α型和β型PbO2正极的充放电性能的比较

doi:10.61558/2993-074X.2938

电化学（中英文） ›› 2013, Vol. 19 ›› Issue (1): 43-52. doi: 10.61558/2993-074X.2938

• 电化学材料基础与表界面研究专辑（中国科学院化学研究所万立骏院士主编） • 上一篇下一篇

α型和β型PbO₂正极的充放电性能的比较

崔聪颖¹, 马学美¹, 孔德龙², 马厚义^1*

1. 山东大学化学与化工学院，山东济南 250100； 2. 山东圣阳电源股份有限公司，山东曲阜 273100

收稿日期:2011-11-04 修回日期:2012-03-17 出版日期:2013-02-28 发布日期:2012-03-27
通讯作者: 马厚义 E-mail:hyma@sdu.edu.cn
基金资助:
国家973项目计划（No. 2011CB935901）和山东大学自主创新基金（No. 2009JC019）资助

A Comparative Study of Charge-Discharge Behaviors of α-PbO₂ and β-PbO₂Cathodes

CUI Cong-Ying¹, MA Xue-Mei¹, KONG De-Long², MA Hou-Yi^1*

1. School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China; 2. Shandong Sacred Sun Power Sources Co. LTD., Qufu 273100, Shandong, China

Received:2011-11-04 Revised:2012-03-17 Published:2013-02-28 Online:2012-03-27
Contact: MA Hou-Yi E-mail:hyma@sdu.edu.cn

摘要/Abstract

摘要： 利用化学合成法分别制得α-PbO2和β-PbO2样品，采用XRD、SEM表征与观察两种不同晶型的PbO2样品. 由两种晶型PbO2粉末做成铅酸电池的活性正极，采用循环伏安、恒电流充放电以及电化学阻抗谱等电化学方法研究了其电化学性能. 结果表明，α-PbO2电极的放电容量较低，β-PbO2电极的放电容量较高，两种晶型PbO2粉末按不同配比制成复合电极有利于提高铅酸电池正极的充放电性能.

关键词: 二氧化铅, 铅酸蓄电池, 充放电性能, 电化学阻抗谱

Abstract: The α-PbO2 and β-PbO2 powders were prepared using simple chemical synthetic methods, and their crystalline structures and surface morphologies were characterized with X-ray powder diffraction spectroscopy and scanning electron microscopy. Using the as-synthesized α-PbO2 and β-PbO2 powders as positive active materials, the electrochemical performance of the two PbO2 materials was investigated by means of cyclic voltammetry, galvanostatic charge-discharge tests, and electrochemical impedance spectroscopy. The results indicate that the discharge capacity of α-PbO2 electrode is larger than that of β-PbO2; moreover, the composite electrodes made by α-PbO2 and β-PbO2 mixtures with different proportions are favorable for enhancing the charge-discharge cycle performance of PbO2 positive electrode.

Key words: lead dioxide, lead acid battery, charge-discharge performance, electrochemical impedance spectroscopy

中图分类号:

O646

崔聪颖, 马学美, 孔德龙, 马厚义. α型和β型PbO₂正极的充放电性能的比较[J]. 电化学（中英文）, 2013, 19(1): 43-52.

CUI Cong-Ying, MA Xue-Mei, KONG De-Long, MA Hou-Yi. A Comparative Study of Charge-Discharge Behaviors of α-PbO₂ and β-PbO₂Cathodes[J]. Journal of Electrochemistry, 2013, 19(1): 43-52.

参考文献

[1] Cart J P, Hampson N A. Lead dioxide electrode[J].Chemical Reviews, 1972, 72(6): 679-703.
[2] Munichandraiah N, Sathyanarayana S. Insoluble anode of α-lead dioxide coated on titanium for electrosynthesis of sodium perchlorate[J]. Journal of Applied Electrochemistry, 1988, 18(2): 314-316.
[3] Cao M H, Hu C W, Peng G, et al. Selected-control Synthesis of PbO2 and Pb3O4 single-crystalline nanorods[J]. Journal of the American Chemical Society, 2003, 125(17): 4982-4983.
[4] Xi G C, Peng Y Y, Xu L Q, et al. Selected-control synthesis of PbO2 submicrometer-sized hollow spheres and Pb3O4 microtubes[J]. Inorganic Chemistry Communications, 2004, 7(5): 607-610.
[5] Wu C Z, Hu S Q, Lei L Y, et al. ?-PbO2 hollow nanostructures from the complex precursor: A self-produced intermediate template route[J]. Microporous and Mesoporous Materials, 2006, 89(1/3): 300-305.
[6] Perkins J. Materials and mechanisms determining the performance of lead-acid storage batteries an invited review[J]. Materials Science and Engineering, 1977, 28(2): 167-199.
[7] Fitas R, Zerroual L, Cheladi N, et al. Heat treatment of ?-and ?-battery lead dioxide and its relationship to capacity loss[J]. Journal of Power Sources, 1996, 58(2): 225-229.
[8] Bervas M, Perrin M, Geniès S, et al. Low-cost synthesis and utilization in mini-tubular electrodes of nano PbO2[J]. Journal of Power Sources, 2007, 173(1): 570-577.
[9] Moséley P T, Bridger N J. Lead-acid battery, cathodes incorporating chemically prepared PbO2[J]. Journal of the Electrochemical Society, 1984, 131(3): 608-610.
[10] Taylor E J, Shia G A, Peters D T. A "precharged" positive plate for the lead-Acid automotive battery ? positive plate allowing direct incorporation of PbO2[J]. Journal of the Electrochemical Society, 1984, 131(3): 483-487.
[11] Baker S V, Moseley P T, Turner A D. The role of additives in the positive active mass of the lead/acid cell[J]. Journal of Power Sources, 1989, 27(2): 127-143.
[12] Devilliers D, Dinh Thi M T, Mahé E, et al. Electroanalytical investigations on electrodeposited lead dioxide[J]. Journal of Electroanalytical Chemistry, 2004, 573(2): 227-239.
[13] Herron M E, Pletcher D. A combined electrochemical and in-situ X-ray diffraction study of the cycling of well-defined lead dioxide layers on platinum[J]. Journal of Electroanalytical Chemistry, 1992, 332(1/2): 183-197.

