嵌段共聚物薄膜在电化学能源领域的应用

doi:10.61558/2993-074X.2028

电化学（中英文） ›› 2010, Vol. 16 ›› Issue (1): 11-15. doi: 10.61558/2993-074X.2028

嵌段共聚物薄膜在电化学能源领域的应用

李晶泽;陈国光;梅迪;邹威;李剑文;小村元宪;弥田智一;

电子科技大学微电子与固体电子学院电子薄膜与集成器件国家重点实验室;日本东京工业大学资源化学研究所;

收稿日期:2010-02-28 修回日期:2010-02-28 出版日期:2010-02-28 发布日期:2010-02-28

Applications of Block Copolymer Films in the Field of Electrochemical Energy Systems

LI Jing-ze1*,CHEN Guo-guang1,MEI Di1,ZOU Wei1,LI Jian-wen1,KOMURA Motonori2,IYODA Tomokazu2

(1.State Key Laboratory of Electronic Thin Film and Integrated Device,School of Microelectronic and Solid-state Electronic,University of Electronic Science and Technology of China,Chengdu 610054,China;2.Chemical Resources Laboratory,Tokyo Institute of Technology,Yokohama 226-8503,Japan

Received:2010-02-28 Revised:2010-02-28 Published:2010-02-28 Online:2010-02-28

摘要/Abstract

摘要： 采取选择性掺杂方法,将新型两亲性液晶嵌段共聚物薄膜功能化为具有各向异性的锂离子导电材料.这类薄膜不仅具有同轴且垂直取向的一维离子导电通道,而且可以在大面积范围内形成规则的阵列,可以作为锂离子电池、燃料电池等电化学能源系统的新型电解质.另一方面,这类薄膜作为模板可制备周期性排列的纳米孔、纳米粒子、纳米线阵列,形成的有序纳米结构材料可作为锂离子电池的三维电极.

关键词: 嵌段共聚物, 离子导电, 锂离子电池, 纳米材料

Abstract: A new series of amphiphilic liquid crystalline block copolymer thin films,having normally aligned and highly ordered nanocylinder array,were functionalized as anisotropic ion conducting materials by selectively infiltration.These ion-active nanocylinders are coaxially aligned and hexagonally arranged in a large area,which might be used as novel types of electrolyte films for electrochemical energy systems such as lithium ion battery,fuel cell,etc.Since the ordered cylinders can carry on and store the ions,the block copolymer films can be utilized as the advanced template to fabricate the ordered array of nanoporous,nanoparticles,and nanowires for the potential application in lithium ion battery as three dimensional electrode materials.

Key words: block copolymer, ionic conducting, lithium ion battery, nanomaterials

中图分类号:

TM912

李晶泽, 陈国光, 梅迪, 邹威, 李剑文, 小村元宪, 弥田智一, . 嵌段共聚物薄膜在电化学能源领域的应用[J]. 电化学（中英文）, 2010, 16(1): 11-15.

LI Jing-ze, CHEN Guo-guang, MEI Di, ZOU Wei, LI Jian-wen, KOMURA Motonori, IYODA Tomokazu. Applications of Block Copolymer Films in the Field of Electrochemical Energy Systems[J]. Journal of Electrochemistry, 2010, 16(1): 11-15.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.61558/2993-074X.2028

https://electrochem.xmu.edu.cn/CN/Y2010/V16/I1/11

参考文献

[1]Gray F M.Polymer electrolytes[M].London:The Royal Society of Chemistry,1987. [2]Bandara L,Dissanayake M,Mellander B E.Ionic con-ductivity of plasticized(PEO)-LiCF3SO3electrolytes[J].Electrochim Acta,1998,43:1447. [3]Golodnitsky D,Livshits E,Rosenberg Y,et al.Stretching-induced changes in ion-polymer interactions in semicrys-talline LiI-P(EO)(n)polymer electrolytes[J].Solid State Ionics,2002,147:265. [4]Kato T.Self-assembly of phase-segregated liquid crystal structures[J].Science,2002,295:2414. [5]Maki-Ontto R,K de Moel,Polushkin E,et al.Tridirec-tional protonic conductivity in soft materials[J].Adv Mater,2002,14:357. [6]Tian Y Q,Watanabe K,Kong X X,et al.Synthesis,nanostructures,and functionality of amphiphilic liquid crystalline block copolymers with azobenzene moieties[J].Macromolecules,2002,35:3739. [7]Li J Z,Kamata K,Komura M,et al.Anisotropic ion con-ductivity in liquid crystalline diblock copolymer mem-branes with perpendicularly oriented PEO cylindrical do-mains[J].Macromolecules,2007,40:8125. [8]Li J Z,Kamata K,Iyoda T.Tailored Ag nanoparticle ar-ray fabricated by block copolymer photolithography[J].Thin Solid Films,2008,516:2577. [9]Li J Z,Kamata K,Watanabe S,et al.Template-and vac-uum-ultraviolet-assisted fabrication of a Ag-nanoparticle array on flexible and rigid substrates[J].Adv Mater,2007,19:1267. [10]Komura M,Iyoda T.AFM cross-sectional imaging of perpendicularly oriented nanocylinder structures of mi-crophase-separated block copolymer films by crystal-like cleavage[J].Macromolecules,2007,40:4106. [11]Yu H F,Li J Z,Ikeda T,et al.Macroscopic parallel nanocylinder array fabrication using a simple rubbing technique[J].Adv Mater,2006,18:2213. [12]Li H,Huang X J,Chen L Q,et al.A high capacity nano-Si composite anode material for lithium recharge-able batteries[J].Electrochem Solid State Lett,1999,2:547. [13]Maier J.Mass storage in space charge regions of nano-sized systems(Nano-ionics.Part V)[J].Faraday Discuss,2007,134:51.

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嵌段共聚物薄膜在电化学能源领域的应用

Applications of Block Copolymer Films in the Field of Electrochemical Energy Systems

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