materials. Different coating materials ranging from metal oxides, metal phosphates to carbon have been discussed. We also showed that an accurate control on the surface layer can be crucial for optimizing the electrochemical performances of the core-shell structured materials.

Key words: surface modification, electrode materials, core-shell structure, heterogeneous growth, lithium ion batteries

中图分类号:

TM911.14

段舒怡，张伟，朴俊宇，曹安民，万立骏. 具有均匀壳层的纳米功能材料：构筑与应用[J]. 电化学（中英文）, 2016, 22(3): 260-270.

DUAN Shu-yi, ZHANG Wei, PIAO Jun-yu, CAO An-min, WAN Li-jun. Uniform Nanoshells for Functional Materials：Constructions and Applications[J]. Journal of Electrochemistry, 2016, 22(3): 260-270.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.151247

https://electrochem.xmu.edu.cn/CN/Y2016/V22/I3/260

参考文献

[1] Dabbousi B O, RodriguezViejo J, Mikulec F V, et al. (CdSe)ZnS core-shell quantum dots: Synthesis and characterization of a size series of highly luminescent nanocrystallites[J]. Journal of Physical Chemistry B, 1997, 101(46): 9463-9475.

[2] Deheer W A. The physics of simple metal-clusters – experimental aspects and simple models[J]. Reviews of Modern Physics, 1993, 65(3): 611-676.

[3] Peng X G, Schlamp M C, Kadavanich A V, et al. Epitaxial growth of highly luminescent CdSe/CdS core/shell nanocrystals with photostability and electronic accessibility[J]. Journal of the American Chemical Society, 1997, 119(30): 7019-7029.

[4] Lauhon L J, Gudiksen M S, Wang C L, et al. Epitaxial core-shell and core-multishell nanowire heterostructures[J]. Nature, 2002, 420(6911): 57-61.

[5] Sun X M, Li Y D. Colloidal carbon spheres and their core/shell structures with noble-metal nanoparticles [J]. Angewandte Chemie-International Edition, 2004, 43(5): 597-601.

[6] Zhang Q F, Dandeneau C S, Zhou X Y, et al. ZnO nanostructures for dye-sensitized solar cells[J]. Advanced Materials, 2009, 21(41): 4087-4108.

[7] Jiang J, Li Y Y, Liu J P, et al. Recent advances in metal oxide-based electrode architecture design for electrochemical energy storage [J]. Advanced Materials, 2012, 24(38): 5166-5180.

[8] Lou X W, Archer L A, Yang Z C. Hollow micro-/nanostructures: synthesis and applications [J]. Advanced Materials, 2008, 20(21): 3987-4019.

[9] Liu J, Manthiram A. Understanding the improvement in the electrochemical properties of surface modified 5 V LiMn_1.42Ni_0.42Co_0.16O₄ spinel cathodes in lithium-ion cells [J]. Chemistry of Materials, 2009, 21(8): 1695-1707.

[10] Cho J, Kim Y W, Kim B, et al. A breakthrough in the safety of lithium secondary batteries by coating the cathode material with AlPO₄ nanoparticles [J]. Angewandte Chemie-International Edition, 2003, 42(14): 1618-1621.

[11] Cho J. Correlation between AlPO₄ nanoparticle coating thickness on LiCoO₂ cathode and thermal stability [J]. Electrochimica Acta, 2003, 48(19): 2807-2811.

[12] Wang J H, Wang Y, Guo Y Z, et al. Effect of heat-treatment on the surface structure and electrochemical behavior of AlPO₄-coated LiNi_1/3Co_1/3Mn_1/3O₂ cathode materials [J]. Journal of Materials Chemistry A, 2013, 1(15): 4879-4884.

[13] Jung Y S, Lu P, Cavanagh A S, et al. Unexpected improved performance of ALD coated LiCoO₂/graphite li-ion batteries [J]. Advanced Energy Materials, 2013, 3(2): 213-219.

[14] Choi M, Ham G, Jin B S, et al. Ultra-thin Al₂O₃ coating on the acid- treated 0.3Li₂MnO₃·0.7LiMn_0.60Ni_0.25Co_0.15O₂ electrode for Li-ion batteries [J]. Journal of Alloys and Compounds, 2014, 608: 110-117.

