碳纳米管电极电催化氧化降解活性艳红X-3B研究

电化学（中英文） ›› 2005, Vol. 11 ›› Issue (3): 329-332.

碳纳米管电极电催化氧化降解活性艳红X-3B研究

温轶,方建慧,曹为民,施利毅

上海大学理学院化学系,上海大学理学院化学系,上海大学理学院化学系,上海大学理学院化学系上海200444 ,上海200444 ,上海200444 ,上海200444

收稿日期:2005-08-28 修回日期:2005-08-28 出版日期:2005-08-28 发布日期:2005-08-28

Electrocatalytic Oxidation and Degration of Active Red X-3B by Nanotubes Catalytic Electrodes

WEN Yi, FANG Jian-hui~

(*), CAO Wei-min, SHI Li-yi(Departmentof Chemistry, ShanghaiUniversity, Shanghai200444,China

Received:2005-08-28 Revised:2005-08-28 Published:2005-08-28 Online:2005-08-28

摘要/Abstract

摘要： 将催化裂解法制得的碳纳米管,先经稀酸分散和空气热氧化处理,再按一定比例加入酚醛树脂,高速球磨处理后,将碳纳米管电极片热压成型.其表面形貌由扫描电镜(SEM)表征.以碳纳米管电催化电极作阳极,不锈钢片为阴极,降解处理含活性艳红X-3B模拟印染废水.考察了电流密度、电解质浓度、体系反应温度及pH值对废水降解效率的影响.结果表明:酸性条件下有利于染料有机物降解反应的进行,于常温下即可作高效降解处理.

关键词: 碳纳米管电极, 电催化氧化

Abstract: The catalytic splitting decomposition of carbon nanotubes isprocessed by dispersing with dilute nitric acid and thermal oxidation. Then well-proportionedphenolic resin is mixed in the carbon nanotubes. Then, the carbon nanotubesare made into electrodes by hot-press molding after the process of milling with high speed. The surface of the carbon nanotubes electrodes is analyzed by SEM. Active red X-3B simulated waster water is disposed by carbon nanotubes catalyticelectrode (anode) and stainless steel(cathode). The influencing factors of degradation by current density, concentrationof electrolyte, systemtemperature and pH are investigated. The experimental results indicated that acidiccondition is propitious tothe degradationreaction of organicdyestuff and wastewater can be disposed at normal temperature.

Key words: Nanotubes catalytic electrodes, Electrocatalytic oxidation, Dyestuff waste water

中图分类号:

TB383

温轶,方建慧,曹为民,施利毅. 碳纳米管电极电催化氧化降解活性艳红X-3B研究[J]. 电化学（中英文）, 2005, 11(3): 329-332.

WEN Yi, FANG Jian-hui~. Electrocatalytic Oxidation and Degration of Active Red X-3B by Nanotubes Catalytic Electrodes[J]. Journal of Electrochemistry, 2005, 11(3): 329-332.

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://electrochem.xmu.edu.cn/CN/

https://electrochem.xmu.edu.cn/CN/Y2005/V11/I3/329

参考文献

[1]WANG A i-m in(王爱民),YANG L i-hong(杨立红),ZHANG Su-juan(张素娟),et al.Status quo and pro-gress on treating wastewater contain ing dyestuff by elec-trochem ical m ethod[J].Industrial W ater Treatm ent,2001,21(8):4~7. [2]Le i L,Hu X,Chu H,et al.Catalytic wet air oxidationof dye ing and printing wastewater[J].W ater Sc ienceand Technology,1997,35(4):311~319. [3]Deepak B,Suresh K,Irfan,et al.Catalytic wet oxida-tion an environm ental solution for organ ic pollutant re-moval from paper and pu lp industrial waste liquor[J].App lied Catalysis A,2002,236:255~262. [4]N ikolayM,M arina V,A leksandr S.Solid catalysts forwet oxidation of n itrogen-contain ing organ ic compounds[J].Catalysis Today,1998,45:257~260. [5]WANG Dong-tian(王东田),WEI jie(魏杰),YU X iu-juan(于秀娟),et al.E lectro-catalytic oxidation of n i-trogen-contain ing organ ic compounds[J].Journal ofHarb in Institute of Technology,2003,10(1):19~23. [6]ZOU Q i-guang(邹启光),ZHOU Gong-m ing(周恭明).App lication and prospects for electro-catalytic oxi-dation in organ ic wastewater treatm ent[J].Engineeringand Technology,2002,7:20~21. [7]MENG Q ing-han(孟庆函),LI Kai-xi(李开喜),SONG Yan(宋燕).Study on the capac itive propertiesof activated carbon electrodes obtained from oil tar[J].New Carbon M aterials,2001,16(4):6~8. [8]ZHANG Deng-song(张登松),Dai Kai(代凯),FangJian-hu i(方建慧),et al.Research on mod ifications ofcarbon nanotubes[J].IndustrialM inerals and Process-ing,2004(3):14~17. [9]YANG Ye(杨晔),LU Fang(陆芳),PAN Zh i-yan(潘志彦),et al.H igh-salin ity O rgan ic W astewater Treat-m ent[J].Ch ina B iogas,2003,21(3):22~25. [10]Panswad T,Anan C.Impact of h igh chloride waste-water on an anaerob ic/anoxic/aerob ic process w ith andw ithout inocu lation of chloride acc lim ated seeds[J].W ater Research,1999,33:1 165~1 172.

