基于CoP纳米阵列的亚硝酸根传感器的研究

doi:10.13208/j.electrochem.181055

摘要/Abstract

摘要： 亚硝酸盐对环境和人体健康有着不利的影响，人体长期食用含大量亚硝酸盐的食物有致癌的风险，对亚硝酸盐的分析和检测是非常重要的. 开发高效的电催化剂，从而实现高灵敏度和高选择性的亚硝酸盐检测具有十分重要的意义. 作者通过先水热再低温磷化获得了磷化钴纳米阵列（CoP/TM）.电化学测试结果表明，所构建的CoP/TM电极对亚硝酸盐的还原具有高效的催化作用，线性检测范围为1.0 μmol·L^-1到1.0 mmol·L^-1，检测下限为18 nmol·L^-1（S/N=3），响应灵敏度为17781 μA·(mmol·L^-1)^-1·cm^-2，响应时间小于3 s，选择性良好.

关键词: 磷化钴, 纳米阵列, 亚硝酸钠, 电化学, 传感器

Abstract: Nitrite has a negative impact on the environment and human health. The long-term consumption of nitrite-containing foods has a carcinogenic risk. Therefore, the analysis and detection of nitrite are important. It is of great significance to develop high-efficiency electrocatalysts to achieve high sensitivity and selectivity for nitrite detection. The cobalt phosphide nano-array (CoP/TM) was obtained by hydrothermal and low-temperature phosphating. The electrochemical test results show that the constructed CoP/TM was a highly efficient electrochemical reduction nitrite catalyst with the excellent sensing performance and response time less than 3 s, as well as the linear detection range of 1.0 μmol·L^-1 to 1.0 mmol·L^-1 and lower detection limit of 18 nmol·L^-1 (S/N = 3). The response sensitivity was 17718 μA·(mmol·L^-1)-1·cm^-2 with the satisfactory selectivity.

Key words: CoP, nanoarray, nitrite, electrochemical, sensor

中图分类号:

O646

周福玲, 熊小莉, 孙旭平. 基于CoP纳米阵列的亚硝酸根传感器的研究[J]. 电化学（中英文）, 2019, 25(2): 252-259.

ZHOU Fu-ling, XIONG Xiao-li, SUN Xu-ping. High-Efficiency Nitrite Sensor Based on CoP Nanowire Array[J]. Journal of Electrochemistry, 2019, 25(2): 252-259.

