高比能电池新材料与安全性新技术的研究进展  Ⅰ.锂离子电池自激发安全保护机制

doi:10.61558/2993-074X.2027

电化学（中英文） ›› 2010, Vol. 16 ›› Issue (1): 6-10. doi: 10.61558/2993-074X.2027

高比能电池新材料与安全性新技术的研究进展 Ⅰ.锂离子电池自激发安全保护机制

艾新平;曹余良;杨汉西;

湖北省化学电源材料与技术重点实验室武汉大学化学与分子科学学院;

收稿日期:2010-02-28 修回日期:2010-02-28 出版日期:2010-02-28 发布日期:2010-02-28

Self-activating Safety Mechanisms for Li-ion Batteries

AI Xin-ping*,CAO Yu-Liang,YANG Han-Xi

(College of Chemistry and Molecular Sciences,Hubei Key Lab.of Eletrochemical Power Sources,Wuhan University,Wuhan 430072,China

Received:2010-02-28 Revised:2010-02-28 Published:2010-02-28 Online:2010-02-28

摘要/Abstract

摘要： 安全性问题是阻碍大容量和高功率锂离子动力电池应用的关键.本文以作者课题组近期研究工作为主,简要介绍了几种旨在提高锂离子电池安全性的自激发安全保护机制,包括氧化还原穿梭剂、电压敏感隔膜、温度敏感电极、阻燃性电解液,并分析了这些方法的应用特点.

关键词: 锂离子电池, 安全性, 电压钳制, 阻燃, 温度敏感电极

Abstract: The safety concerns of LIBs are considered to be a main obstacle to their high rate or large capacity applications in electric vehicles.This paper describes briefly our research works on the development of self-activating safety mechanisms for LIBs,including redox shuttle,potential-sensitive separator,temperature-sensitive electrode,and fire-retardent electrolyte.The problems and future in this research area are also discussed.

Key words: lithium ion battery, overcharge protection, safety, fire-retardancy, temperature-sensitive electrode

中图分类号:

TM912

艾新平, 曹余良, 杨汉西, . 高比能电池新材料与安全性新技术的研究进展 Ⅰ.锂离子电池自激发安全保护机制[J]. 电化学（中英文）, 2010, 16(1): 6-10.

AI Xin-ping, CAO Yu-Liang, YANG Han-Xi. Self-activating Safety Mechanisms for Li-ion Batteries[J]. Journal of Electrochemistry, 2010, 16(1): 6-10.

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://electrochem.xmu.edu.cn/CN/10.61558/2993-074X.2027

https://electrochem.xmu.edu.cn/CN/Y2010/V16/I1/6

参考文献

[1]Moshkovich M,Cojocaru M,Gottlieb H E,et al.The study of the anodic stability of alkyl carbonate solutions by in situ FTIR spectroscopy,EQCM,NMR and MS[J].Journal of Electroanalytical Chemistry,2001,497:84-96. [2]Du Pasquier A,Disma F,Bowmer T,et al.Differential scanning calorimetry study of the reactivity of carbon an-odes in plastic Li-ion batteries[J].J Electrochem Soc,1998,145:472-477. [3]Xiao Lifen,Ai Xinping,Cao Yuliang,et al.Electrochem-ical behavior of biphenyl as polymerizable additive for o-vercharge protection of lithium ion batteries[J].Electro-chimica Acta,2004,49(24):4189-4196. [4]Feng X M,Ai X P,Yang H X.Possible use of methyl-benzenes as electrolyte additives for improving the over-charge tolerance of Li-ion batteries[J].Journal of Ap-plied Electrochemistry,2004,34:1199-1203. [5]Cha C S,Ai X P,Yang H X.Polypyridine complexes of iron used as redox shuttles for overcharge protection of secondary lithium batteries[J].Journal of Power Sources,1995,54(2):255-258. [6]Feng J K,Ai X P,Cao Y L,et al.A highly soluble dime-thoxybenzene derivative as a redox shuttle for overcharge protection of secondary lithium batteries[J].Electro-chemistry Communications,2007,9:25-30. [7]Li S L,Ai X P,Feng J K,et al.Diphenylamine:A safety electrolyte additive for reversible overcharge protection of3.6V-class lithium ion batteries[J].Journal of Pow-er Sources,2008,184:553-556. [8]Xiao L F,Ai X P,Cao Y L,et al.A composite polymer membrane with reversible overcharge protection mecha-nism for lithium ion batteries[J].Electrochemistry Communications,2005,7:589-592. [9]Novak Petr,Muller Klaus,Santhanam K S V,et al.Elec-trochemically active polymers for rechargeable batteries[J].Chem Rev,1997,97:207-281. [10]Feng J K,Ai X P,Cao Y L,et al.Polytriphenylamine used as an electroactive separator material for over-charge protection of rechargeable lithium battery[J].Journal of Power Sources,2006,161:545-549. [11]Li S L,Ai X P,Yang H X,et al.A polytriphenylamine-modified separator with reversible overcharge protection for3.6V-class lithium-ion battery[J].Journal of Pow-er Sources,2009,189:771-774. [12]Feng X M,Ai X P,Yang H X,et al.A positive-temper-ature-coefficient electrode with thermalcut-off mecha-nism for use in rechargeable lithium batteries[J].Electrochemistry Communications,2004,6:1021-1024. [13]Feng J K,Sun X J,Ai X P,et al.Dimethyl methyl phosphate:A new nonflammable electrolyte solvent for lithium-ion batteries[J].Journal of Power Sources,2008,184:570-573. [14]Feng J K,Cao Y L,Ai X P,et al.Tri-(4-methoxyth-phenyl)phosphate:A new electrolyte additive with both fire-retardancy and overcharge protection for Li-ion batteries[J].Electrochimica Acta,2008,53:8265-8268.

