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电化学(中英文) ›› 2018, Vol. 24 ›› Issue (3): 216-226.  doi: 10.13208/j.electrochem.170509

• 研究论文 • 上一篇    下一篇

FEC 基电解液对高压正极材料 Li2CoPO4F 电化学性能的影响

王志刚1,赵卫民1,王红春1,林 敏1,龚正良1*,杨 勇1,2*   

  1. 1. 厦门大学能源学院, 福建 厦门 361005; 2. 固体表面物理化学国家重点实验室, 厦门大学化学化工学院, 福建 厦门 361005
  • 收稿日期:2017-05-11 修回日期:2017-06-06 出版日期:2018-06-28 发布日期:2017-06-09
  • 通讯作者: 龚正良,杨 勇 E-mail:zlgong@xmu.edu.cn, yyang@xmu.edu.cn
  • 基金资助:

    福建省自然科学基金项目(No.2014J05019)、国家自然科学基金项目(No.21233004,No.21303147)和厦门大学校长基金(No. 20720150090)资助

Influences of FEC-based Electrolyte on Electrochemical Performance of High Voltage Cathode Material Li2CoPO4F

WANG Zhi-gang1, ZHAO Wei-min1, WANG Hong-chun1, LIN Min1, GONG Zheng-liang1*, YANG Yong1,2*   

  1. 1.College of Energy,Xiamen University,Xiamen 361005,Fujian,China;2. State Key Lab of Physical Chemistry of Solid Surfaces,and College of Chemistry & Chemical Engineering,Xiamen University,Xiamen 361005,Fujian,China
  • Received:2017-05-11 Revised:2017-06-06 Published:2018-06-28 Online:2017-06-09
  • Contact: GONG Zheng-liang, YANG Yong E-mail:zlgong@xmu.edu.cn, yyang@xmu.edu.cn

摘要:

本文研究了以氟代碳酸乙烯酯FEC(fluoroethylene carbonate)为共溶剂的电解液对高压正极材料 Li2CoPO4F 电化学性能的影响,与碳酸酯基电解液1 mol·L-1 LiPF6 EC/DMC=1:1(m:m)相比,1 mol·L-1 LiPF6 FEC/DMC=1:1(m:m)可显著提高Li2CoPO4F的循环稳定性. 通过线性扫描伏安法(LSV)、扫描电镜(SEM)、X射线光电子能谱(XPS)、X射线衍射(XRD)结合电化学阻抗(EIS)对 FEC 改善 Li2CoPO4F 材料循环稳定性的机理进行了探索,结果表明与传统碳酸酯基电解液相比,FEC 基电解液在高压下有着优异的抗氧化性,能够有效抑制电解液的氧化分解. 同时,FEC 基电解液中形成的表面膜具有更高的稳定性,能够抑制电极/电解液界面副反应的发生,提高循环过程中电极材料结构稳定性,从而有益于提高 Li2CoPO4F 材料的电化学性能.

关键词: 锂离子电池, 高压电解液, 氟代碳酸乙烯酯, 氟磷酸钴锂

Abstract:

The effects of fluoroethylene carbonate (FEC) as co-solvent on the electrochemical performance of high voltage cathode material Li2CoPO4F are investigated. Compared with traditional carbonate based electrolyte (1 mol·L-1 LiPF6 EC/DMC (1:1, m:m)), the FEC/DMC based electrolyte can significantly improved the electrochemical performance of Li2CoPO4F. After 100 cycles between 3V and 5.4 V at 1 C rate, the capacity retention of Li2CoPO4F electrode in 1 mol·L-1 LiPF6 EC/DMC (1:1, m:m) was 52.6 % , while that in the EC/DMC based electrolyte was only 14.5 %. Possible functional mechanisms of FEC improving the electrochemical performance of Li2CoPO4F were studied by LSV, EIS, SEM and XPS measurements. It was shown that compared with the traditional EC/DMC based electrolyte, the FEC/DMC based electrolyte exhibited higher stability at high voltage, which suppressed the side reactions at electrode/electrolyte interface when charged to high voltage, and improved the structure stability of Li2CoPO4F during cycling, thus, significantly enhanced the electrochemical performance of Li2CoPO4F.

Key words: lithium ion battery, high voltage electrolytes; fluoroethylene carbonate; Li2CoPO4F

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