碳纳米管表面的无钯活化化学镀镍研究

电化学（中英文） ›› 2006, Vol. 12 ›› Issue (1): 25-28.

碳纳米管表面的无钯活化化学镀镍研究

胡光辉;吴辉煌;杨防祖;

厦门大学化学化工学院固体表面物理化学国家重点实验室,厦门大学化学化工学院固体表面物理化学国家重点实验室,厦门大学化学化工学院固体表面物理化学国家重点实验室福建厦门361005,福建厦门361005,福建厦门361005

收稿日期:2006-02-28 修回日期:2006-02-28 出版日期:2006-02-28 发布日期:2006-02-28

Electroless Nickel Plating on Carbon Nanotube with Non-palladium Activation Procedure

HUGuang-hui,WUHui-huang~*,YANGFang-zu

(College of Chemistry and Chemical Engineering,State Key Laboratory of Physical Chemistry of Solid Surfaces,Xiamen University,Xiamen 361005,Fujian,Chnia

Received:2006-02-28 Revised:2006-02-28 Published:2006-02-28 Online:2006-02-28

摘要/Abstract

摘要： 本文提出碳纳米管表面无钯活化的化学镀镍方法.碳纳米管经硝酸氧化和碱中和后表面生成羧基,利用羧基吸附镍离子,之后吸附的镍离子被化学还原为镍的纳米微粒并成为化学镀镍的催化活性中心.红外吸收光谱和电子显微镜观察等证实了上述活化过程的机理.实验表明,新的活化方法对碳纳米管表面化学镀是切实可行的,文中同时对化学沉积层的不同形貌进行讨论.

关键词: 碳纳米管, 表面活化, 化学镀镍

Abstract: A new procedure of surface activation without using palladium salt was proposed for electroless nickel plating on carbon nanotubes.In the procedure,carbon nanotubes were oxidized by nitric acid and then neutralized with NaOH to create carboxyl surface groups which were used to adsorb Ni~(2+)ions,thereafter the adsorbed Ni~(2+)ions were chemically reduced into Ni nano-particles as a catalytic center for electroless nickel deposition,all these were further confirmed by infrared absorption spectra and electron microscopic observations.The results indicate that the procedure is feasible to electroless nickel plating on carbon nanotubes.The different morphology of deposits obtained from electroless plating was also discussed.

Key words: Carbon nanotube, Surface activation, Electroless nickel plating

中图分类号:

TQ153

胡光辉;吴辉煌;杨防祖;. 碳纳米管表面的无钯活化化学镀镍研究[J]. 电化学（中英文）, 2006, 12(1): 25-28.

HUGuang-hui,WUHui-huang~*,YANGFang-zu. Electroless Nickel Plating on Carbon Nanotube with Non-palladium Activation Procedure[J]. Journal of Electrochemistry, 2006, 12(1): 25-28.

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链接本文: https://electrochem.xmu.edu.cn/CN/

https://electrochem.xmu.edu.cn/CN/Y2006/V12/I1/25

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