改性壳聚糖质子交换膜在隔膜电解制备FeO_4~(2-)中的应用

电化学（中英文） ›› 2006, Vol. 12 ›› Issue (1): 35-39.

改性壳聚糖质子交换膜在隔膜电解制备FeO_4~(2-)中的应用

钟淮真;陈日耀;郑曦;陈震;

福建师范大学化学与材料学院,福建师范大学化学与材料学院,福建师范大学化学与材料学院,福建师范大学化学与材料学院福建福州350007,福建福州350007,福建福州350007,福建福州350007

收稿日期:2006-02-28 修回日期:2006-02-28 出版日期:2006-02-28 发布日期:2006-02-28

Electro-generated FeO_4~(2-) Using Modified Chitosan Cation Exchange Membrane

ZHONG Huai-zhen,CHEN Ri-yao,ZHENG Xi,CHEN Zhen~*

(College of Chemistry and Materials Science,Fujian Normal University,Fuzhou 350007,Fujian,China

Received:2006-02-28 Revised:2006-02-28 Published:2006-02-28 Online:2006-02-28

摘要/Abstract

摘要： 由壳聚糖,经2%H2SO4交联处理、1%H2SO4掺杂制备壳聚糖质子交换膜.膜特性(如溶胀率、交换容量、渗透性、电解隔膜等)测试表明,该壳聚糖膜可适用于隔膜电解制备高铁酸盐.与Nafion膜相比,具有工艺简便,价格便宜等优点.

关键词: 改性壳聚糖, FeO42-, 质子交换膜, 电解

Abstract: The chitosan cation membrane was prepared by crosslinked 2% and doped with 1% H_(2)SO_(4).The products were marked as MCS.The physical properties and the ion exchange capacity of MCS were studied.Compared to the non-modified membrane,it was found that chemical modifications contributed to improving ion exchange capacity from 0.25 to 2.09 meq/g.Results was also suggested that the MCS can be used as a separator when producing sodium ferrate flocculent using electrochemical process.

Key words: Chitosan, Modification, Cation exchange membrane, Electrolyte

中图分类号:

O614.811

钟淮真;陈日耀;郑曦;陈震;. 改性壳聚糖质子交换膜在隔膜电解制备FeO_4~(2-)中的应用[J]. 电化学（中英文）, 2006, 12(1): 35-39.

ZHONG Huai-zhen,CHEN Ri-yao,ZHENG Xi,CHEN Zhen~*. Electro-generated FeO_4~(2-) Using Modified Chitosan Cation Exchange Membrane[J]. Journal of Electrochemistry, 2006, 12(1): 35-39.

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://electrochem.xmu.edu.cn/CN/

https://electrochem.xmu.edu.cn/CN/Y2006/V12/I1/35

参考文献

[1]ZHEN Q iu-yang,BAO Zhen-song.E ffects of surfactantand ac id type on preparation of ch itosan m icrocapsu les[J].Ch ina Particuology,2004,2(2):70~75. [2]H ideto M atsuyam a,H ideto Sh ish iraish i.E ffect of m em-brane preparation cond itions on solute perm eab ility inch itosan m embrane[J].Journal of App lied Polym er Sc i-ence,1999,73:2715~2725. [3]Y ING W an,Katherine A M.Creber.Synthesis,char-acterization and ion ic conductive properties of phospho-rylated ch itosan m embranes.m acromol[J].Chem.Phys.,2003,204:850~858. [4]Nelsen L,Cross R A,V igen M A.,et al.Syntheticthromboresistant surfaces from su lfonated polyelectrolytecomp lexes[J].Surgery,1970,67:826~830. [5]Schreyer J M,Thompson G W,Ockerm an L.Oxidationof chrom ium(III)w ith potassium ferrate(VI)[J].A-nal.Chem.,1950,22(11):1426~1427. [6]WAMG X iao-p ing(王筱平),YU Zhao-xiang(余兆祥).Preparation and properties of ch itosan/pectin polyelec-trolyte comp lex[J].Chem ical W orld,2002,261~263(5):235~271. [7]LIU Fu-q iang(刘富强),X ING Dan-m in(邢丹敏),etal.Nafion/PTFE composite m embrane for PEMFC[J].E lectrochem istry,2002,8(1):86~92. [8]Tiekea B,Van F,Ackern L,et al.U ltrath in self-assem-b led polyelectrolyte mu ltilayerm embranes[J].Phys.J.E,2001,5:29~39. [9]Byun H S,Burford R P,et al.Su lfonation of cross-linked asymm etri m embranes based on polystyrene andd ivinylbenzene[J].App lied Polym er Sc ience,1994,52:825~835. [10]Mokrin i A.,Acosta J L.New ion conducting system sbased on star branched b lock copolym er[J].Polym er,2001,42:8817~8824. [11]Unn ikrishnan E K,Kum ar S D.Perm eation of inorgan-ic an ions through nafion ionom erm embrane[J].M em-brane Sc i.,1997,125:269. [12]CHEN Zhen,Okum i Z,Takehara Z I.App lication ofthe SPE mothod to organ ic electrochem istry.X II.-leadd ioxide as a m ed iator for electro-oxidation of c innamylalcohol on Pt-nafion[J].Bu ll.Chem.Soc.Jpn.,1991,64:1261. [13]CHEN Zhen,M izoe T,Okum i Z,et al.App lication ofthe SPE mothod to organ ic electrochem istry.X I.-influ-ence of the solvent on electro-oxidation of c innamyl al-cohol on Pt-nafion[J].Bu ll.Chem.Soc.Jpn.,1991,64:537.

