富锂Li1.23Ni0.09Co0.12Mn0.56O2材料的水溶-蒸发法合成及其初始1.5周充放电过程的原位XRD研究

doi:10.13208/j.electrochem.130359

电化学（中英文） ›› 2013, Vol. 19 ›› Issue (6): 537-543. doi: 10.13208/j.electrochem.130359

• 锂离子电池近期研究专辑 (厦门大学杨勇教授主编) • 上一篇下一篇

富锂Li_1.23Ni_0.09Co_0.12Mn_0.56O₂材料的水溶-蒸发法合成及其初始1.5周充放电过程的原位XRD研究

沈重亨¹，沈守宇¹，林舟¹，郑小美¹，苏航¹，黄令^1*，李君涛²，孙世刚¹

1. 厦门大学化学化工学院化学系，福建厦门 361005；2. 厦门大学能源研究院，福建厦门 361005

收稿日期:2013-05-31 修回日期:2013-07-01 出版日期:2013-12-28 发布日期:2013-12-23
通讯作者: 黄令 E-mail:huangl@xmu.edu.cn
基金资助:
国家自然科学基金（No. 21273184）、科技部863（No. 2011AA11A254）和973（No. 2009CB220102）项目资助

Aqueous Solution-Evaporation Route Synthesis and Phase Structural Research of the Li-Rich Cathode Li_1.23Ni_0.09Co_0.12Mn_0.56O₂ by In-Situ XRD

SHEN Chong-Heng¹, SHEN Shou-Yu¹, LIN Zhou¹, ZHENG Xiao-Mei¹, SU Hang1, HUANG Ling^1*, LI Jun-Tao², SUN Shi-Gang¹

1. Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Fujian Xiamen 361005; 2. School of Energy Research, Xiamen University, Fujian Xiamen 361005

Received:2013-05-31 Revised:2013-07-01 Published:2013-12-28 Online:2013-12-23
Contact: HUANG Ling E-mail:huangl@xmu.edu.cn

摘要/Abstract

摘要： 采用水溶-蒸发法成功合成了锂离子电池Li_1.23Ni_0.09Co_0.12Mn_0.56O₂正极材料. 通过扫面电镜(SEM)、非原位XRD、原位XRD观察材料形貌表征材料结构，并测试电极电化学性能. 结果显示，材料为粒径330 nm的多边形结构，是层状的固溶体—Li₂MnO₃结构，该正极0.1C首周期放电比容量250.8 mAh·g^-1，40周期循环容量保持率86.5%. 通过原位XRD可确证电极在首周期充放电过程产生少量Li_0.9MnO₂新相，在其后多周期循环过程电极层状结构趋于向尖晶石结构发生转变致使电极电化学性能恶化. 此外，晶格参数c首周期充电过程先增后减在4.54 V左右保持稳定，放电与第2周期充电过程其值逐渐下降；晶格参数a则经历了下降平稳再升高的过程，该数值的变化均对应于相应电化学行为.

关键词: 锂离子电池, 正极, 水溶-蒸发法, 原位XRD, 结构转变

Abstract: The Li-rich Li_1.23Ni_0.09Co_0.12Mn_0.56O₂material was synthesized via aqueous solution-evaporation route. The structure and morphology of the material were characterized by means of XRD and SEM. The results indicated that the single particle of the product was polygonal with the size of 330 nm and the structure was layered solid solution with a certain amount of Li₂MnO₃. Electrochemical tests showed that the first discharge capacity of the Li-rich layered material was 250.8 mAh·g^-1 at 0.1C，the capacity retention was 86.5% after 40 cycles. Through in-situ XRD study a new phase Li_0.9MnO₂ which would cause electrochemical properties deteriorated due to its structure transformation from layered to spinel came out with a small amount during the first charge-discharge cycle. Moreover, the value of c-parameter increased first and decreased before 4.54 V, and remained stable till the end of the first charge, and then reduced from the first discharge to the second charge continually. However, the value of a-parameter underwent a falling-steady-rising course. The change in the values of the lattice parameters corresponded to the variation of electrochemical behaviors.

Key words: Li-ion battery, cathode, aqueous solution-evaporation route, in-situ XRD, structure transformation

中图分类号:

TM912.9

沈重亨，沈守宇，林舟，郑小美，苏航，黄令*，李君涛，孙世刚. 富锂Li_1.23Ni_0.09Co_0.12Mn_0.56O₂材料的水溶-蒸发法合成及其初始1.5周充放电过程的原位XRD研究[J]. 电化学（中英文）, 2013, 19(6): 537-543.

SHEN Chong-Heng, SHEN Shou-Yu, LIN Zhou, ZHENG Xiao-Mei, SU Hang, HUANG Ling*, LI Jun-Tao, SUN Shi-Gang. Aqueous Solution-Evaporation Route Synthesis and Phase Structural Research of the Li-Rich Cathode Li_1.23Ni_0.09Co_0.12Mn_0.56O₂ by In-Situ XRD[J]. Journal of Electrochemistry, 2013, 19(6): 537-543.

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https://electrochem.xmu.edu.cn/CN/Y2013/V19/I6/537

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富锂Li_1.23Ni_0.09Co_0.12Mn_0.56O₂材料的水溶-蒸发法合成及其初始1.5周充放电过程的原位XRD研究

Aqueous Solution-Evaporation Route Synthesis and Phase Structural Research of the Li-Rich Cathode Li_1.23Ni_0.09Co_0.12Mn_0.56O₂ by In-Situ XRD

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