氮掺杂碳片的模板诱导制备及其在超级电容器中的应用

doi:10.13208/j.electrochem.170345

电化学（中英文） ›› 2017, Vol. 23 ›› Issue (5): 604-609. doi: 10.13208/j.electrochem.170345

• 超级电容器近期研究专辑（南京航空航天大学张校刚教授主编） • 上一篇下一篇

氮掺杂碳片的模板诱导制备及其在超级电容器中的应用

黄涛，陶广智，杨重庆，鲁登，马列，吴东清*

上海交通大学化学化工学院，上海 200240

收稿日期:2017-04-12 修回日期:2017-05-14 出版日期:2017-10-28 发布日期:2017-10-28
通讯作者: 吴东清 E-mail:wudongqing@sjtu.edu.cn
基金资助:
国家重点基础研究发展计划项目（973计划，2014CB239701）国家自然科学基金项目(21372155和21572132)资助

Template Induced Fabrication of Nitrogen Doped Carbon Sheets as Electrode Materials in Supercapacitors

HUANG Tao, TAO Guang-zhi, YANG Chong-qing, LU Deng, MA Lie, WU Dong-qing*

School of Chemistry and chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

Received:2017-04-12 Revised:2017-05-14 Published:2017-10-28 Online:2017-10-28
Contact: WU Dong-qing E-mail:wudongqing@sjtu.edu.cn

摘要/Abstract

摘要：

兼具有优良的导电能力，高的比表面积和极佳的化学/机械稳定性，具有二维形貌的纳米碳材料近年来逐渐成为超级电容器电极材料的研究热点. 我们在此首次报道一种模板诱导方法以制备具有规整片状形貌的氮掺杂碳材料. 我们将作为硬模板的片状镁铝双金属氢氧化物与熔融的邻苯二胺混合后加入三氯化铁催化剂，进而通过加热使邻苯二胺聚合并碳化，随后刻蚀除去其中的氧化物成分即可以得到具有规整六边形片状氮掺杂碳材料. 通过改变碳化时的温度，可以有效的调节利用该方法所得到的氮掺杂碳片的形貌、结构、石墨化程度、氮含量以及比表面积. 更重要的是这些氮掺杂碳片在用作超级电容器电极材料时体现出优异的电化学性能，在0.5 A·g^-1的电流密度下其比容量可以达到290.0 F·g^-1的. 在1 A·g^-1的电流密度下经过10000周循环测试后，其容量仍然可以达到初始值83%.

关键词: 二维材料, 纳米碳材料, 氮掺杂碳片, 模板诱导, 超级电容器

Abstract: Due to the good electrical conductivity, high specific surface area, and excellent chemical/mechanical stability, carbon nanomaterials with two-dimensional morphology have gradually become the hot topic of the research on supercapacitors. Herein, we report for the first time the fabrication of nitrogen doped carbon sheets (NCSs). In our approach, the sheet-like magnisum aluminum (MgAl) layered double hydroxide was used as the hard template, which was mixed with o-phenylene diamine and iron chloride. The following thermal treatment could render the polymerization and carbonization of o-phenylene diamine. The NCSs with ordered hexagonal architectures were formed by final etching process of the thermally treated mixture. The morphology, structure, graphitic degree, nitrogen content and surface area of the as-prepared NCSs could be adjusted by the temperatures of the thermal treatment. More importantly, the NCSs exhibited outstanding electrochemical performances as the electrode materials in supercapacitors. Among the NCSs, the sample obtained from 600 ^oC (NCS-600) achieved a capacity of 290.0 F·g^-1 at a current density of 0.5 A·g^-1. After 10,000 cycles at 1 A·g^-1, the NCS-600 still retained 83% of its initial capacity, indicating high cycling stability.

Key words: two-dimensional materials, nanocarbon materials, nitrogen doped carbon sheets, template induced method, supercapacitor

中图分类号:

O646

黄涛，陶广智，杨重庆，鲁登，马列，吴东清. 氮掺杂碳片的模板诱导制备及其在超级电容器中的应用[J]. 电化学（中英文）, 2017, 23(5): 604-609.

