锰氧化物聚苯胺复合电极材料的制备与性能

doi:10.13208/j.electrochem.170510

电化学（中英文） ›› 2018, Vol. 24 ›› Issue (2): 137-142. doi: 10.13208/j.electrochem.170510

锰氧化物聚苯胺复合电极材料的制备与性能

周田田，邬冰，邓超，高颖^*

哈尔滨师范大学化学化工学院，黑龙江省光化学生物材料和储能材料重点实验室，黑龙江哈尔滨 150025

收稿日期:2017-05-10 修回日期:2017-05-22 出版日期:2018-04-28 发布日期:2017-06-05
通讯作者: 高颖 E-mail:yinggao9999@163.com
基金资助:
黑龙江省自然科学基金（No.QC2013C008）资助

Preparation and Properties of Manganese Oxide and Polyaniline-Carbon Composite Electrode

ZHOU Tian-tian, WU Bing, DENG Chao, GAO Ying^*

Key Laboratory of Photochemistry Biological Materials and Energy Story Materials, Heilongjiang Province; College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025, Heilongjiang, China

Received:2017-05-10 Revised:2017-05-22 Published:2018-04-28 Online:2017-06-05
Contact: GAO Ying E-mail:yinggao9999@163.com

摘要/Abstract

摘要：

本文制备了二氧化锰和聚苯胺碳的复合电级材料(MnO₂-PAnC)，测试结果表明MnO₂-PAnC材料为松散结构组成的纳米颗粒. MnO₂-PAnC 材料的比电容最大可达459 F•g^-1，MnO₂-PAnC电极在较高的扫速下循环伏安曲线变形较小，表现出良好的可逆性. 交流阻抗测试结果表明，MnO₂-PAnC 电极电荷传递电阻小，表面离子扩散速度快. 充放电500个循环后，MnO₂-PAnC 电容的保持率仍高于60%. 以上实验结果表明，MnO₂-PAnC 是很好的超级电容器的电极材料.

关键词: 锰氧化物, 聚苯胺, 活性炭, 电极材料, 超级电容器

Abstract:

The polyaniline-carbon (PAnC) electrode was prepared by the polymerization of aniline monomer and activated carbon in ice water bath, and followed by chemical deposition of manganese dioxide MnO₂-PAnC composite material. The specific capacitance of MnO₂-PAnC reached 459 F•g^-1. The cyclic voltammetric results showed a small deformation in the voltammogram curve obtained with the MnO₂-PAnC electrode at high scan rate, indicating good reversibility and capacitive properties. The AC impedance results revealed that the MnO₂-PAnC electrode displayed the smallest charge transfer resistance and the fastest diffusion
rate of surface ions than other two materials of MnO₂ and MnO₂-C. After 500 cycles of charging and discharging processes, the capacitance retention rate of MnO₂-PAnC was still higher than 60%. The MnO₂-PAnC is promising as a good electrode material for supercapacitors.

Key words: manganese oxide, polyaniline, active carbon, electrode material, supercapacitor

中图分类号:

O646
TM533

周田田，邬冰，邓超，高颖. 锰氧化物聚苯胺复合电极材料的制备与性能[J]. 电化学（中英文）, 2018, 24(2): 137-142.

ZHOU Tian-tian, WU Bing, DENG Chao, GAO Ying. Preparation and Properties of Manganese Oxide and Polyaniline-Carbon Composite Electrode[J]. Journal of Electrochemistry, 2018, 24(2): 137-142.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.170510

https://electrochem.xmu.edu.cn/CN/Y2018/V24/I2/137

参考文献

[1] Simon P, Gogotsi Y. Materials for electrochemical capacitors[J]. Nature Materials, 2008, 7(11): 845-854.

[2] Ye S B, Feng J C, Wu P Y. Deposition of three-dimensional grapheme aerogel on nickel foam as a binder-free supercapacitorelectrode[J]. ACS Applied Materials Interfaces, 2013, 5(15): 7122-7129.

[3] Kotz R, Carlen M. Principles and applications of electrochemical capacitors[J]. Electrochimica Acta, 2000, 45(15/16): 2483-2498.

[4] Gupta V, Miura N. High performance electrochemical supercapacitor from electrochemically synthesized nanostructured polyaniline[J]. Materials Letters, 2006, 60(12): 1466-1469.

[5] Wan H(万慧), Ying Z R(应宗荣), Liu X D(刘信东), et al. Preparation and electrochemical properties of attapulgite-supported nitrogen-doped carbon@NiCo₂O₄ composites for supercapacitors[J]. Journal of Electrochemistry(电化学), 2017, 23(1): 28-35.

[6] Xu M W, Bao S J, Li H L. Synthesis and characterization of mesoporous nickel oxide for electrochemical capacitor[J]. Journal of Solid State Electrochemistry, 2007, 11(3): 372-377.

[7] Luan Q(栾琼), Xue C F(薛春峰), Zhu H Y(祝红叶), et al. Electrochemical synthesis of porous polyaniline electrodes using HKUST-1 as a template and their electrochemical supercapacitor property[J]. Journal of Electrochemistry(电化学), 2017, 23(1): 13-20.

[8] Murat C, Kakarla R R, Fernando A-M. Advanced electrochemical energy storage supercapacitors based on the flexible carbon fiber fabric-coated with uniform coral-like MnO₂ structured electrodes[J]. Journal of Chemical Engineering, 2017, 309: 151-158.

[9] Xin G X, Wang Y H, Zhang J H, et al. A self-supporting graphene/MnO₂ composite for high-performance supercapacitors[J]. International Journal of Hydrogen Energy, 2015, 40(32): 10176-10184.

[10] Sun D M, Wang Z, Huang K, et al. A sandwich-structured porous MnO₂/polyaniline/MnO₂ thin film for supercapacitor applications [J]. Chemical Physics Letters, 2015, 638, 38-42.

[11] Xie A, Tao F, Jiang C, et al. A coralliform-structured g-MnO₂/polyaniline nanocomposite high-performance supercapacitors[J]. Journal of Electroanalytical Chemistry, 2017, 789: 29-37.

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锰氧化物聚苯胺复合电极材料的制备与性能

Preparation and Properties of Manganese Oxide and Polyaniline-Carbon Composite Electrode

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