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电化学(中英文)

• 电化学获奖人专辑 •    

电解水用溶剂化离子交换膜的研究现状及存在问题

周正元a, 孙雨涛b刘振邦c, 王传正a,b, 周永南a, 罗希a, 周天池b,d,*, 乔锦丽a,*   

  1. a. 东华大学环境工程学院国家先进纤维材料重点实验室,上海,201620; b. 盐城工学院柔性功能材料研究所,盐城,224051; c. 上海工程技术大学纺织服装学院,上海,201620; d. 绍兴市图锦纺织有限公司博士创新工作站,绍兴,312099
  • 发布日期:2025-09-22
  • 通讯作者: 周天池, 乔锦丽 E-mail:zhoutianchi@ycit.edu.cn; qiaojl@dhu.edu.cn

Development Status and Existing Problems of Ion-Solvating Membranes for Electrolysis of Water

Zhengyuan Zhoua, Yutao Sunb, Zhengbang Liuc, Chuanzheng Wangb, Yongnan Zhoua, Xi Luoa, Tianchi Zhoub,d,*, Jinli Qiaoa,*   

  1. a. State Key Laboratory of Advanced fiber Malterials, College of Environmental science and Engineering, Donghua University, Shanghai 201620, China; b. Flexible functional materials Institute, Yancheng Institute of Technology, Yancheng 224051, China; c. School of Textiles and Fashion, Shanghai University of Engineering Science, Shanghai 201620, China; d. Shaoxing Doctoral Innovation Station, Shaoxing Tujin Textile Co, Shaoxing 312099, China
  • Online:2025-09-22
  • Contact: Tianchi Zhou, Jinli Qiao E-mail:zhoutianchi@ycit.edu.cn; qiaojl@dhu.edu.cn

摘要: 溶剂化离子交换膜(ISMs)近年来作为电化学能源转换与存储装置的核心组件,已获得学界广泛关注。本文从基质结构分类角度,系统梳理了离子交换膜的结构组成、性能优势、研究进展、离子传导机制及现存问题,并深入解析了性能优化方法、关键性能指标及影响因素。该研究为优化离子交换膜的设计应用提供理论支撑,为未来水电解制氢、电化学储能等领域的技术发展注入新动能。

关键词: 离子溶剂化膜, 碱性水电解, 去质子化基团, 离子传导机制, 氢能

Abstract: Ion-solvaing membranes (ISMs) have received extensive attention in recent years as a key component in electrochemical energy conversion and storage devices. This article provides an overview of structural composition, the performance advantages, research progress, ion conduction mechanism and existing issues of ISMs, primarily classifying them according to the matrix structure. A detailed analysis of performance enhancement methods, the key performance indicators of ISMs and performance influencing factors are also presented. The article contributes to further optimizing the design and application of ion-solvation membranes, providing theoretical support for the development of fields such as hydrogen production through electrolysis of water and electrochemical energy in the future.

Key words: Ion-solvation membrane, Alkaline Water Electrolysis, Deprotonated group, Ionic conduction mechanism, Hydrogen energy