纳米Na_2SiF_6的电化学制备、表征与荧光性质

doi:10.61558/2993-074X.1912

电化学（中英文） ›› 2008, Vol. 14 ›› Issue (3): 308-312. doi: 10.61558/2993-074X.1912

纳米Na_2SiF_6的电化学制备、表征与荧光性质

秦国旭;万新军;袁希梅;褚道葆;

巢湖学院化学系新型内能材料与精细化学品研究所;安徽恒锐新技术开发有限责任公司;安徽师范大学化学与材料科学学院;

收稿日期:2008-08-28 修回日期:2008-08-28 出版日期:2008-08-28 发布日期:2008-08-28

Electrochemical Synthesis,Characterization and Fluorescence Property of nano Na_2SiF_6

QIN Guo-xu1,WAN Xin-jun1,YUAN Xi-mei3,CHU Dao-bao2

(1.Department of Chemistry,Laboratory of Novel Functional Material and Fine Chemicals,Chaohu NormalCollege,Chaohu 238000,Anhui,China;2.College of Chemistry and Materials Science,Anhui Normal University,Wuhu 241000,Anhui,China;3.Anhui Horae New TechnologyDevelopment Co.,Ltd,Hefei 230088,Anhui,China

Received:2008-08-28 Revised:2008-08-28 Published:2008-08-28 Online:2008-08-28

摘要/Abstract

摘要： 采用溶胶-凝胶法在Ti表面修饰一层纳米TiO2(nanoTiO2)膜,经X射线粉末衍射(XRD)和扫描电镜(SEM)表征,证明多孔TiO2膜的平均孔径为80 nm.以该多孔膜电极为模板,借助电化学沉积的方法制备了纳米Na2SiF6(nano Na2SiF6).经XRD和透射电镜(TEM)测试证实该Na2SiF6为均一的白锰钒型结构,平均粒径约为20 nm.初步研究了其荧光性质,发现在452.4 nm和285 nm处分别有强的荧光发射峰和激发峰.

关键词: Na2SiF6纳米粒子, 多孔nanoTiO2电极, 电化学沉积, 表征, 荧光性质

Abstract: The nano TiO2 film was prepared by sol-gel process and characterized with X-ray diffraction(XRD) and scanning electron microscope(SEM).It was found that the average size of pore diameter was about 80 nm for the nano TiO2 film.The Nano Na2SiF6 was synthesized by electrochemical deposition on the nanoporous film electrode and characterized with XRD and transmission electron microscope(TEM).The result showed that the average size of nanoparticle was 20 nm for the nano Na2SiF6.The fluorescence property of nano Na2SiF6 was also studied briefly.The result indicated that the nano Na2SiF6 exhibited strong fluorescence emission at 452.4 nm and 285 nm,respectively.

Key words: nanoparticle of Na2SiF6, nanoporous TiO2 film electrode, electrochemical deposition, characterization, fluorescence property

中图分类号:

TB383.1

秦国旭, 万新军, 袁希梅, 褚道葆, . 纳米Na_2SiF_6的电化学制备、表征与荧光性质[J]. 电化学（中英文）, 2008, 14(3): 308-312.

QIN Guo-xu, WAN Xin-jun, YUAN Xi-mei, CHU Dao-bao. Electrochemical Synthesis,Characterization and Fluorescence Property of nano Na_2SiF_6[J]. Journal of Electrochemistry, 2008, 14(3): 308-312.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.61558/2993-074X.1912

https://electrochem.xmu.edu.cn/CN/Y2008/V14/I3/308

参考文献

[1]Jin R,Cao Y,Mirkin C A,et al.Photo-induced con-version of silver nanospheres to nanoprisms[J].Sci-ence,2001,294:1901-1903. [2]Millstone J E,Park S,Shuford K L,et al.Observationof a quadrupole plasmon mode for a colloidal solution ofgold nanoprisms[J].J Am Chem Soc,2005,127:5312-5313. [3]Sun Y,Mayers B,Xia Y.Transformation of silvernanospheres into nanobelts and triangular nanoplatesthrough a thermal process[J].Nano Lett,2003,3:675-679. [4]Jin R C,Cao Y C,Hao E C,et al.Controlling aniso-tropic nanoparticle growth through plasmon excitation[J].Nature,2003,425:487-490. [5]Wei G T,Yang Z,Lee C Y,et al.Aqueous-organicphase transfer of gold nanoparticles and gold nanorods u-sing an ionic liquid[J].J Am Chem Soc,2004,126:5036-5037. [6]Cikby A F J,Hornyak G L,Stochert J A,et al.Tem-plate-synthesized nanoscopic gold particle:optical spec-tra and the effects of particle[J].J Phys Chem,1994,98:2963-2971. [7]Yu Y Y,Chang S S,Lee C L,et al.Gold nanorods:electrochemical synthesis and optical properties[J].JPhys Chem B,1997.101:6661-6664. [8]Zach M P,Kwokh N,Penner R M.Molybdenumnanowires by electrodeposition[J].Science,2000,290:2120-2123. [9]The Tianjin Chemical Industry Research Institute(天津化工研究院).The handbook of inorganic salt industry(the first volume)[M].Beijing:Chemical IndustryPress,1996:731-732. [10]CHU Dao-Bao(褚道葆),SHEN Guang-Xia(沈广霞),ZHOU Xin-Fu(周幸福),et al.Electrocatalyticactivity of nanocrystalline TiO2film modified Ti elec-trode[J].Chem J Chin Univ-Chin(in Chinese),2002,23(4):678-681. [11]CHU Dao-Bao(褚道葆),YAO Wen-Li(姚文俐),GU Jia-Shan(顾家山),et al.Heterogeneous electro-catalytic reduction of p-nitrobenzoic acid on nanocrys-talline TiO2film modified electrode[J].Chem J ChinUniv-Chin(in Chinese),2004,25(11):2137-2139. [12]Xiong G,Zhi Z L,Wang X J.Characterization of per-ovskitetype LaCoO3nanocrystals prepared by a stearicacid sol-gel process[J].Mater Sci Lett,1997,16:1064-1068. [13]Lakowiz J R,Gryczynski I,Gryczynski Z.Lumines-cence spectral properties of CdS nanoparticles[J].JPhys Chem B,1999,103:7613-7620.

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纳米Na_2SiF_6的电化学制备、表征与荧光性质

Electrochemical Synthesis,Characterization and Fluorescence Property of nano Na_2SiF_6

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