[1]	陈涛, 许元红, 李景虹. 基于电化学阻抗谱的致病菌检测传感器的研究进展[J]. 电化学（中英文）, 2023, 29(6): 2218002-.
[2]	张露露, 李琛坤, 黄俊. 平衡、非平衡、交流状态下电化学双电层建模的初学者指南[J]. 电化学（中英文）, 2022, 28(2): 2108471-.
[3]	李响, 黄秋安, 李伟恒, 白玉轩, 王佳, 刘杨, 赵玉峰, 王娟, 张久俊. 宏观均相多孔电极电化学阻抗谱基础[J]. 电化学（中英文）, 2021, 27(5): 467-497.
[4]	孙齐, 韩严和, 付晓璐. 改性钛基PbO₂电极的制备及其对COD的快速检测[J]. 电化学（中英文）, 2021, 27(5): 558-569.
[5]	陈品松, 胡一涛, 张信义, 沈培康. 立体构造石墨烯材料对铅酸蓄电池负极性能影响的研究[J]. 电化学（中英文）, 2020, 26(6): 834-843.
[6]	王佳, 黄秋安, 李伟恒, 王娟, 庄全超, 张久俊. 电化学阻抗谱弛豫时间分布基础[J]. 电化学（中英文）, 2020, 26(5): 607-627.
[7]	马洪运, 姚晓辉, 妙孟姚, 易阳, 伍绍中, 周江. 高镍正极材料(LiNi_0.83Co_0.12Mn_0.05O₂)45°C循环失效机理研究[J]. 电化学（中英文）, 2020, 26(3): 431-440.
[8]	黄俊. 电催化界面和反应的电化学阻抗谱研究：经典永不褪色[J]. 电化学（中英文）, 2020, 26(1): 3-18.
[9]	廖群，张曙枫，冷文华. 铁电极电还原溴化钠甲醇溶液反应动力学和机理[J]. 电化学（中英文）, 2017, 23(6): 645-653.
[10]	徐迈，王凤武，梁铣,魏亦军，方文彦，朱传高，胡云虎. Pr-PVP掺杂Ti/PbO₂电极制备及其在有机物降解中的应用[J]. 电化学（中英文）, 2017, 23(3): 340-346.
[11]	史坤明，郭建伟，王佳. Pt/C催化剂氧还原反应的交流阻抗动态研究[J]. 电化学（中英文）, 2016, 22(5): 542-548.
[12]	宋宇桥，朱华，赵光金，吴文龙，周寿斌，汪的华. CO₂资源化转化纳米碳材料对硫酸盐化铅盘电极的活化性能研究[J]. 电化学（中英文）, 2016, 22(4): 425-432.
[13]	姜磊, 衣守忠. 阀控蓄电池活性物质微观结构对性能影响的研究[J]. 电化学（中英文）, 2015, 21(5): 471-479.
[14]	张力, 董文燕, 杨太来, 梁镇海. ZrO₂掺杂铌基二氧化铅电极制备及其甲基橙降解电催化性能[J]. 电化学（中英文）, 2015, 21(3): 294-298.
[15]	侯瑞青，蒋平丽，董士刚，林昌健*. 镁钙合金表面贻贝类吸附蛋白膜的NaIO₄氧化处理及抗腐蚀性能[J]. 电化学（中英文）, 2015, 21(1): 58-65.

α型和β型PbO₂正极的充放电性能的比较

A Comparative Study of Charge-Discharge Behaviors of α-PbO₂ and β-PbO₂Cathodes

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics