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电化学(中英文) ›› 1998, Vol. 4 ›› Issue (4): 365-371. 

• 研究论文 • 上一篇    下一篇

锂离子电池阴极材料尖晶石结构Li_(1+x)Mn_(2-x)O_4的研究

  

  • 收稿日期:1998-11-28 修回日期:1998-11-28 出版日期:1998-11-28 发布日期:1998-11-28

Studies of Spinal Li 1+x Mn 2-x O 4 Rechargeable Lithium Ion Battery

Wu Xiaomei * Yang Qinghe Jin Zhongkao Wu Haoqing Zong Xiangfu   

  1. (Inst. of Material Sci., Fudan Univ., Shanghai, China 200433
  • Received:1998-11-28 Revised:1998-11-28 Published:1998-11-28 Online:1998-11-28

摘要: 本文报导尖晶石结构阴极材料Li1+xMn2-xO4(O<x<1)的制备方法,讨论温度及原料对合成材料的电化学特性的影响,用电化学及结构化学理论研究了化学计量尖晶石结构LiMn2O4中,过量锂占据晶格中锰的位置,对电池初始容量及循环寿命产生的影响.

关键词: 锂离子电池, 尖晶石结构

Abstract: The spinel Li intercalation compound Li 1+ x Mn 2- x O 4(0< x <1) was prepared by using techniques of cyclic voltammetry. The electrochemical parameters of Li 1+ x Mn 2- x O 4 electrode vary as either the starting materials or the synthesis temperature changes. It was found that the initial capacity and reversible behaviors of the Li 1+ x Mn 2- x O 4 electrode depends on the amount of the excess Li, represented as x in Li 1+ x Mn 2- x O 4. The reversible of Li intercalation process for Li 1+ x Mn 2- x O 4 electrode was demonstrate by cyclic voltammograms.

Key words: Lithium on battery, Spinel, Initial capacity

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