CVD 法制备三维石墨烯的电化学储能性能

doi:10.13208/j.electrochem.180548

摘要/Abstract

摘要： 维石墨烯是由二维石墨烯构成的三维网络结构，多孔的网络结构赋予了三维石墨烯超大的比表面积、超高的机械强度以及优异的电子传输通道. 因其优异的性能，三维石墨烯及其复合材料已经广泛地应用于能源、化学和生物等研究领域. 在三维石墨烯的合成方法中，化学气相沉积法由于制备的三维石墨烯具有高纯度、良好结晶性和优异的机械性能而备受推崇. 本文结合当前研究热点，综述了化学气相沉积法制备三维石墨烯及其复合材料在电化学储能领域（铝电池、锂离子电池、锂-硫电池、钠离子电池、金属-空气电池、超级电容器）中的应用，并简要评述当前化学气相沉积法制备三维石墨烯在应用中所面临的挑战及发展前景.

关键词: 三维石墨烯, 铝电池, 锂离子电池, 锂-硫电池, 钠离子电池, 金属-空气电池, 超级电容器

Abstract: Three-dimensional (3D) graphene combinations with the excellent intrinsic properties of graphene and the 3D micro/nano porous structures provide a graphene foam with high specific surface area, excellent mechanical strength and fast electron and mass transports. The 3D graphene foam and its composite nanomaterials are widely used in the fields of nano-electronics, energy storage, chemical and biological sensing. The 3D graphene foam prepared by chemical vapor deposition (CVD) method is of high purity and crystallinity. In this review, a brief overview in the CVD preparations of 3D graphene and properties of CVD prepared 3D graphene based nanomaterials in electrochemical energy storage systems (aluminum battery, lithium-ion battery, lithium-sulfur battery, sodium-ion battery, metal-air battery and supercapacitor) is given. Recent progresses and possible future applications in CVD prepared 3D graphene based nanomaterials are also reviewed and highlighted.

Key words: three-dimensional graphene, aluminum battery, lithium-ion battery, lithium-sulfur battery, sodium-ion battery, metal-air battery, supercapacitor

中图分类号:

O646

夏永康, 顾明远, 杨红官, 于馨智, 鲁兵安. CVD 法制备三维石墨烯的电化学储能性能[J]. 电化学（中英文）, 2019, 25(1): 89-103.

XIA Yong-kang, GU Ming-yuan, YANG Hong-guan, YU Xin-zhi, LU Bing-an. CVD Preparation and Application of 3D Graphene in Electrochemical Energy Storage[J]. Journal of Electrochemistry, 2019, 25(1): 89-103.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.180548

https://electrochem.xmu.edu.cn/CN/Y2019/V25/I1/89

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