[15] Cheng H M, Wang F M, Chu J P, et al. Enhanced cycleabity in lithium ion batteries: resulting from atomic layer deposition of Al₂O₃ or TiO₂ on LiCoO₂ electrodes [J]. Journal of Physical Chemistry C, 2012, 116(14): 7629-7637.

[16] Scott I D, Jung Y S, Cavanagh A S, et al. Ultrathin coatings on nano-LiCoO2 for li-ion vehicular applications [J]. Nano Letters, 2011, 11(2): 414-418.

[17] Gu M, Belharouak I, Zheng J, et al. Formation of the spinel phase in the layered composite cathode used in li-ion batteries [J]. ACS NANO, 2013, 7(1): 760-767.

[18] Hwang B J, Chen C Y, Cheng M Y, et al. Mechanism study of enhanced electrochemical performance of ZrO₂-coated LiCoO₂ in high voltage region [J]. Journal of Power Sources, 2010, 195(13): 4255-4265.

[19] Zhang X F, Belharouak I, Li L, et al. Structural and electrochemical study of Al₂O₃ and TiO₂ coated Li_1.2Ni_0.13Mn_0.54Co_0.13O₂ cathode material using ALD [J]. Advanced Energy Materials, 2013, 3(10): 1299-1307.

[20] Leskelä M, Ritala M. Atomic layer deposition chemistry: recent developments and future challenges [J]. Angewandte Chemie-International Edition, 2003, 42(45): 5548-5554.

[21] Knez M, Nielsch K, Niinistö L. Synthesis and surface engineering of complex nanostructures by atomic layer deposition [J]. Advanced Materials, 2007, 19(21): 3425-3438.

[22] Puurunen R L. Surface chemistry of atomic layer deposition: A case study for the trimethylaluminum/water process [J]. Journal of Applied Physics, 2005, 97(12): 121301-1-121301-52.

[23] Marichy C, Bechelany M, Pinna N. Atomic layer deposition of nanostructured materials for energy and environmental applications [J]. Advanced Materials, 2012, 24(8): 1017-1032.

[24] LaMer V K, Dinegar R H. Theory, production and mechanism of formation of monodispersed hydrosols [J]. Journal of the American Chemical Society, 1950, 72(11): 4847-4854.

[25] Cao A M, Hu J S, Wan L J. Morphology control and shape evolution in 3D hierarchical superstructures [J]. Science China-Chemistry, 2012, 55(11): 2249-2256.

[26] Noguchi T, Yamazaki I, Numataa T, et al. Effect of Bi oxide surface treatment on 5 V spinel LiNi_0.5Mn_1.5−xTi_xO₄[J]. Journal of Power Sources, 2007, 174(2): 359-365.

[27] Cho J, Kim Y J, Park B. Novel LiCoO₂ cathode material with Al₂O₃ coating for a Li ion cell [J]. Chemistry of Materials, 2000, 12(12): 3788-3791.

[28] Zhang W, Chi Z X, Mao W X, et al. One-nanometer-precision control of Al₂O₃ nanoshells through a solution-based Synthesis Route[J]. Angewandte Chemie-International Edition, 2014, 126(47): 12990–12994.

[29] Sun Y K, Hong K J, Prakash J, et al. Electrochemical performance of nano-sized ZnO-coated LiNi_0.5Mn_1.5O₄ spinel as 5 V materials at elevated temperatures[J]. Electrochemistry Communications, 2002, 4(4): 344-348.

[30] Sun Y K, Yoon C S, Oh I H. Surface structural change of ZnO-coated LiNi_0.5Mn_1.5O₄ spinel as 5 V cathode materials at elevated temperatures [J]. Electrochimica Acta, 2003, 48(5): 503-506.

[31] Alcantara R, Jaraba M, Lavela P, et al. X-ray diffraction and electrochemical impedance spectroscopy study of zinc coated LiNi_0.5Mn_1.5O₄ electrodes [J]. Journal of Electroanalytical Chemistry, 2004, 566(1): 187-192.

[32] Mao W X, Zhang W, Chi Z X, et al. Core–shell structured Ce2S3@ZnO and its potential as a pigment [J]. Journal of Materials Chemistry A, 2015, 3(5): 2176-2180.

[33] Stöber W, Fink A, Bohn E J, Controlled growth of monodisperse silica spheres in the micron size range [J]. Journal of Colloid and Interface Science, 1968, 26(1): 62-69.

