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电化学(中英文) ›› 2013, Vol. 19 ›› Issue (5): 437-443.  doi: 10.61558/2993-074X.2134

• 环境电化学近期研究专辑(吉林大学 林海波教授主编) • 上一篇    下一篇

结合(光)电化学方法研究光催化降解污染物反应

冷文华*,朱红乔   

  1. 浙江大学玉泉校区化学系,浙江 杭州 310027
  • 收稿日期:2012-12-25 修回日期:2013-03-18 出版日期:2013-10-28 发布日期:2013-03-18
  • 通讯作者: 冷文华 E-mail:lengwh@zju.edu.cn
  • 基金资助:

    国家自然科学基金项目(No. 50971116)和国家基础研究计划(No. 2011CB936003)资助

An Investigation of Photocatalytic Degradation Reactions of Pollutants by Combination of (Photo)electrochemical Measurements

LENG Wen-hua*, ZHU Hong-qiao   

  1. Department of Chemistry, Zhejiang University, Hangzhou 310027, China
  • Received:2012-12-25 Revised:2013-03-18 Published:2013-10-28 Online:2013-03-18
  • Contact: LENG Wen-hua E-mail:lengwh@zju.edu.cn

摘要: 半导体光催化在环境保护和未来新能源开发等领域中具有重要的作用和意义. 由于参与光催化反应的主体是光生载流子,并涉及光生电子和空穴的界面转移与复合,(光)电化学方法是研究光催化反应微观动力学和机理的重要手段. 本文主要介绍本课题组应用这类研究方法在液相光催化去污方面所获得的部分研究结果,并对今后研究重点提出了某些看法.

关键词: 光催化, 反应动力学和机理, 电化学阻抗谱, 光电化学

Abstract: Semiconductor photocatalysis plays a critical role in the environment protection and future energy development. (Photo)electrochemical measurements are powerful tools for studying the kinetics and mechanism of photocatalytic reactions, since photo-carriers, as reactants of photocatalytic reactions, are involved in the interfacial transfer and recombination of semiconductor/electrolyte interface. This review describes the part of our recent results regarding aqueous photocatalytic decontamination obtained by these methods, and the focus of future work in this field is suggested.

Key words: photocatalysis, reaction kinetics and mechanism, electrochemical impedance spectroscopy, photoelectrochemistry

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