三维多级孔类石墨烯载三氧化二铁锂离子电池负极材料

doi:10.13208/j.electrochem.140913

电化学（中英文） ›› 2015, Vol. 21 ›› Issue (1): 66-71. doi: 10.13208/j.electrochem.140913

三维多级孔类石墨烯载三氧化二铁锂离子电池负极材料

张勤伟，李运勇，沈培康^*

中山大学光电材料与技术国家重点实验室，物理科学与工程技术学院，广东广州510275

收稿日期:2014-09-12 修回日期:2014-11-13 出版日期:2015-02-28 发布日期:2014-11-18
通讯作者: 沈培康 E-mail:stsspk@mail.sysu.edu.cn
基金资助:
国家自然科学基金项目（No. 21073241，No. 51210002）资助

Nanosized Fe₂O₃ on Three Dimensional Hierarchical Porous Graphene-Like Matrices as High-Performance Anode Material for Lithium Ion Batteries

ZHANG Qin-wei, LI Yun-yong, SHEN Pei-kang^*

State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-sen University, Guangzhou 510275, China

Received:2014-09-12 Revised:2014-11-13 Published:2015-02-28 Online:2014-11-18
Contact: SHEN Pei-kang E-mail:stsspk@mail.sysu.edu.cn

摘要/Abstract

摘要： 采用简单的水解、热处理方法合成三氧化二铁（Fe₂O₃）负载在三维多级孔类石墨烯（3D HPG）上的复合材料. 3D HPG有效的导电网络有利于负载纳米Fe₂O₃，使其呈均匀分散状态，并有效增强纳米复合物的导电率，提高Fe₂O₃利用率，抑制纳米Fe₂O₃的团聚，从而制得稳定、高性能的锂离子电池负极材料. Fe₂O₃-3D HPG电极在50 mA·g^-1电流密度下首次放电容量达1745 mAh·g^-1，50周期放电容量保持于1095 mAh·g^-1.

关键词: Fe₂O₃, 负极材料, 锂离子电池, 三维多级孔类石墨烯材料, 电化学

Abstract: Ferric oxide (Fe₂O₃) as a promising anode material for lithium ion battery is due to its high theoretical capacity (1007 mAh·g^-1), earth abundance and low cost. The nanosized Fe₂O₃on the three dimensional hierarchical porous graphene-like network (denoted as Fe₂O₃-3D HPG) has been synthesized by homogeneous precipitation and heat treatment. The 3D HPG can provide a highly conductive structure in conjunction to support well contacted Fe₂O₃ nanoparticles, and effectively enhance the mechanical strength of the matrices during volume changes, as well as improve the utilization rate of Fe₂O₃ and suppress the aggregation of Fe₂O₃ nanoparticles during Li ion insertion/extraction. As a result, the first discharge capacity of Fe2O3-3D HPG was up to 1745 mAh·g^-1 at 50 mA·g^-1, and after 50 cycles, the retention of the capacity was 1095 mAh·g^-1.

Key words: Fe2O3, anode materials, Li ion batteries, three dimensional hierarchical porous graphene-like matrix, electrochemistry

中图分类号:

O646
TM912.9

张勤伟，李运勇，沈培康*. 三维多级孔类石墨烯载三氧化二铁锂离子电池负极材料[J]. 电化学（中英文）, 2015, 21(1): 66-71.

ZHANG Qin-wei, LI Yun-yong, SHEN Pei-kang*. Nanosized Fe₂O₃ on Three Dimensional Hierarchical Porous Graphene-Like Matrices as High-Performance Anode Material for Lithium Ion Batteries[J]. Journal of Electrochemistry, 2015, 21(1): 66-71.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.140913