[1]	孙齐, 韩严和, 付晓璐. 改性钛基PbO₂电极的制备及其对COD的快速检测[J]. 电化学（中英文）, 2021, 27(5): 558-569.
[2]	郑玉梅，尹振，王虹，李建新. Co₃O₄/Ti电催化膜电极制备及其苯甲醇催化氧化性能[J]. 电化学（中英文）, 2018, 24(2): 122-128.
[3]	林晓东，陈杜宏，田中群. 壳层厚度可调控的Ag@Pd@Pt纳米粒子的合成和甲酸电催化研究[J]. 电化学（中英文）, 2016, 22(6): 570-576.
[4]	王霞，胡俊，李永军*. 电化学制备二维“花状”Pt纳米结构及其对甲醇的电催化氧化[J]. 电化学（中英文）, 2014, 20(4): 365-369.
[5]	马永钧*，田玉秀，刘婧，周敏，丁静，金芝梅，王向梅. Nd-Fe-MoO₄^2-氰桥混配聚合物修饰铂电极的丙三醇电催化氧化[J]. 电化学（中英文）, 2014, 20(2): 150-155.
[6]	王彬, 王崇太, 华英杰, 刘津媛, 郑良飞. Keggin型钴取代杂多阴离子PW₁₁O₃₉Co(II)(H₂O)^5-的电催化性能[J]. 电化学（中英文）, 2013, 19(5): 488-492.
[7]	苏静, 林海波, 徐红, 黄卫民, 何亚鹏. 草酸在Ti/IrO₂-Ta₂O₅阳极圆柱形电解槽中的电催化氧化降解动力学[J]. 电化学（中英文）, 2013, 19(4): 293-299.
[8]	刘晓蕾, 丹媛媛, 陆海彦, 林海波, 欧阳明丽, 袁传军. 不同掺杂元素的钛基PbO₂电极对苯酚电催化氧化性能的影响[J]. 电化学（中英文）, 2013, 19(1): 59-64.
[9]	胡光辉, 曾海霞, 魏志钢, 潘湛昌, 谢署光, 邹燕娣. Ni-P-TiO2化学复合镀层电极的乙醇电催化氧化[J]. 电化学（中英文）, 2012, 18(2): 186-190.
[10]	陈野, 赵文丽, 温青. 阳极电沉积Ti/MnO2电极及其苯酚降解的电催化性能[J]. 电化学（中英文）, 2011, 17(2): 199-203.
[11]	褚道葆, 查龙武, 王树西, 王建, 肖英, 侯源源, 何建国, 张雪娇, . 离子液体中CNT/nanoTiO_2-Pt膜电极电催化氧化葡萄糖[J]. 电化学（中英文）, 2009, 15(3): 299-303.
[12]	崔艳萍, 杨昌柱, 黄健, 濮文虹, 张敬东, . 新型纳米金修饰玻碳电极对水杨酸的电催化氧化[J]. 电化学（中英文）, 2008, 14(3): 298-303.
[13]	初园园, 邬冰, 唐亚文, 陆天虹, 高颖, . 甲醇在Pt/C和Pt/WO_3/C电极上的电氧化[J]. 电化学（中英文）, 2008, 14(2): 155-158.
[14]	郑一雄;姚士冰;周绍民;. Ni-B非晶态合金纳米粉末微电极上甲醇的电催化氧化[J]. 电化学（中英文）, 2007, 13(3): 307-311.
[15]	潘丹梅, 胡荣宗, 韦冬萍, 丁昊冬, . Ni电极电化学流通池检测四环素类药品的研究[J]. 电化学（中英文）, 2007, 13(2): 122-126.