HUANG Tao, TAO Guang-zhi, YANG Chong-qing, LU Deng, MA Lie, WU Dong-qing. Template Induced Fabrication of Nitrogen Doped Carbon Sheets as Electrode Materials in Supercapacitors[J]. Journal of Electrochemistry, 2017, 23(5): 604-609.

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.170345

https://electrochem.xmu.edu.cn/CN/Y2017/V23/I5/604

参考文献

[1] Aricò, A. S., Bruce, P., Scrosati, B., Tarascon, J. M., Van Schalkwijk, W. Nanostructured materials for advanced energy conversion and storage devices [J]. Nature Materials, 2005, 4(5), 366-377.

[2] Dunn, B., Kamath, H., Tarascon, J. M. Electrical energy storage for the grid: a battery of choices [J]. Science, 2011, 334(6058), 928-935.

[3] Simon, P., Gogotsi, Y. Materials for electrochemical capacitors [J]. Nature Materials, 2008, 7(11), 845-854.

[4] Peng, X., Peng, L., Wu, C., Xie, Y. Two dimensional nanomaterials for flexible supercapacitors [J]. Chemical Society Reviews, 2014, 43(10), 3303-3323.

[5] Frackowiak, E., Beguin, F. Carbon materials for the electrochemical storage of energy in capacitors [J]. Carbon, 2001, 39(6), 937-950.

[6] González, A., Goikolea, E., Barrena, J. A., Mysyk, R. Review on supercapacitors: technologies and materials [J]. Renewable and Sustainable Energy Reviews, 2016, 58, 1189-1206.

[7] Müller, E. A., Gubbins. K. E., Molecular simulation study of hydrophilic and hydrophobic behavior of activated carbon surfaces [J]. Carbon, 1998, 36(10), 1433-1438.

[8] Cote, L. J., Kim, F., Huang, J. Langmuir − blodgett assembly of graphite oxide single layers [J]. Journal of the American Chemical Society, 2009, 131(3), 1043-1049.

[9] Wang, X., Li, X., Zhang, L., Yoon, Y., Weber, P. K., Wang, H., Guo, J., Dai, H. N-doping of graphene through electrothermal reactions with ammonia [J]. Science, 2009, 324(5928), 768-771.

[10] Guo, B., Liu, Q., Chen, E., Zhu, H., Fang, L., Gong, J. R. Controllable N-doping of grapheme [J]. Nano Letters, 2010, 10(12), 4975-4980.

[11] Wang, C., Huang, Y., Pan, H., Jiang, J., Yang, X., Xu, Z., Tian, H., Han,S., Wu, D. Nitrogen-doped porous carbon/graphene aerogel with much enhanced capacitive behaviors [J]. Electrochimica Acta, 2016, 215, 100-107.

[12] Huang, T., Yang, C., Wang, X., Qiu, F., Jing, F., Jiang, J., Liu, R., Han, S., Wu, D. Sacrificial templating fabrication of hierarchically porous nitrogen‐doped carbon nanosheets as superior oxygen reduction electrocatalysts[J]. ChemNanoMat, 2017, 3(2), 130-134.

[13] Zhu, H., Wang, X., Liu, X., Yang, X. Integrated synthesis of poly (o-phenylenediamine) derived carbon materials for high performance supercapacitors [J]. Advanced Materials, 2012, 24(48), 6524-6529.

[14] Lu, Y., Zhang, F., Zhang, T., Leng, K., Zhang, L., Yang, X., Ma, Y., Huang, Y., Zhang, M., Chen, Y. Synthesis and supercapacitor gerformance studies of N-doped graphene materials using o-phenylenediamine as the double-N precursor [J]. Carbon, 2013, 63, 508-516.

[15] Lu, Y., Zhu, Z., Liu, Z. Carbon-encapsulated Fe nanoparticles from detonation-induced pyrolysis of ferrocene [J]. Carbon, 2005, 43(2), 369-374.