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.181055

https://electrochem.xmu.edu.cn/CN/Y2019/V25/I2/252

参考文献

[1] Manea F, Remes A, Radovan C, et al. Simultaneous electrochemical determination of nitrate and nitrite in aqueous solution using Ag-doped zeolite-expanded graphite-epoxy electrode[J]. Talanta, 2010, 83(1): 66-71.
[2] Braman R S, Hendrix S A. Nanogram nitrite and nitrate determination in environmental and biological materials by vanadium(III) reduction with chemiluminescence detection[J]. Analytical Chemistry, 1989, 61(24): 2715-2718.
[3] Guadagnini L, Tonelli D. Carbon electrodes unmodified and decorated with silver nanoparticles for the determination of nitrite, nitrate and iodate[J]. Sensors and Actuators B: Chemical, 2013, 188: 806-814.
[4] Panchompoo J, Compton R G. Electrochemical detection of ammonia in aqueous solution using fluorescamine: comparison of fluorometric versus voltammetric analysis[J]. Journal of Electrochemistry(电化学), 2012, 18(5): 437-449.
[5] Okafor P N, Ogbonna U I. Nitrate and nitrite contamination of water sources and fruit juices marketed in South-Eastern Nigeria[J]. Journal of Food Composition and Analysis, 2003, 16(2): 213-218.
[6] Akyüz M, Ata S. Determination of low level nitrite and nitrate in biological, food and environmental samples by gas chromatography-mass spectrometry and liquid chromatography with fluorescence detection[J]. Talanta, 2009, 79(3): 900-904.
[7] Fan Y Q(范艳群), Chen Q Y(陈庆阳), Xia J M(夏金梅 ), et al. Detection of glucosamine hydrochloride by ion chromatography with integrated pulsed amperometric detector[J]. Journal of Electrochemistry(电化学), 2014, 20(2): 164-170.
[8] Freitas C B, Moreira R C, de Oliveira Tavares M G, et al. Monitoring of nitrite, nitrate, chloride and sulfate in environmental samples using electrophoresis microchips coupled with contactless conductivity detection[J]. Talanta, 2016, 147: 335-341.
[9] Butt S B, Riaz M, Iqbal M Z. Simultaneous determination of nitrite and nitrate by normal phase ion-pair liquid chromatography[J]. Talanta, 2001, 55(4): 789-797.
[10] Wang C Y(王春燕), Liu X Q(刘晓秋), Qi Y X(戚颖欣). Electrochemical detection of hydrogen peroxide at AuNPs modified electrode using p-hydroxyphenylboronic acid as a precursor[J]. Journal of Electrochemistry(电化学), 2016, 22(1): 88-93.
[11] Shi P(石鹏), Wang B X(王伯轩), Song Q L(宋泉霖), et al. Application of Pd/graphene modified electrode in the detection of 4-chlorophenol[J]. Journal of Electrochemistry(电化学), 2015, 21(5): 488-495.
[12] Oyama S T, Gott T, Zhao H, et al. Transition metal phosphide hydroprocessing catalysts: A review[J]. Catalysis Today, 2009, 143(1/2): 94-107.
[13] Carenco S, Portehault D, Boissiere C, et al. Nanoscaled metal borides and phosphides: recent developments and perspectives[J]. Chemical Reviews, 2013, 113(10): 7981-
8065.
[14] Wang H J(王慧娟). Synthesis of ultrathin Co₃O₄ nanoflakes film material for electrochemical sensing[J]. Journal of Electrochemistry(电化学), 2016, 22(6): 631-635.
[15] Tang C, Cheng N Y, Pu Z H, et al. NiSe nanowire film supported on nickel foam: an efficient and stable 3D bifunctional electrode for full water splitting[J]. Angewandte Chemie International Edition, 2015, 127(32): 9483-9487.
[16] Jiang P, Liu Q, Liang Y H, et al. A cost-effective 3D hydrogen evolution cathode with high catalytic activity: FeP nanowire array as the active phase[J]. Angewandte Chemie International Edition, 2014, 126(47): 13069-13073.
[17] Li M X(李明轩), Ou J L(欧洁连), Chen Y X(陈燕鑫), et al. Preparation and catalytic properties of FeCo alloy nanocatalyst[J]. Journal of Electrochemistry(电化学), 2013, 19(2): 125-129.
[18] Liu Y W, Cao X Q, Kong R M, et al. Cobalt phosphide nanowire array as an effective electrocatalyst for non-enzymatic glucose sensing[J]. Journal of Materials Chemistry B, 2017, 5(10): 1901-1904.
[19] Tian J Q, Liu Q, Asiri A M, et al. Self-supported nanoporous cobalt phosphide nanowire arrays: an efficient 3D hydrogen-evolving cathode over the wide range of pH 0-14[J]. Journal of the American Chemical Society, 2014, 136(21): 7587-7590.
[20] Liu T T, Wang K Y, Du G, et al. Self-supported CoP nanosheet arrays: a non-precious metal catalyst for efficient hydrogen generation from alkaline NaBH4 solution[J]. Journal of Materials Chemistry A, 2016, 4(34): 13053-13057.
[21] Ai L, Niu Z, Jiang J. Mechanistic insight into oxygen evolution electrocatalysis of surface phosphate modified cobalt phosphide nanorod bundles and their superior performance for overall water splitting[J]. Electrochimica Acta, 2017, 242: 355-363.
[22] Pham X H, Li C A, Han K N, et al. Electrochemical detection of nitrite using urchin-like palladium nanostructures on carbon nanotube thin film electrodes[J]. Sensors and Actuators B: Chemical, 2014, 193: 815-822.
[23] Radhakrishnan S, Krishnamoorthy K, Sekar C, et al. A highly sensitive electrochemical sensor for nitrite detection based on Fe₂O₃ nanoparticles decorated reduced graphene oxide nanosheets[J]. Applied Catalysis B: Environmental, 2014, 148: 22-28.
[24] Zhang D, Fang Y X, Miao Z Y, et al. Direct electrodeposion of reduced graphene oxide and dendritic copper nanoclusters on glassy carbon electrode for electrochemical detection of nitrite[J]. Electrochimica Acta, 2013, 107: 656-663.
[25] Wang P, Mai Z B, Dai Z, et al. Construction of Au nano-particles on choline chloride modified glassy carbon electrode for sensitive detection of nitrite[J]. Biosensors and Bioelectronics, 2009, 24(11): 3242-3247.
[26] Shahid M M, Rameshkumar P, Pandikumar A, et al. An electrochemical sensing platform based on a reduced graphene oxide-cobalt oxide nanocube@platinum nano-
composite for nitric oxide detection[J]. Journal of Materials Chemistry A, 2015, 3(27): 14458-14468.
[27] Ting S L, Guo C X, Leong K C, et al. Gold nanoparticles decorated reduced graphene oxide for detecting the presence and cellular release of nitric oxide[J]. Electrochimica Acta, 2013, 111: 441-446.
[28] Pandikumar A, Yusoff N, Huang N M, et al. Electrochemical sensing of nitrite using a glassy carbon electrode modified with reduced functionalized graphene oxide decorated with flower-like zinc oxide[J]. Microchimica Acta, 2015, 182(5/6): 1113-1122.
[29] Haldorai Y, Kim J Y, Vilian A T E, et al. An enzyme-free electrochemical sensor based on reduced graphene oxide/Co₃O₄ nanospindle composite for sensitive detection of nitrite[J]. Sensors and Actuators B: Chemical, 2016, 227: 92-99.
[30] Saravanan J, Ramasamy R, Therese H A, et al. Electrospun CuO/NiO composite nanofibers for sensitive and selective non-enzymatic nitrite sensors[J]. New Journal of Chemistry, 2017, 41(23): 14766-14771.
[31] Lu L. Highly sensitive detection of nitrite at a novel electrochemical sensor based on mutually stabilized Pt nano-clusters doped CoO nanohybrid[J]. Sensors and Actuators B: Chemical, 2019, 281: 182-190.
[32] Wu Y Y, Li C, Dou Z Y, et al. A novel nitrite sensor fabricated through anchoring nickel-tetrahydroxy-phthalocyanine and polyethylene oxide film onto glassy carbon electrode by a two-step covalent modification approach[J]. Journal of Solid State Electrochemistry, 2014, 18(9): 2625-2635.
[33] Mani V, Periasamy A P, Chen S M. Highly selective amperometric nitrite sensor based on chemically reduced graphene oxide modified electrode[J]. Electrochemistry Communications, 2012, 17: 75-78.