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电化学(中英文) ›› 2008, Vol. 14 ›› Issue (1): 66-70.  doi: 10.61558/2993-074X.1865

• 研究论文 • 上一篇    下一篇

溅射功率对氧化锡薄膜结构和电化学性能的影响

蔡敏真;宋杰;吴启辉;郑明森;吴孙桃;董全峰;   

  1. 厦门大学物理系,厦门大学固体表面物理化学国家重点实验室化学化工学院化学系,厦门大学物理系,厦门大学固体表面物理化学国家重点实验室化学化工学院化学系,厦门大学萨本栋微机电研究中心,厦门大学固体表面物理化学国家重点实验室化学化工学院化学系 福建厦门361005,福建厦门361005,福建厦门361005,福建厦门361005,福建厦门361005,福建厦门361005
  • 收稿日期:2008-02-28 修回日期:2008-02-28 出版日期:2008-02-28 发布日期:2008-02-28

The Influence of the Sputtering Power on the Structural and Electrochemical Properties of Tin Oxide Films

CAI Min-zhen1,SONG Jie2,ZHENG Ming-sen2,WU Qi-hui1,WU Sun-tao3,Dong Quan-Feng2   

  1. (1.Department of Physics,Xiamen University,Xiamen 361005,Fujian,China;2.School of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,Fujian,China;3.Pen Tung Sah MEMS Research Center,Xiamen University,Xiamen 361005,Fujian,China
  • Received:2008-02-28 Revised:2008-02-28 Published:2008-02-28 Online:2008-02-28

摘要: 应用射频磁控溅射技术在硅基底上制备氧化锡薄膜,着重研究溅射功率对薄膜结构和电化学性能的影响.XRD,SEM分析及恒电流充放电测试表明,随着溅射功率的增大,薄膜的结晶程度提高;生长速率和晶粒尺寸增大;电池的贮锂容量减少,且首圈不可逆容量损失增大.溅射功率对薄膜的电化学性能有较大的影响.

关键词: 氧化锡薄膜, 阳极材料, 磁控溅射, 电化学性能

Abstract: Tin oxide films were deposited on silicon substrates at room temperature using the radio frequency(RF) magnetron sputtering with different sputtering power.The influence of sputtering power upon the crystal structure,surface morphology and electrochemical properties of tin oxide films were then investigated.The XRD and SEM results illustrate that the phase of tin oxide thin films changed from amorphous to crystalline and the grain size augments with the increase of the sputtering power.The constant current charge and discharge cycle tests imply that the initial irreversible capacity loss of Li/tin oxide batteries increase and which capacity decrease as the sputtering power increases.The sputtering power has a great influence upon the structural and electrochemical properties of tin oxide films.

Key words: tin oxide films, the anode material, RF magnetron sputtering, electrochemical property

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