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电化学(中英文) ›› 2000, Vol. 6 ›› Issue (4): 478-481. 

• 研究论文 • 上一篇    下一篇

MH-Ni电池记忆效应的研究

谢德明,王建明,张鉴清,曹楚南   

  1. 浙江大学化学系!浙江杭州310027,浙江大学化学系!浙江杭州310027,浙江大学化学系!浙江杭州310027,浙江大学化学系!浙江杭州310027
  • 收稿日期:2000-11-28 修回日期:2000-11-28 出版日期:2000-11-28 发布日期:2000-11-28

The Memory Effect of MH-Ni Battery

XIE De ming *, WANG Jian ming, ZHANG Jian qing, CAO Chu nan   

  1. (Dept. of Chem., Zhejiang Univ., Hangzhou City, 310027, China
  • Received:2000-11-28 Revised:2000-11-28 Published:2000-11-28 Online:2000-11-28

摘要: 放电深度 (DOD)、放电速率、循环次数对MH Ni电池的记忆效应影响很大 .经过几次全充放循环可以消除记忆效应 .记忆效应的存在与Zn无关 .电池在低DOD循环过程中 ,其放电电位、放电容量一开始下降很快 ,然后逐渐趋于某一值 ,并且放电电流越小 ,相应的最高充电电压越低 .若放电电流增加 ,在随后的第一周充放电过程中最高充电电压迅速增加、放电容量显著小于稳定值 .最后探讨了导致记忆效应的原因 ,并给出了若干消除或减弱记忆效应的设想

关键词: MH-Ni电池, 记忆效应, 放电深度(DOD),

Abstract: The memory effect of MH Ni battery was investigated. The depth of discharge, discharge rate and cycle number influence the memory effect greatly. A few completely full charge/discharge cycles could eliminate it. The existence of the memory effect had nothing to do with zinc element. During the course of life cycling at low DOD (degree of discharge),the smaller the discharge current was, the lower was the maximum charge voltage. In addition, discharge voltage and discharge capacity drop fast at the beginning, gradually leveled off at about a value. If the discharge current was increased, the discharge capacity was obviously less than the stabilized value and maximum charge voltage was also changed suddenly. At last, the cause of the memory effect is discussed, and tentative recommendations to eliminate or mitigate the appearance of the memory effect phenomena are given.

Key words: MH Ni battery, Memory effect, DOD, Zin