金属配位化合物溶液的电化学研究

摘要/Abstract

摘要： 在已有的研究基础上，综述了近年来金属配位化合物溶液的电化学研究．内容包括：采用多种电化学方法研究金属配合物、簇状化合物溶液的电化学，配合物氧化还原电对的标准电极电位及有关的平衡常数，配合物的电极反应动力学及其与结构性能的关系，配合物的电催化作用，配合物的电合成．探讨配合物电极反应机理，测定多种电化学参数，提供了许多关于配合物性质、结构和功能的重要信息

关键词: 金属配合物, 簇合物, 溶液电化学, 电催化, 电合成

Abstract: The prospectus of electrochemical studies of metal complexes in solution have been introduced as a background of our research work. The electrochemical behaviors of the metal complexes and clusters have been investigated by many kinds of electrochemical methods.The content includes the standard electrode potential and the related equilibrium constant, electrochemical kinetics and the related behavior of structure, electrocatalysis and electrosynthesis of metal complexes. The electrode reaction mechanisms of the complexes have been approached. The methods for measuring some thermodynamic and kinetic parameters of the complexes are also given. Electrochemical studies would provid many kinds of important information for studying the coordination behaviour,structure ,property and function of the metal complexes.

Key words: Metal complexes, Cluster, Electrochemistry of solution, Electrocatalysis, Electrosyntheses

中图分类号:

O646

童叶翔,康北笙,杨绮琴. 金属配位化合物溶液的电化学研究[J]. 电化学（中英文）, 1999, 5(4): 361-370.

Tong Yexiang * Kang Beisheng Yang Qiqin . Electrochemical Studies of Metal Complexes in Solution[J]. Journal of Electrochemistry, 1999, 5(4): 361-370.

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链接本文: https://electrochem.xmu.edu.cn/CN/

https://electrochem.xmu.edu.cn/CN/Y1999/V5/I4/361

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