基于对羟基苯硼酸为前驱体的金纳米粒子修饰电极电化学检测过氧化氢

doi:10.13208/j.electrochem.150908

电化学（中英文） ›› 2016, Vol. 22 ›› Issue (1): 88-93. doi: 10.13208/j.electrochem.150908

基于对羟基苯硼酸为前驱体的金纳米粒子修饰电极电化学检测过氧化氢

王春燕^1,2*，刘晓秋¹，戚颖欣¹

1. 吉林工程技术师范学院食品工程学院，吉林长春 130052；2. 中国科学院长春应用化学研究所电分析化学国家重点实验室，吉林长春 130022

收稿日期:2015-09-08 修回日期:2015-11-08 出版日期:2016-02-29 发布日期:2015-11-16
通讯作者: 王春燕 E-mail:wangcy@ciac.ac.cn
作者简介:王春燕
基金资助:
吉林省教育厅项目（No. 2013318，No. 2013372）、吉林省社会科学项目（No. 2012B260）资助

Electrochemical Detection of Hydrogen Peroxide at AuNPs Modified Electrode Using p-Hydroxyphenylboronic Acid as a Precursor

WANG Chun-yan ^{1, 2*}, LIU Xiao-qiu¹, QI Ying-xin¹

1. Institute of Food Engineering, Jilin Engineering Normal University, Changchun 130052, China; 2. State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, the Chinese Academy of Sciences, Changchun 130022, China

Received:2015-09-08 Revised:2015-11-08 Published:2016-02-29 Online:2015-11-16
Contact: WANG Chun-yan E-mail:wangcy@ciac.ac.cn
About author:WANG Chun-yan

摘要/Abstract

摘要：

以对羟基苯硼酸为前驱体，利用H₂O₂可以定量氧化对羟基苯硼酸产生对羟基苯酚的原理，以反应产物对羟基苯酚为电化学信号物质，结合金纳米粒子修饰玻碳电极（AuNPs/GCE），发展了一种间接检测H₂O₂的电化学方法. 由于AuNPs/GCE具有有效电子传递性能和比表面积大等优点，对硼酸氧化产物具有较高的催化活性，因此在含1.0 mmol•L^-1对羟基苯硼酸的0.1 mol•L^-1 pH 7.5 PBS中，AuNPs/GCE可以检测到1.0 ~ 1.0 × 10³ μmol•L^-1的H₂O₂，检测限为0.5 μmol•L^-1. 同时，该方法具有良好的选择性和重现性，且操作简单、速度快、价格低廉，非常适用于实际样品中H₂O₂含量的测定.

关键词: 对羟基苯硼酸, 金纳米粒子, 过氧化氢, 电化学检测

Abstract:

We developed a new method for electrochemical detection of hydrogen peroxide (H₂O₂) based on boronate oxidation of p-hydroxyphenylboronic acid. This method using p-aminophenol which is produced from the reaction of H₂O₂ and p-aminophenylboronic acid as a well electrochemical probe, combined with a gold nanoparticles (AuNPs) modified electrode for an indirect detection of H₂O₂. Because of the large surface area and enhanced electrocatalytic behavior by the AuNPs modified electrode, the detection sensitivity was improved. The method could detect H₂O₂ in the concentration range of 1 ~ 100 μmol•L^-1 and 0.1 ~ 1 mmol•L^-1 in 0.1 mol•L^-1pH 7.5 PBS containing 1.0 mmol•L^-1 p-hydroxyphenylboronic acid. The low detection limit was 0.5 μmol•L^-1. The proposed method had good selectivity and stability. Moreover, the method was quick, simple and cheap, which has potential application in real samples analysis.

Key words: p-Hydroxyphenylboronic acid, hydrogen peroxide, gold nanoparticles, electrochemical detection

中图分类号:

O657

王春燕*，刘晓秋，戚颖欣. 基于对羟基苯硼酸为前驱体的金纳米粒子修饰电极电化学检测过氧化氢[J]. 电化学（中英文）, 2016, 22(1): 88-93.

WANG Chun-yan*, LIU Xiao-qiu, QI Ying-xin. Electrochemical Detection of Hydrogen Peroxide at AuNPs Modified Electrode Using p-Hydroxyphenylboronic Acid as a Precursor[J]. Journal of Electrochemistry, 2016, 22(1): 88-93.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.150908

https://electrochem.xmu.edu.cn/CN/Y2016/V22/I1/88

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基于对羟基苯硼酸为前驱体的金纳米粒子修饰电极电化学检测过氧化氢

Electrochemical Detection of Hydrogen Peroxide at AuNPs Modified Electrode Using p-Hydroxyphenylboronic Acid as a Precursor

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