氧化铁镍电极上析氧反应的电化学研究(英文)

电化学（中英文） ›› 2006, Vol. 12 ›› Issue (2): 154-158.

氧化铁镍电极上析氧反应的电化学研究(英文)

黄金昭;徐征;李海玲;亢国虎;王文静;

北京交通大学发光与光信息技术教育部重点实验室,北京交通大学发光与光信息技术教育部重点实验室,北京市太阳能研究所,北京市太阳能研究所,北京市太阳能研究所北京100044,北京100044,北京100083,北京100083,北京100083

收稿日期:2006-05-28 修回日期:2006-05-28 出版日期:2006-05-28 发布日期:2006-05-28

Electrochemical Studies of Iron-doped Nickel Oxide Electrode for Oxygen Evolution Reaction

HUANG Jin-zhao1,XUZheng*1,LI Hai-ling2,KANG Guo-hu2,WANG Wen-jing2

(1.Key Laboratory ofLuminescence and Optical Information,Ministry ofEducation,Institute ofoptoelectronic technology,Beijing jiaotong university,Beijing100044,China,2.Beijing solar energy research institute,Beijing100083,China

Received:2006-05-28 Revised:2006-05-28 Published:2006-05-28 Online:2006-05-28

摘要/Abstract

摘要： 应用射频反应磁控溅射法制备阳极催化氧化铁镍薄膜,由循环伏安、线性扫描伏安、极化曲线和电化学交流阻抗谱等研究发生在该电极上的氧化反应.结果表明,作为活化中心的铁能使过电势降低,并且随着溅射过程氧流量的增加催化性能增强,铁的掺入使得速率限定步骤由OH-的释放变为氧原子的结合.与镍相比,氧化铁镍是更理想的催化阳极材料,当电流密度为50 mA/cm2时,其氧的过电势比镍的下降了500 mV.

关键词: 氧化铁镍, 电催化

Abstract: In this paper,the iron-doped nickel oxide thin film as anode catalyst was prepared by RF reactivesputtering method.The oxygen evolution reaction(OER) on the iron-doped nickel oxide was investigated withcyclic voltammetry,liner sweep voltammetry,polarization curves and electrochemical impedance spectroscopy.Results showthat the iron acts as active site in the film which makes the overpotential lower,and changes therate-limiting from primary discharge of OH-ions to the recombination of oxygen atom.With the increasing of ox-ygen content in flu ratio during sputtering,the electrocatalytic activities of the film increase.Iron-doped nickeloxide thin film is promising material as OER electrocatalyst for hydrogen production than the nickel electrode.The oxygen overpotential on the film was over 500 mV lower than the overpotential with nickel at50mA/cm2.

Key words: Iron-doped nickel oxide, Electrocatalytic

中图分类号:

O646.54

黄金昭;徐征;李海玲;亢国虎;王文静;. 氧化铁镍电极上析氧反应的电化学研究(英文)[J]. 电化学（中英文）, 2006, 12(2): 154-158.

HUANG Jin-zhao1,XUZheng*1,LI Hai-ling2,KANG Guo-hu2,WANG Wen-jing2. Electrochemical Studies of Iron-doped Nickel Oxide Electrode for Oxygen Evolution Reaction[J]. Journal of Electrochemistry, 2006, 12(2): 154-158.

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链接本文: https://electrochem.xmu.edu.cn/CN/

https://electrochem.xmu.edu.cn/CN/Y2006/V12/I2/154

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