芦丁碳纳米管修饰玻碳电极电催化氧化肼的研究

doi:10.61558/2993-074X.2080

电化学（中英文） ›› 2011, Vol. 17 ›› Issue (1): 107-111. doi: 10.61558/2993-074X.2080

芦丁碳纳米管修饰玻碳电极电催化氧化肼的研究

张宏芳;盛庆林;郑建斌;

西北大学化学与材料科学学院合成与天然功能分子化学教育部重点实验室;西北大学分析科学研究所;

收稿日期:2011-02-28 修回日期:2011-02-28 出版日期:2011-02-28 发布日期:2011-02-28

Electrocatalytic Oxidation of Hydrazine at Rutin Carbon Nanotubes Modified Electrode

ZHANG Hong-fang1,SHENG Qing-lin2,ZHENG Jian-bin2

(1.Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry & materials Science,Northwest University,Xi'an 710069,China; 2.Institute of Analytical Science,Northwest University,Xi'an 710069,China

Received:2011-02-28 Revised:2011-02-28 Published:2011-02-28 Online:2011-02-28

摘要/Abstract

摘要： 应用循环伏安法研究了芦丁碳纳米管修饰玻碳电极(Rt-MWNT/GC)的电化学行为及其对肼的电催化氧化.实验表明,该修饰电极能使肼的氧化电位降至260 mV附近,表现出良好的电催化作用.安培法测得催化电流与肼浓度在2.5×10-6～1.0×10-4 mol·L-1范围内呈线性关系,检出限5×10-7 mol.L-1.

关键词: 电分析, 电催化, 碳纳米管, 芦丁, 肼

Abstract: The electrochemical behavior and electrocatalytic oxidation of hydrazine on rutin multiwall carbon nanotubes modified glassy carbon electrode were studied by cyclic voltammetry.The experimental results indicated that the electrode exhibits good electrocatalytic activity to hydrazine at a reduced oxidation potential of 262 mV.The amperometric response of the modified electrode showed linear increase after successive addition of hydrazine in the concentration range of 2.5×10-6~1.0×10-4 mol·L-1 with a detection limit of 5×10-7 mol·L-1.

Key words: electroanalysis, electrocatalysis, carbon nanotubes, rutin, hydrazine

中图分类号:

O657.1

张宏芳, 盛庆林, 郑建斌, . 芦丁碳纳米管修饰玻碳电极电催化氧化肼的研究[J]. 电化学（中英文）, 2011, 17(1): 107-111.

ZHANG Hong-fang, SHENG Qing-lin, ZHENG Jian-bin. Electrocatalytic Oxidation of Hydrazine at Rutin Carbon Nanotubes Modified Electrode[J]. Journal of Electrochemistry, 2011, 17(1): 107-111.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.61558/2993-074X.2080

https://electrochem.xmu.edu.cn/CN/Y2011/V17/I1/107

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芦丁碳纳米管修饰玻碳电极电催化氧化肼的研究

Electrocatalytic Oxidation of Hydrazine at Rutin Carbon Nanotubes Modified Electrode

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