[16] Jiang, B., Tian, C., Wang, L., Sun, L., Chen, C., Nong, X., Qiao, Y., Fu, H. Highly concentrated, stable nitrogen-doped graphene for supercapacitors: simultaneous doping and reduction [J]. Applied Surface Science, 2012, 258(8), 3438-3443.

[17] Wen, Z., Wang, X., Mao, S., Bo, Z., Kim, H., Cui, S., Lu, G., Feng, X., Chen, J. Crumpled nitrogen‐doped graphene nanosheets with ultrahigh pore volume for high‐performance supercapacitor [J]. Advanced Materials, 2012, 24(41), 5610-5616.

氮掺杂碳片的模板诱导制备及其在超级电容器中的应用

Template Induced Fabrication of Nitrogen Doped Carbon Sheets as Electrode Materials in Supercapacitors

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

[1]	叶珍珍, 张抒婷, 陈鑫祺, 王瑾, 金鹰, 崔超婕, 张磊, 钱陆明, 张刚, 骞伟中. 基于离子液体的超级电容在3 V及65 ^oC老化条件下的铝碳界面效应[J]. 电化学（中英文）, 2022, 28(12): 2219005-.
[2]	李丹丹, 纪翔宇, 陈明, 杨燕茹, 王晓东, 冯光. 低聚离子液体的体相与界面及其电化学储能应用[J]. 电化学（中英文）, 2022, 28(11): 2219002-.
[3]	王佳, 黄秋安, 李伟恒, 王娟, 庄全超, 张久俊. 电化学阻抗谱弛豫时间分布基础[J]. 电化学（中英文）, 2020, 26(5): 607-627.
[4]	杨裕生. 电化学储能研究22年回顾[J]. 电化学（中英文）, 2020, 26(4): 443-463.
[5]	周岳珅, 李梦, 吴双, 李照磊, 高延敏. ZnCo₂O₄电极材料的形貌调控制备与超级电容特性的研究[J]. 电化学（中英文）, 2019, 25(6): 740-748.
[6]	张韩方, 魏风, 孙健, 荆梦莹, 何孝军. 离子液体辅助条件下由稻壳合成超级电容器用多孔炭[J]. 电化学（中英文）, 2019, 25(6): 764-772.
[7]	夏永康, 顾明远, 杨红官, 于馨智, 鲁兵安. CVD 法制备三维石墨烯的电化学储能性能[J]. 电化学（中英文）, 2019, 25(1): 89-103.
[8]	苏秀丽, 董晓丽, 刘瑶, 王永刚, 余爱水. 基于钛酸锂负极和聚三苯胺正极的电池电容体系[J]. 电化学（中英文）, 2018, 24(4): 324-331.
[9]	邵雯柯，赵雷，刘超，董艳莹，朱元杰，王秋凡. WO₃/碳布柔性非对称超级电容器的组装及性能研究[J]. 电化学（中英文）, 2018, 24(4): 351-358.
[10]	杨波，金直航，赵亚萍，蔡再生. 自支撑柔性氮掺杂碳织物电极的制备与性能研究[J]. 电化学（中英文）, 2018, 24(4): 359-366.
[11]	荆鑫，张旭，王玮，郎俊伟. 兼具高质量和高体积能量密度的水系全金属氧化物不对称超级电容器[J]. 电化学（中英文）, 2018, 24(4): 332-343.
[12]	周田田，邬冰，邓超，高颖. 锰氧化物聚苯胺复合电极材料的制备与性能[J]. 电化学（中英文）, 2018, 24(2): 137-142.
[13]	张秋红，申保收，左宋林，卫歆雨. 离子液体电解质种类对活性炭电极超级电容器电化学性能的影响[J]. 电化学（中英文）, 2017, 23(6): 684-693.
[14]	林顿，张熙悦，曾银香，于明浩，卢锡洪，童叶翔. 高性能碳基与过渡金属化合物基超级电容器电极材料的研究进展[J]. 电化学（中英文）, 2017, 23(5): 560-580.
[15]	赵井文，李佳佳，韩鹏献，崔光磊. 水系锌离子电容器[J]. 电化学（中英文）, 2017, 23(5): 581-585.