负载型离子液体在C-H键电氧化活化中的应用研究

doi:10.13208/j.electrochem.160315

电化学（中英文） ›› 2017, Vol. 23 ›› Issue (1): 1-6. doi: 10.13208/j.electrochem.160315

负载型离子液体在C-H键电氧化活化中的应用研究

陈姿颖，武倩倩，张健青，朱英红*，马淳安*

浙江工业大学化学工程学院，绿色化学合成技术国家重点实验室培育基地，浙江杭州 310032

收稿日期:2016-03-12 修回日期:2016-04-12 出版日期:2017-02-28 发布日期:2016-05-18
通讯作者: 朱英红，马淳安 E-mail:science@zjut. edu. cn
基金资助:
973前期研究专项（No. 2012CB722604）资助

Application of Composite Ionic Liquid in Electro-oxidation Activation of a C-H Bond

CHEN Zi-ying, WU Qian-qian, ZHANG Jian-qing, ZHU Ying-hong*, MA Chun-an*

College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

Received:2016-03-12 Revised:2016-04-12 Published:2017-02-28 Online:2016-05-18
Contact: ZHU Ying-hong, MA Chun-an E-mail:science@zjut. edu. cn

摘要/Abstract

摘要：

本文将1-乙基-3-甲基咪唑醋酸盐离子液体修饰在多壁碳纳米管上，制备出离子液体/碳纳米管复合材料，并研究了对甲氧基甲苯（p-MT）在该复合离子液体水溶液体系中的电氧化性能. 同时，通过循环伏安法和计时电流法考查了扫描速率、温度、反应底物浓度等因素对电氧化性能的影响，研究了p-MT在该体系中的动力学过程. 实验结果表明，p-MT在复合离子液体水溶液体系中发生不可逆的电氧化反应，且该过程受扩散控制，扩散系数为7.69×10^-10 cm²·s^-1. 适当地升高温度和增大反应底物浓度都有利于促进p-MT中C-H键选择性电氧化为相应醛基，选择性可达到95%. 通过在不同结构电解槽中进行恒电位电解研究，发现离子液体/MWCNTs复合电解质在一室型电解槽中进行p-MT电氧化的电解效率更高、对目标产物对甲氧基苯甲醛（p-MBA）的选择性也更好.

关键词: C-H键氧化, 离子液体/碳纳米管复合材料, 电氧化活化, 对甲氧基苯甲醛

Abstract:

In this paper, the ionic liquid/carbon nanotube composite material was prepared through modifying the ionic liquid 1-ethyl-3-methylimidazolium acetate to multi-walled carbon nanotubes. The electro-oxidation properties of p-methoxy toluene (p-MT) were studied using the composite as an electrolyte. The effects of scanning speed, temperature and substrate concentration were studied by cyclic voltammetry and chronoamperometry. The electrochemical kinetics of p-MT in this system was also studied. The results showed that the electrochemical oxidation of p-MT in the composite electrolyte solution was irreversible. The process was mainly controlled by diffusion, and the diffusion coefficient (D) was 7.69×10-10 cm2.s-1. Increasing the reaction temperature and the concentration of substrate could promote the electro-oxidation of the C-H bond to the corresponding aldehyde, and the selectivity of p-methoxybenzaldehyde (p-MBA) could improve to 95%. The electrolysis in one-pot was more efficiency and achieved better selectivity than that in the H-type.

Key words: the C-H bond oxidation, ionic liquid / nano composite material, Electro-oxidation activation, p-methoxybenzaldehyde

中图分类号:

O646

陈姿颖，武倩倩，张健青，朱英红，马淳安. 负载型离子液体在C-H键电氧化活化中的应用研究[J]. 电化学（中英文）, 2017, 23(1): 1-6.

CHEN Zi-ying, WU Qian-qian, ZHANG Jian-qing, ZHU Ying-hong, MA Chun-an. Application of Composite Ionic Liquid in Electro-oxidation Activation of a C-H Bond[J]. Journal of Electrochemistry, 2017, 23(1): 1-6.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.160315

https://electrochem.xmu.edu.cn/CN/Y2017/V23/I1/1

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负载型离子液体在C-H键电氧化活化中的应用研究

Application of Composite Ionic Liquid in Electro-oxidation Activation of a C-H Bond

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