[1]	左东旭, 李培超. 基于电化学-热-力耦合模型的快速充电下锂离子电池的老化特性分析[J]. 电化学（中英文）, 2024, 30(9): 2402061-.
[2]	陈露露, 李浩冉, 刘维祎, 王伟. 锂离子电池正极材料原位漫反射光谱电化学研究[J]. 电化学（中英文）, 2024, 30(6): 2314006-.
[3]	赵刚, 龚正良, 李益孝, 杨勇. 氧化钨和磷钨酸对LiNi_0.96Co_0.02Mn_0.02O₂材料的表面包覆改性研究[J]. 电化学（中英文）, 2023, 29(10): 2204281-.
[4]	陈思, 郑淞生, 郑雷铭, 张叶涵, 王兆林. 水热法制备锂电池Si@C负极材料的工艺优化研究[J]. 电化学（中英文）, 2022, 28(8): 2112221-.
[5]	王京玥, 王睿, 王诗琦, 王立帆, 詹纯. 一步固相法合成锂离子电池高镍层状正极材料[J]. 电化学（中英文）, 2022, 28(8): 2112131-.
[6]	谯渭川, 李芳儒, 肖瑾林, 屈丽娟, 赵晓, 张梦, 庞春雷, 李子坤, 任建国, 贺雪琴. 硅氧材料的膨胀性能研究和改善[J]. 电化学（中英文）, 2022, 28(5): 2108121-.
[7]	王加义, 郭胜楠, 王新, 谷林, 苏东. 锂离子电池高镍层状氧化物正极结构失效机制[J]. 电化学（中英文）, 2022, 28(2): 2108431-.
[8]	郭瑞琪, 吴锋, 王欣然, 白莹, 吴川. 多电子反应材料推动高能量密度电池发展：材料与体系创新[J]. 电化学（中英文）, 2022, 28(12): 2219011-.
[9]	朱振威, 邱景义, 王莉, 曹高萍, 何向明, 王京, 张浩. 人工智能在锂离子电池研发中的应用[J]. 电化学（中英文）, 2022, 28(12): 2219003-.
[10]	侯廷政, 陈翔, 蒋璐, 唐城. 当前和下一代锂离子电池电解液的原子尺度微观认识和研究进展[J]. 电化学（中英文）, 2022, 28(11): 2219007-.
[11]	李丹丹, 纪翔宇, 陈明, 杨燕茹, 王晓东, 冯光. 低聚离子液体的体相与界面及其电化学储能应用[J]. 电化学（中英文）, 2022, 28(11): 2219002-.
[12]	骆晨旭, 师晨光, 余志远, 黄令, 孙世刚. 富锂锰基层状正极材料的合成及其首周过充下的结构演化[J]. 电化学（中英文）, 2022, 28(1): 2006131-.
[13]	蔡雪凡, 孙升. 多孔电极电池的循环伏安法模拟[J]. 电化学（中英文）, 2021, 27(6): 646-657.
[14]	彭依, 张伟, 左防震, 吕浩莹, 洪凯骏. 二硒化钼纳米球储锂和储镁的性能和机理研究[J]. 电化学（中英文）, 2021, 27(4): 456-464.
[15]	周莉, 吴勰, 薛照明. 热塑性聚氨酯基聚合物电解质的制备与表征[J]. 电化学（中英文）, 2021, 27(4): 439-448.

高比能电池新材料与安全性新技术的研究进展 Ⅰ.锂离子电池自激发安全保护机制

Self-activating Safety Mechanisms for Li-ion Batteries

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics