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电化学(中英文) ›› 2011, Vol. 17 ›› Issue (2): 199-203.  doi: 10.61558/2993-074X.2832

• 研究论文 • 上一篇    下一篇

阳极电沉积Ti/MnO2电极及其苯酚降解的电催化性能

陈野*, 赵文丽, 温青   

  1. 哈尔滨工程大学 材料科学与化学工程学院,黑龙江 哈尔滨 150001
  • 收稿日期:2011-05-05 修回日期:2011-05-05 出版日期:2011-05-28 发布日期:2011-05-06
  • 通讯作者: 陈野 E-mail:chenye@hrbeu.edu.cn
  • 基金资助:

    哈尔滨市科技创新人才研究专项资金项目(2009RFXXG204);高技术船舶专项项目

Anode Electrodeposition of Ti/MnO2 Electrode and Electrocatalytic Oxidization Properties of Phenol Degradation

CHEN Ye*, ZHAO Wen-Li, WEN Qing   

  1. College of Materials Science and Chemical Engineering, Harbin Engineering University,
    Harbin 150001, Heilongjiang, China
  • Received:2011-05-05 Revised:2011-05-05 Published:2011-05-28 Online:2011-05-06
  • Contact: CHEN Ye E-mail:chenye@hrbeu.edu.cn

摘要: 应用阳极电沉积法制备钛基二氧化锰(Ti/MnO2)电极. 采用X射线衍射(XRD)、扫描电子显微镜(SEM)及能谱(EDS)表征电极结构形貌. 用V~logi及苯酚降解实验优化电极制备工艺参数:在电流密度4 mA•cm-2、Mn2+离子浓度0.5 mol•L-1及温度70 ℃条件下阳极电沉积Ti/MnO2电极. 以苯酚为目标有机物,评价该电极电催化氧化性能,降解7h降解效率达49.6%.

关键词: 二氧化锰, 电沉积, 电催化氧化, 苯酚

Abstract: Ti-base manganese dioxide (Ti/MnO2) electrode was prepared by anodically electrodeposition technology in this paper. The structure of the electrode, the microstructure of the electrode surface and the element composition of the electrode were analyzed by XRD, SEM and EDS. The preparation process parameters of the electrode were studied in detail with the help of the V~logi curve and phenol degradation curve. The Ti/MnO2 electrode was anodically electrodeposited at current density 4mA•cm-2, the Mn2 + ions concentration 0.5mol•L-1 and temperature70℃. The V~logi curve and phenol degradation curve were used to evaluate electrocatalytic oxidization properties of the electrode with phenol as the goal organisms, achievng 49.6 % degradation efficiency for 7 hours.

Key words: MnO2, electrodeposition, electrocatalytic oxidization, phenol

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