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电化学(中英文) ›› 2014, Vol. 20 ›› Issue (5): 470-475.  doi: 10.13208/j.electrochem.131129

• 研究论文 • 上一篇    下一篇

固体氧化物燃料电池Cu-LSCM-CeO2/LSCM-YSZ/Ni-ScSZ复合阳极制备及性能

吕尧,黄波*,顾习之,候春一,胡一星,王晓颖,朱新坚   

  1. 上海交通大学机械与动力工程学院燃料电池研究所,上海 200240
  • 收稿日期:2013-11-29 修回日期:2014-02-18 出版日期:2014-10-28 发布日期:2014-02-23
  • 通讯作者: 黄波 E-mail:huangbo2k@hotmail.com
  • 基金资助:

    国家自然科学基金项目(No. 51201098)资助

Fabrication and Characterization of the Ni-ScSZ Composite Anodes with a Cu-LSCM-CeO2 Catalyst Layer in the Thin Film SOFC

LV Yao, HUANG Bo*, GU Xi-zhi, HOU Chun-yi, HU Yi-xing, WANG Xiao-yin, ZHU Xin-jian   

  1. Institute of Fuel Cell, School of Mechanical Engineering, Shanghai Jiaotong University, Shanghai 200240, China
  • Received:2013-11-29 Revised:2014-02-18 Published:2014-10-28 Online:2014-02-23
  • Contact: HUANG Bo E-mail:huangbo2k@hotmail.com

摘要: 采用流延法制得LSCM-YSZ阳极支撑层/Ni-ScSZ阳极活性层/ScSZ电解质层复合膜,在LSCM-YSZ支撑层上印刷一层Cu-LSCM-CeO2阳极催化层,即Cu-LSCM-CeO2/LSCM-YSZ/Ni-ScSZ功能梯度层阳极. 研究表明,Cu/LSCM/CeO2质量配比为2:7:1功能梯度阳极(LSCM-YSZ2010)有较好的性能,单电池以氢气和乙醇为燃料(750 oC)最大功率密度分别为511和390 mW?cm-2,单电池稳定性实验表明,LSCM-YSZ2010阳极单电池以乙醇为燃料750 oC长时间运行218 h,性能稳定. X-射线能量散射分析表明该阳极具有较好的抗碳沉积性能.

关键词: 固体氧化物燃料电池(SOFC), 催化层, 碳沉积, 阻抗谱, 电化学性能

Abstract: Solid oxide fuel cell (SOFC) directly operating on hydrocarbon without external reforming has the potential of greatly speeding up the application of SOFCs for transportation. In this paper, a three-layer structure anode was fabricated by tape casting and screen printing method. The addition of Cu-LSCM-CeO2 to the supported anode surface presented better performance running on H2 and ethanol. The maximum power densities were 511 and 390 mW?cm-2, respectively, running on H2 and ethanol at 750 °C. No significant degradation was observed on the anode. Consequently, the Cu-LSCM-CeO2 catalyst layer on the surface of the LSCM-YSZ support layer makes it possible to have good stability for long-term operation in ethanol fuel due to free carbon deposition.

Key words: solid oxide fuel cell, catalyst layer, carbon deposit, impedance spectra, electrochemical performance

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