锂离子电池电解液的研究进展(英文)

摘要/Abstract

摘要： 综述现今锂离子电池电解液的研究进展 .评估了电解液中锂盐、溶剂、填加剂以及杂质等对电解液的电导、固体电解质相界面 (SEI)的形成、电池循环寿命等的影响

Abstract: We present a reviewed the development and status of electrolyte for LiC 6/electrolyte/cathode battery. The effect of the salt, solvent, additive and impurity on the conductivity of the electrolyte, formation of the solid_electrolyte_interphase (SEI) and cycle life of the battery were described.

Key words: electrolyte, lithium_ion Battery, SEI, conductivity

中图分类号:

TM911

王翠英 ,赵胜亮 ,朱光明 ,尤金跨 ,林祖赓. 锂离子电池电解液的研究进展(英文)[J]. 电化学（中英文）, 2002, 8(2): 125-133.

WANG Cui_ying,ZHAO Sheng_liang *,ZHU Guang_ming, YOU Jin_kua,LIN Zu_geng . Recent developments in the electrolyte for LiC _6/electrolyte/cathode battery[J]. Journal of Electrochemistry, 2002, 8(2): 125-133.

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链接本文: https://electrochem.xmu.edu.cn/CN/

https://electrochem.xmu.edu.cn/CN/Y2002/V8/I2/125

参考文献

[1]　D .FauteuxandR .koksbangmRechargeablelithiumbatteryanodes:alternativestometalliclithium[J].JournalofPowerSources,1993,23. [2]　HeiderU ,OestenR ,JungnitzM .Challengeinmanufacturingelectrolytesolutionsforlithiumandlithiumionbatteriesqualitycontrolandminimizingcontaminationlevel[J].J .PowerSources,1999:81～82,119. [3]　RitchieAG .Recentdevelopmentsandfutureprospectsforlithiumrechargeablebatteries[J].J.powersources,2001,96:1～4. [4]　PlichtaEJ ,BehlWK .Alow_temperatureelectrolyteforlithiumandlithium_ionbatteries[J].J .PowerSources,2000,88:192. [5]　YukioSasaki,NamoruHosoya,MinoruHanda.Lithiumcyclingefficiencyofternarysolventelectrolyteswithethylenecarbonate_dimethylcarbonatemixture[J].J.powersources,1997,68:492 [6]　HerreyreS ,HuchetO ,BarusseayS .NewLiionelectrolytesforLowtemperatureapplications[C].In:Pro ceedingsofthe10thinternationalmeetingonlithiumbatteries,Lithium2000.Como,May2000,Abstractno,282. [7]　MoritaM ,IshikawaM ,MatsudaY .Organicelectrolytesforrechargeablelithiumionbatteries[M ].In:M .Wakihara,O .Yamamoto(Eds.),LithiumIonBatteries,Kodansha,Tokyo:Wiley/VCH ,Weiheim,1998.156. [8]　QiyiXing.BasalOrganicChemistry[M ].Beijing:AdvancedEducationPress,2000.6. [9]　McbreenJ,LeeHS ,YangXQ ,SunX .Newapproachestothedesignofpolymerandliquidelectrolytesforlithiumbatteries[J].J .PowerSources,2000,89:163. [10]　ChusidO ,GoferY ,AurbachD ,etal.StudiesoftheinterfacebetweenlithiumelectrodesandpolymericelectrolytesystemsusinginsituFTIRspectroscopy[J].JournalofPowerSources,2001,97～98:632. [11]　AurbachD ,Ein_EliY ,ChusidO .ThecorrelationbetweenthesurfacechemistryandtheperformanceofLi_carbonintercalationanodesforrechargeable”rockingchair”typebatteries[J].J .Electrochemistry.Soc,1994,141:603. [12]　PeledE .InlithiumBatteries[M ](EditedbyJ .P .Gaobano)chap.3.NewYork:AcademicPress,1993. [13]　Yamaki,Jun_ichi,Tobishima,Shin_ichi,etal.Aconsiderationofthemorphologyofelectrochemicallyde positedlithiuminanorganicelectrolyte[J]..JournalofPowerSources,1998,74:219. [14]　DeyAN ,SullivanBP .Theelectrochemicaldecompositionofpropylenecarbonateongraphite[J].J.Elec trochem.Soc.,1970,117:222. [15]　SaitoK ,ArakawaM ,TobishimaS ,YamakiJ .Specificsurface_areameasurementoflithiumanodeinrechargeablelithiumcells[J].JournalofPowerSources,1998,72:111. [16]　NajiA ,GhanbajaJ,WillmannP .ThereareseveralmethodsreportedtoimprovethebatteryperformancewithPCbasedelectrolyte[J].Carbon,1997,35:845. [17]　NajiA ,GhanbajaJ ,WillmannP ,BillaudD .Newhalogenatedadditivestopropylenecarbonatebasedelec trolytesforlithium_ionbatteries[J].ElectrochimcaActa,2000,45:1893～1899. [18]　YEin_Eli,SRThomas.NewelectrolytesystemforLi_ionbattery[J].J ..Electrochem.Soc.,1996,143:L195. [19]　NajiA ,GhanbajaJ ,WillmannP ,BillaudD .Newhalogenatedadditivestopropylenecarbonatebasedelec trolytesforlithium_ionbatteries[J].ElectrochimcaActa,2000,45:1893. [20]　ChungGeun_Chang,KimHyung_jin.OriginofGraphiteExfoliation:AnInvestigationoftheImportantRoleofSolventCointercalation[J].J .electrochemicalSociety,2000,147(12):4391. [21]　ChungGeun_Chang,JinKimHyeong,JunSongHui.Newcycliccarbonatesolventforlithiumionbatteries:trans_2,3_butylenecarbonate[J].Electrochem.Comm,1999,1:493～496. [22]　YairEin_Eli,BorisMarkovsky,DoronAurbach.ThedependenceoftheperformanceofLi_CintercalationanodesforLi_ionsecondarybatteriesontheelectrolytesolutioncomposition[J].ElectrochimcaActa,1990,39(17):2559. [23]　AurbachD ,MarkowskyB ,SchechterA ,Ein_EliY .AcomparativestudyofsyntheticgraphiteandLielec trodesonelectrolytesolutionsbasedonethylenecarbonate_dimethylcarbonatemixtures[J].J.Electrochem.Soc.,1996,143:3809.. [24]　HeiderU ,OestenR ,JungnitzM .Challengeinmanufacturingelectrolytesolutionsforlithiumandlithiumionbatteriesqualitycontrolandminimizingcontaminationlevel[J].J .PowerSources,1999,81～82:119～122. [25]　AurbachD ,ZabanA ,Ein_EliY .ThestudyofelectrolytesolutionsbasedonethyleneanddiethylcarbonatesforrechargeableLibatteries[J].J .Elelctrochem.Soc.,1995,142:2873. [26]　AurbachD ,GottliebHE .Theelectrochemicalbehaviorofselectedpolaraproticsystem[J].ElectrochemActa,1989,34:141. [27]　AurbachD ,GoferY ,Ben_ZionM .Thebehavioroflithiumelectrodesinpropyleneandethylenecarbonate:themajorfactorsinfluenceLicyclingefficiency[J].J.Electroanal.Chem.,1992,339:451. [28]　HeiderU ,OestenR ,JungnitzM .Challengeinmanufacturingelectrolytesolutionsforlithiumandlithiumionbatteriesqualitycontrolandminimizingcontaminationlevel[J].J .PowerSources,1999,81～82:119～122. [29]　FelixJoho,BeatRykart,RomanImhof.Keyfactorsforthecyclingstabilityofgraphiteintercalationelec trodesforlithium_ionbatteries[J].J .PowerSources,1999,81～82:243～247.LiC6/electrolyte/Lisys tem. [30]　M interKC ,HodalT ,AppelWK ,WinterM .,BesenhardJO .Fluorinatedorganicsolventsinelec trolytesforlithiumioncells[J].JournalofPowerSources.Adv.Mater.,2001,97～98:595. [31]　WinterM ,NovakP .Graphitesforlithium_ioncells:thecorrelatinofthefirst_cycleschargelosswiththeBrunauer_Emmett_Tellersurfacearea[J].J .Electrochem.Soc,1998,145:428