[1]	刘晨希, 邹泽萍, 胡梅雪, 丁宇, 谷宇, 刘帅, 南文静, 马溢昌, 陈招斌, 詹东平, 张秋根, 庄林, 颜佳伟, 毛秉伟. 电极/碱性聚电解质界面的微分电容曲线和零电荷电位测定[J]. 电化学（中英文）, 2024, 30(3): 2303151-.
[2]	陈浩杰, 唐美华, 陈胜利. 质子交换膜燃料电池阴极催化层疏水性优化[J]. 电化学（中英文）, 2023, 29(9): 2207061-.
[3]	高玲玉, 杨琳, 王晨辉, 单桂轩, 霍欣怡, 张梦飞, 李韡, 张金利. 碱性电解槽三维两相CFD模拟研究[J]. 电化学（中英文）, 2023, 29(9): 2207081-.
[4]	丑佳, 王雅慧, 王文鹏, 辛森, 郭玉国. 面向高性能锂-硫二次电池应用的非对称电极-电解质界面[J]. 电化学（中英文）, 2023, 29(9): 2217009-.
[5]	侯博文, 何龙, 冯旭宁, 张伟峰, 王莉, 何向明. 胺类添加剂对NCM811‖SiC电池热失控抑制效果研究[J]. 电化学（中英文）, 2023, 29(8): 2211141-.
[6]	张修庆, 唐帅, 付永柱. 锂硫电池电解液功能性添加剂研究进展[J]. 电化学（中英文）, 2023, 29(4): 2217005-.
[7]	罗宇, 马如琴, 龚正良, 杨勇. 固态锂硫电池研究进展[J]. 电化学（中英文）, 2023, 29(3): 2217007-.
[8]	冯辛, 刘博文, 郭可鑫, 范林丰, 王根香, 次素琴, 温珍海. 基于阳极甘油氧化电催化的碱/酸混合电解制氢研究[J]. 电化学（中英文）, 2023, 29(2): 2215005-.
[9]	邹庚, 冯炜程, 宋月锋, 汪国雄. 固体氧化物电解池阳极材料研究进展[J]. 电化学（中英文）, 2023, 29(2): 2215006-.
[10]	汪恒吉, 陈文国, 全周益, 赵凯, 孙毅飞, 陈旻, 奥坚科·弗拉基米尔. 多孔陶瓷支撑型管式固体氧化物电解池性能研究[J]. 电化学（中英文）, 2023, 29(12): 2204131-.
[11]	谷宇, 胡元飞, 王卫伟, 尤恩铭, 唐帅, 苏建加, 易骏, 颜佳伟, 田中群, 毛秉伟. 碳酸酯类电解液中纳米银电极界面过程的原位拉曼光谱研究[J]. 电化学（中英文）, 2023, 29(12): 2301261-.
[12]	韦宗楠, 曹敏纳, 曹荣. 瓜环基金属纳米催化剂的电化学研究进展[J]. 电化学（中英文）, 2023, 29(1): 2215008-.
[13]	郭丹丹, 俞红梅, 迟军, 邵志刚. 自支撑NiFe LDHs@Co-OH-CO₃纳米棒阵列电极用于碱性阴离子交换膜电解水[J]. 电化学（中英文）, 2022, 28(9): 2214003-.
[14]	倪静, 施兆平, 王显, 王意波, 吴鸿翔, 刘长鹏, 葛君杰, 邢巍. 低铱酸性氧析出电催化剂的研究进展[J]. 电化学（中英文）, 2022, 28(9): 2214010-.
[15]	甘团杰, 武建平, 刘石, 区文俊, 凌彬, 康雄武. 低结晶度AuPt-Ru/CNTs合金异质结作为高效多功能电催化剂[J]. 电化学（中英文）, 2022, 28(8): 2201241-.