单分散球形纳米Fe3O4的可控合成和嵌锂性质研究

doi:10.13208/j.electrochem.130360

电化学（中英文） ›› 2013, Vol. 19 ›› Issue (6): 590-594. doi: 10.13208/j.electrochem.130360

• 锂离子电池近期研究专辑 (厦门大学杨勇教授主编) • 上一篇下一篇

单分散球形纳米Fe₃O₄的可控合成和嵌锂性质研究

邹红丽^*，李伟善

华南师范大学电化学储能材料与技术教育部工程研究中心，化学与环境学院，广州，510006

收稿日期:2013-06-21 修回日期:2013-07-15 出版日期:2013-12-28 发布日期:2013-12-23
通讯作者: 邹红丽 E-mail:zouhli@163.com
基金资助:
国家自然科学基金项目(No. U1134002)资助

Controllable Synthesis of Dispersed Spherical Fe₃O₄ Nanoparticles as Lithium-Inserted Materials

ZOU Hong-li^*, LI Wei-shan

Engineering Research Center of Materials and Technology for Electrochemical Energy Storage (Ministry of Education), School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China

Received:2013-06-21 Revised:2013-07-15 Published:2013-12-28 Online:2013-12-23
Contact: ZOU Hong-li E-mail:zouhli@163.com

摘要/Abstract

摘要： 利用水热法合成出分散的球形纳米Fe₃O₄，探讨含十二烷基三甲基溴化铵表面活性剂合成样品形貌和尺寸. 测试表明Fe₃O₄纳米球呈现出优越的倍率性能和循环性能.

关键词: Fe₃O₄, 锂离子电池, 负极材料, 纳米粒子, 水热法

Abstract: Dispersed spherical Fe₃O₄ nanoparticles were synthesized by a hydrothermal method. The influences of odecyl trimethyl ammonium bromide (DTAB) concentration on the morphology and particle size of the as-prepared Fe₃O₄ were studied. Electrochemical performance of the as-prepared sample as anode materials of lithium ion battery was investigated. It is found that the as-prepared sample exhibits superior rate performance and cycle performance. The nano-sized materials provide structural stability and favor the transfer of lithium ions.

Key words: Fe₃O₄, lithium ion battery, anode, nanoparticles, hydrothermal

中图分类号:

O646
TM911

邹红丽*，李伟善. 单分散球形纳米Fe₃O₄的可控合成和嵌锂性质研究[J]. 电化学（中英文）, 2013, 19(6): 590-594.

ZOU Hong-li*, LI Wei-shan. Controllable Synthesis of Dispersed Spherical Fe₃O₄ Nanoparticles as Lithium-Inserted Materials[J]. Journal of Electrochemistry, 2013, 19(6): 590-594.

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.130360

https://electrochem.xmu.edu.cn/CN/Y2013/V19/I6/590

参考文献

[1] Cai J J(蔡俊杰), Yao S(姚姝)，Li Z S(李泽胜)，et al. Electrochemical performance of Fe3O4/C composites as negative material for lithium-ion batteries[J]. Journal of Electrochemistry(电化学), 2013, 19(1): 89-92.
[2] Zhang W M, Wu X L, Hu J S, et al. Carbon coated Fe3O4 nanospindles as a superior anode material for lithium-ion batteries[J]. Advanced Functional Material, 2008, 18:(24): 3941-3946.
[3] Lim H S, Jung B Y, Sun Y K, et al. Hollow Fe3O4 microspheres as anode materials for lithium-ion batteries[J]. Electrochimica Acta, 2012, 75: 123-130.
[4] Hao Q Y, Lei D N, Yin X M, et al. 3-D mesoporous nano/micro-structured Fe3O4/C as a superior anode material for lithium-ion batteries[J]. Journal of Solid State Electrochemistry, 2011, 15(11/12): 2563-2569.
[5] Iida H, Takayanagi K, Nakanishi T, et al. Synthesis of Fe3O4 nanoparticles with various sizes and magnetic properties by controlled hydrolysis[J]. Journal of Colloid Interface Science, 2007, 314(1): 274-280.
[6] Wang J, Deng T, Dai Y. Study on the processes and mechanism of the formation of Fe3O4 at low temperature[J]. Journal of Alloy Compound, 2005, 390(1/2): 127-132.
[7] Su D W, Horvat J, Munroe P, et al. Polyhedral magnetite nanocrystals with multiple facets: Facile synthesis, structural modelling, magnetic properties and application for high capacity lithium storage[J]. Chemistry-A European Journal, 2012, 18(2): 488-497.
[8] Gao G, Wu H X, Zhang Y X, et al. Synthesis of ultrasmal nucleotide-functionalized superparamagnetic γ-Fe2O3 nanoparticles[J]. CrystEngComm, 2011, 13(15): 4810-4813.
[9] Chen L Q, Yang X F, Chen J, et al. Continuous shape- and spectroscopy-tuning of hematite nanocrystals[J]. Inorganic Chemistry, 2010, 49(18): 8411-8420.
[10] Liu H, Wang G X, Wang J Z, et al. Magnetite/carbon core-shell nanorods as anode materials for lithium-ion batteries[J]. Electrochemistry Communination, 2008, 10(12): 1879-1882.
[11] Wang S Q, Zhang J Y, Chen C H. Fe3O4 submicron spheroids as anode materials for lithium-ion batteries with stable and high electrochemical performance[J]. Journal of Power Sources, 2010, 195(16): 5379-5381.
[12] Jin S L, Deng H G, Liu X J, et al. Facile synthesis of hierarchically structured Fe3O4/carbon micro-flowers and their application to lithium-ion battery anodes[J]. Journal of Power Sources, 2011, 196(8): 3887-3893.