https://electrochem.xmu.edu.cn/CN/Y2015/V21/I1/66

参考文献

[1] Tarascon J M, Armand M. Issues and challenges facing rechargeable lithium batteries[J]. Nature, 2001, 414(6861): 359-367.
[2] Zhu X, Zhu Y, Murali S, et al. Nanostructured reduced graphene oxide/Fe2O3 composite as a high-performance anode material for lithium ion batteries[J]. ACS Nano, 2011, 5(4): 3333-3338.
[3] Buqa H, Goers D, Holzapfel M, et al. High rate capability of graphite negative electrodes for lithium-ion batteries[J]. Journal of The Electrochemical Society, 2005, 152(2): A474-A481.
[4] Aricò A S, Bruce P, Scrosati B, et al. Nanostructured materials for advanced energy conversion and storage devices[J]. Nature materials, 2005, 4(5): 366-377.
[5] Jang B, Park M, Chae O B, et al. Direct synthesis of self-assembled ferrite/carbon hybrid nanosheets for high performance lithium-ion battery anodes[J]. Journal of the American Chemical Society, 2012, 134(36): 15010-15015.
[6] Kwon K A, Lim H S, Sun Y K, et al. α-Fe2O3 submicron spheres with hollow and macroporous structures as high-performance anode materials for lithium ion batteries[J]. The Journal of Physical Chemistry C, 2014, 118(6): 2897-2907.
[7] Zhao B, Liu R, Cai X, et al. Nanorod-like Fe2O3/graphene composite as a high-performance anode material for lithium ion batteries[J]. Journal of Applied Electrochemistry 2014, 44(1): 53-60.
[8] Luo J, Liu J, Zeng Z, et al. Three-dimensional graphene foam supported Fe3O4 lithium battery anodes with long cycle life and high rate capability[J]. Nano letters, 2013, 13(12): 6136-6143.
[9] He C, Wu S, Zhao N, et al. Carbon-encapsulated Fe3O4 nanoparticles as a high-rate lithium ion battery anode material[J]. ACS Nano, 2013, 7(5): 4459-4469.
[10] Y Li, Q Zhang, Zhu J, et al. An extremely stable MnO2 anode incorporated with 3D porous graphene-like networks for lithium-ion batteries[J]. Journal of Materials Chemistry A, 2014, 2(9): 3163-3168.
[11] C X Guo, M Wang, Chen T, et al. A hierarchically nanostructured composite of MnO2/conjugated polymer/graphene for high-performance lithium ion batteries[J]. Advanced Energy Materials, 2011, 1(5): 736-741.
[12] Wu Z S, Ren W, Wen L, et al. Graphene anchored with Co3O4 nanoparticles as anode of lithium ion batteries with enhanced reversible capacity and cyclic performance[J]. ACS Nano, 2010, 4(6): 3187-3194.
[13] Tao L, Zai J, Wang, K, et al. Co3O4 nanorods/graphene nanosheets nanocomposites for lithium ion batteries with improved reversible capacity and cycle stability[J]. Journal of Power Sources, 2012, 202: 230-235.
[14]Wang Y, Xu M, Peng Z, et al. Direct growth of mesoporous Sn-doped TiO2 thin films on conducting substrates for lithium-ion battery anodes[J]. Journal of Materials Chemistry A, 2013, 1(42): 13222-13226.
[15] Ren Y, Liu Z, Pourpoint F, et al. Nanoparticulate TiO2(B): An anode for lithium-ion batteries[J]. Angewandte Chemie-International Edition, 2012, 124(9): 2206-2209.
[16] Wu H B, Chen J S, Hng H H, et al. Nanostructured metal oxide-based materials as advanced anodes for lithium-ion batteries[J]. Nanoscale, 2012, 4(8): 2526-2542.
[17] Sun Y, Zhang J, Huang T, et al. Fe2O3/CNTs composites as anode materials for lithium-ion batteries[J]. International Journal of Electrochemical Science, 2013, 8(2): 2918-2931.
[18] Chen J, Xu L, Li W, et al. α-Fe2O3 nanotubes in gas sensor and lithium-ion battery applications[J]. Advanced Materials, 2005, 17(5): 582-586.
[19] Reddy M, Yu T, Sow C H, et al. α-Fe2O3 nanoflakes as an anode material for Li-ion batteries[J]. Advanced Functional Materials, 2007, 17(15): 2792-2799.
[20] Wu H, Xu M, Wang Y, et al. Branched Co3O4/Fe2O3 nanowires as high capacity lithium-ion battery anodes[J]. Nano Research, 2013, 6(3): 167-173.
[21] Brandt A, Balducci A. Ferrocene as precursor for carbon-coated α-Fe2O3 nanoparticles for rechargeable lithium batteries[J]. Journal of Power Sources, 2013, 230: 44-49.
[22] Fei H, Peng Z, Li L, et al. Preparation of carbon-coated iron oxide nanoparticles dispersed on graphene sheets and applications as advanced anode materials for lithium-ion batteries[J]. Nano Research, 2014, 7(4): 1-9.
[23] Li Y, Li Z, Shen P K. Simultaneous formation of ultrahigh surface area and three-dimensional hierarchical porous grapheme-like networks for fast and highly stable supercapacitors[J]. Advanced Materials, 2013, 25(17): 2474-2480.
[24] Zhang M, Qu B, Lei D, et al. A green and fast strategy for the scalable synthesis of Fe2O3/graphene with significantly enhanced Li-ion storage properties[J]. Journal of Materials Chemistry, 2012, 22(9): 3868-3874.
[25] Ang W A, Gupta N, Prasanth R, et al. Facile synthesis and electrochemical properties of alpha-phase ferric oxide hematite cocoons and rods as high-performance anodes for lithium-ion batteries[J]. Journal of Materials Research, 2013, 28(6): 824-831.
[26] Reddy M V, Subba R G V, Chowdari B V R, et al. Metal oxides and oxysalts as anode materials for Li ion batteries[J]. Chemical Reviews, 2013, 113(7): 5364-5457.
[27] Su L, Zhou Z, Qin X, et al. CoCO3 submicrocube/graphene composites with high lithium storage capability[J]. Nano Energy, 2013, 2(2): 276-282.
[28] Su L, Zhong Y, Zhen Z, et al. Role of transition metal nanoparticles in the extra lithium storage capacity of transition metal oxides: A case study of hierarchical core-shell Fe3O4@C and Fe@C microspheres[J]. Journal of Materials Chemistry A, 2013, 1(47): 15158-15166.
[29] Yin J, Shi H, Wu P, et al. Graphene-wrapped single-crystalline Fe3O4 nanorods with superior lithium-storage capabilities[J]. New Journal of Chemistry, 2014, 38(9): 4036-4040.

三维多级孔类石墨烯载三氧化二铁锂离子电池负极材料

Nanosized Fe₂O₃ on Three Dimensional Hierarchical Porous Graphene-Like Matrices as High-Performance Anode Material for Lithium Ion Batteries

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三维多级孔类石墨烯载三氧化二铁锂离子电池负极材料

Nanosized Fe2O3 on Three Dimensional Hierarchical Porous Graphene-Like Matrices as High-Performance Anode Material for Lithium Ion Batteries

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Nanosized Fe₂O₃ on Three Dimensional Hierarchical Porous Graphene-Like Matrices as High-Performance Anode Material for Lithium Ion Batteries