[34] Zhong A Z, Zou W, Mao W X, et al. A continuous etching process for highly-active Pd nanoclusters and their in situ stabilization [J]. RSC Advances, 2014, 4(45): 23637-23641.

[35] Li C, Zhang H P, Fu L J. Cathode materials modified by surface coating for lithium ion batteries[J]. Electrochimica Acta, 2006, 51(19): 3872-3883.

[36] Kaden W E, Wu T P, Kunkel W A, et al. Electronic structure controls reactivity of size-selected Pd clusters adsorbed on TiO2 surfaces [J]. Science, 2009, 326(5954): 826-829.

[37] Wang Z X, Liu L J, Chen L Q, et al. Structural and electrochemical characterizations of surface-modified LiCoO₂ cathode materials for Li-ion batteries[J]. Solid State Ionics, 2002, 148(3-4): 335-342.

[38] Jung Y S, Cavanagh A S, Riley L A, et al. Ultrathin direct atomic layer deposition on composite electrodes for highly durable and safe li-ion batteries [J]. Advanced Materials, 2010, 22(9): 2172-2176.

[39] Cho J P, Kim T J, Park B W. The effect of a metal-oxide coating on the cycling behavior at 55°C in orthorhombic LiMnO₂ cathode materials [J]. Journal of the Electrochemical Society, 2002, 149(3): A228-A292.

[40] Jung Y S, Cavanagh A S, Dillon A C, et al. Enhanced stability of LiCoO₂ cathodes in lithium-ion batteries using surface modification by atomic layer deposition [J]. Journal of the Electrochemical Society, 2010, 157(1): A75-A81.

[41] Zhang W, Yang L P, Wu Z X, et al. Controlled formation of uniform CeO2 nanoshells in a buffer solution [J]. Chemical Communications, 2016, 52: 1420-1423.

[42] Lee J G. Kim B S, Cho J P, et al. Effect of AlPO₄-nanoparticle coating concentration on high-cutoff-voltage electrochemical eperformances in LiCoO₂[J]. Journal of the Electrochemical Society, 2004, 151(6): A801-A805.

[43] Yang F L, Zhang W, Chi Z X, et al. Controlled formation of core–shell structures with uniform AlPO₄ nanoshells [J]. Chemical Communications, 2015, 51(14): 2943-2945.

[44] Lu Y C, Mansour A N, Yabuuchi N, et al. Probing the origin of enhanced stability of “AlPO₄” nanoparticle coated LiCoO₂ during cycling to high voltages: combined XRD and XPS studies [J]. Chemistry of Materials, 2009, 21(19): 4408-4424.

[45] Lee K T, Jeong S Y, Cho J P. Roles of surface chemistry on safety and electrochemistry in lithium ion batteries[J]. Accounts of Chemical Research, 2013, 46(5): 1161-1170.

[46] Lee H S, Dellatore S M, Miller W M, et al. Mussel-inspired surface chemistry for multifunctional coatings [J]. Science, 2007, 318(5849): 426-430.

[47] Postma A, Yan Y, Wang Y J, et al. Self-polymerization of dopamine as a versatile and robust technique to prepare polymer capsules [J]. Chemistry of Materials, 2009, 21(14): 3042-3044.

[48] Kang S M, Rho J S, Choi I S, et al. Norepinephrine: Material-independent, multifunctional surface modification reagent [J]. Journal of the American Chemical Society, 2009, 131(37): 13224-13225.

[49] Chi Z X, Zhang W, Cheng F Q, et al. Optimizing the carbon coating on LiFePO₄ for improved battery performance [J]. RSC Advances, 2014, 4(15): 7795-7798.

[50] Liu J, Qiao S Z, Liu H, et al. Extension of the Stöber method to the preparation of monodisperse resorcinol–formaldehyde resin polymer and carbon spheres [J]. Angewandte Chemie-International Edition, 2011, 50(26): 5947-5951.

[51] Liu J, Yang T Y, Wang D W, et al. A facile soft-template synthesis of mesoporous polymeric and carbonaceous nanospheres [J]. Nature Communications, 2013, 4: 2798.

[52] Chi Z X, Zhang W, Wang X S, et al. Accurate surface control of core–shell structured LiMn_0.5Fe_0.5PO4@C for improved battery performance [J]. Journal of Materials Chemistry A, 2014, 2(41): 17359-17365.

具有均匀壳层的纳米功能材料：构筑与应用

Uniform Nanoshells for Functional Materials：Constructions and Applications

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