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电化学(中英文) ›› 2014, Vol. 20 ›› Issue (1): 22-27.  doi: 10.13208/j.electrochem.121122

• 研究论文 • 上一篇    下一篇

锂离子正极材料LiCo1-xMgxMnO4与LiCo1-xAlxMnO4 (x = 0, 0.02, 0.05, 0.1)的制备及其电化学性能

游美玲1,童庆松1,李秀华1,林忞2,黄行康1*,杨勇2*   

  1. 1. 福建师范大学化学系,福建 福州 350007;2. 厦门大学 固体表面物理化学国家重点实验室,化学化工学院化学系,福建 厦门 361005
  • 收稿日期:2012-11-22 修回日期:2013-01-10 出版日期:2014-02-25 发布日期:2014-02-24
  • 通讯作者: 黄行康,杨勇 E-mail:xkhuang@126.com; yyang@xmu.edu.cn
  • 基金资助:

    福建省教育厅科技项目(A类,No. JA10072)、福建省高校杰出青年科研人才计划项目(No. JA11040)以及福建省自然科学基金计划项目(No. 2011J05021)资助

Synthesis and Electrochemical Properties of LiCo1-xMgxMnO4 and LiCo1-xAlxMnO4 (x= 0, 0.02, 0.05, 0.1) as Positive Materials for Lithium-ion Batteries

YOU Mei-ling1, TONG Qing-song1, LI Xiu-hua1, LIN Min2, HUANG Xing-kang1*, YANG Yong2*   

  1. 1. Department of Chemistry, Fujian Normal University, Fuzhou 35007, China; 2. State Key Laboratory for Physical Chemistry of Solid Surfaces, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
  • Received:2012-11-22 Revised:2013-01-10 Published:2014-02-25 Online:2014-02-24
  • Contact: HUANG Xing-kang, YANG Yong E-mail:xkhuang@126.com; yyang@xmu.edu.cn

摘要: 采用固相法合成掺杂镁和铝尖晶石LiCoMnO4材料,研究镁和铝掺杂量对尖晶石LiCoMnO4电极的初始容量、放电平台以及循环性能的影响. 利用扫描电子显微镜、粉末X-射线衍射仪观察分析材料形貌及结构. 结果表明,所合成材料的粒径分布均匀,结晶性较佳. LiCoMnO4电极初始容量为87.0 mAh.g-1,少量镁或铝掺杂使电极初始容量有所增加,LiCo0.98Mg0.02MnO4和LiCo0.98Al0.02MnO4电极初始容量分别为91.3和93.6 mAh.g-1,提高了其5 V放电平台的比例,过量掺杂则其容量降低. 此外,掺杂Al显著改善了LiCoMnO4电极的循环性能,而掺杂镁对电极的循环性能其影响不明显.

关键词: 固相合成, 尖晶石LiCoMnO4, 镁掺杂, 铝掺杂, 锂离子电池, 正极材料

Abstract: The Al-doped and Mg-doped LiCoMnO4 materials were synthesized through solid-state reaction. The effects of doping amounts of Mg and Al on the initial capacities, discharge plateaus, and cycle performances were investigated. The morphologies and structures of the as-prepared materials were studied by scanning electron microscopy and powder X-ray diffraction. The results indicate that the as-prepared samples were composed of uniform, well-crystallized particles. The pristine LiCoMnO4 possessed an initial capacity of 87.0 mAh·g-1, while LiCo0.98Mg0.02MnO4 and LiCo0.98Al0.02MnO4 delivered 91.3 and 93.6 mAh·g-1, respectively. The proper doping amount increased the capacity and the ratio of discharge plateau at 5 V, while over-doping decreased the discharge capacity of LiCoMnO4. In addition, Al doping significantly improved the cycle performance of LiCoMnO4, while no apparent influence with Mg doping.

Key words: solid state reaction, spinel LiCoMnO4, Mg-doped, Al-doped, lithium-ion battery, cathode material

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