[1]	李春艳, 张蕊, 巴笑杰, 姜晓乐, 阳耀月. 氮掺杂多孔碳包覆铁纳米粒子催化剂用于高效碱性介质中氧还原反应[J]. 电化学（中英文）, 2023, 29(5): 2210241-.
[2]	范佳琪, 宋焕巧, 安佳莹, 阿依达娜·阿曼太, 陈默. 碳限域Li₃VO₄纳米材料的制备及其储锂性能[J]. 电化学（中英文）, 2023, 29(11): 211203-.
[3]	殷秀平, 赵玉峰, 张久俊. 钠离子电池硬碳基负极材料的研究进展[J]. 电化学（中英文）, 2023, 29(10): 2204301-.
[4]	赵刚, 龚正良, 李益孝, 杨勇. 氧化钨和磷钨酸对LiNi_0.96Co_0.02Mn_0.02O₂材料的表面包覆改性研究[J]. 电化学（中英文）, 2023, 29(10): 2204281-.
[5]	陈思, 郑淞生, 郑雷铭, 张叶涵, 王兆林. 水热法制备锂电池Si@C负极材料的工艺优化研究[J]. 电化学（中英文）, 2022, 28(8): 2112221-.
[6]	王京玥, 王睿, 王诗琦, 王立帆, 詹纯. 一步固相法合成锂离子电池高镍层状正极材料[J]. 电化学（中英文）, 2022, 28(8): 2112131-.
[7]	谯渭川, 李芳儒, 肖瑾林, 屈丽娟, 赵晓, 张梦, 庞春雷, 李子坤, 任建国, 贺雪琴. 硅氧材料的膨胀性能研究和改善[J]. 电化学（中英文）, 2022, 28(5): 2108121-.
[8]	应方, 许珊珊, 许燕冰, 梁苗苗, 李剑锋. Fe₃O₄磁性纳米颗粒催化电化学降解土霉素的研究[J]. 电化学（中英文）, 2022, 28(4): 2107141-.
[9]	王加义, 郭胜楠, 王新, 谷林, 苏东. 锂离子电池高镍层状氧化物正极结构失效机制[J]. 电化学（中英文）, 2022, 28(2): 2108431-.
[10]	郭瑞琪, 吴锋, 王欣然, 白莹, 吴川. 多电子反应材料推动高能量密度电池发展：材料与体系创新[J]. 电化学（中英文）, 2022, 28(12): 2219011-.
[11]	朱振威, 邱景义, 王莉, 曹高萍, 何向明, 王京, 张浩. 人工智能在锂离子电池研发中的应用[J]. 电化学（中英文）, 2022, 28(12): 2219003-.
[12]	侯廷政, 陈翔, 蒋璐, 唐城. 当前和下一代锂离子电池电解液的原子尺度微观认识和研究进展[J]. 电化学（中英文）, 2022, 28(11): 2219007-.
[13]	李丹丹, 纪翔宇, 陈明, 杨燕茹, 王晓东, 冯光. 低聚离子液体的体相与界面及其电化学储能应用[J]. 电化学（中英文）, 2022, 28(11): 2219002-.
[14]	骆晨旭, 师晨光, 余志远, 黄令, 孙世刚. 富锂锰基层状正极材料的合成及其首周过充下的结构演化[J]. 电化学（中英文）, 2022, 28(1): 2006131-.
[15]	李姝谨, 曹志康, 王文凯, 张晓菡, 向兴德. 硫酸盐功能电解液增强水系钠离子电池NaTi₂(PO₄)₃/C负极材料电化学性能的研究[J]. 电化学（中英文）, 2021, 27(6): 605-613.

单分散球形纳米Fe₃O₄的可控合成和嵌锂性质研究

Controllable Synthesis of Dispersed Spherical Fe₃O₄ Nanoparticles as Lithium-Inserted Materials

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics