氧离子传导型固体氧化物电解池燃料电极的研究进展

doi:10.13208/j.electrochem.191146

摘要/Abstract

摘要：

固体氧化物电解池可高效地电解H₂O/CO₂制备燃料,越来越受到人们的重视. 本文对近年来在燃料电极（阴极）材料方面的研究进展进行了全面综述,指出各种阴极材料的优缺点及发展趋势,强调亟待解决的关键科学与技术问题.

关键词: 固体氧化物电解池, 燃料电极, 水蒸气电解, 二氧化碳电解, 共电解

Abstract:

Solid oxide electrolysers are now attracting much more attentions because they can efficiently produce fuels by electrolyzing H₂O/CO₂. In this paper, a comprehensive introduction to the recent progress in the development of fuel electrode (cathode) materials is provided. The advantages, disadvantages and development trend towards various cathode materials are pointed out. The key scientific and technological problems in this field are emphasized.

Key words: solid oxide electrolysers, fuel electrode, H₂O electrolysis, CO₂ electrolysis, H₂O/CO₂, co-electrolysis

中图分类号:

叶灵婷, 谢奎. 氧离子传导型固体氧化物电解池燃料电极的研究进展[J]. 电化学（中英文）, 2020, 26(2): 253-261.

YE Ling-ting, XIE Kui. Research Progress of Fuel Electrode in Oxide-Ion Conducting Solid Oxide Electrolysers[J]. Journal of Electrochemistry, 2020, 26(2): 253-261.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.191146

https://electrochem.xmu.edu.cn/CN/Y2020/V26/I2/253

图/表 4

参考文献 63

[1]	Li Y H( 李一航), Xia C R( 夏长荣 ). Recent advances of CO₂ electrochemical reduction in solid oxide electrolysis cells[J]. Journal of Electrochemistry( 电化学), 2019,25(2): DOI: 10.13208/j.electrochem.191141.
[2]	Zhang L X, Hu S Q, Zhu X F , et al. Electrochemical reduction of CO₂ in solid oxide electrolysis cells[J]. Journal of Energy Chemistry, 2017,26(4):593-601.
[3]	Chen L, Chen F L, Xia C R . Direct synjournal of methane from CO₂-H₂O co-electrolysis in tubular solid oxide electrolysis cells[J]. Energy & Environmental Science, 2014,7(12):4018-4022.
[4]	Mathiesen B, Lund H, Karlsson K . 100% Renewable energy systems, climate mitigation and economic growth[J]. Applied Energy, 2011,88(2):488-501. doi: 10.1016/j.apenergy.2010.03.001 URL
[5]	Zhao C( 赵晨欢), Zhang W Q( 张文强), Yu B( 于波 ), et al. Solid oxide electrolyzer cells[J]. Progress in Chemistry( 化学进展), 2016,28(8):1265-1288. doi: 10.7536/PC151105 URL
[6]	Kaur G, Kulkarni AP, Giddey S , et al. Ceramic composite cathodes for CO₂, conversion to CO in solid oxide electrolysis cells[J]. Applied Energy, 2018,221:131-138.
[7]	Zheng Y, Wang J C, Yu B . A review of high temperature co-electrolysis of H₂O and CO₂ to produce sustainable fuels using solid oxide electrolysis cells (SOECs): Advanced materials and technology[J]. Chemical Society Reviews, 2017,46(5):1427-1463.
[8]	Qiao J L, Liu Y Y, Hong F , et al. A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels[J]. Chemical Society Reviews, 2014,43(2):631-675. doi: 10.1039/C3CS60323G URL
[9]	Oloman C, Li H . Electrochemical processing of carbon dioxide[J]. ChemSuschem, 2008,1(5):385-391.
[10]	Gao D F, Zhang Y, Zhou Z W , et al. Enhancing CO₂ electroreduction with the metal-oxide interface[J]. Journal of the American Chemical Society, 2017,139(16):5652-5655. doi: 10.1021/jacs.7b00102 URL
[11]	Wang W Y, Gan L Z, Lemmon J P , et al. Enhanced carbon dioxide electrolysis at redox manipulated interfaces[J]. Nature Communications, 2019,10:1550. doi: 10.1038/s41467-019-09568-1 URL
[12]	Lu J H, Zhu C L, Pan C C , et al. Highly efficient electrochemical reforming of CH₄/CO₂ in a solid oxide electrolyser[J]. Science Advances, 2018, 4(3): eaar5100. doi: 10.1126/sciadv.aar5100 URL
[13]	Ye L T, Hu X L, Wang X , et al. Enhanced CO₂ electrolysis with SrTiO₃ cathode through dual doping strategy[J]. Journal of Materials Chemistry A, 2019,7(6):2764-2772. doi: 10.1039/C8TA10188D URL
[14]	Pellegrini LA, Soave G, Gamba S , et al. Economic analysis of a combined energy-methanol production plant[J]. Applied Energy, 2011,88(12):4891-4897. doi: 10.1016/j.apenergy.2011.06.028 URL
[15]	Zhu C L, Hou S S, Hu X L , et al. Electrochemical conversion of methane to ethylene in a solid oxide electrolyzer[J]. Nature Communications, 2019,10:1173. doi: 10.1038/s41467-019-09083-3 URL
[16]	Han M F, Fan H, Peng S P . H₂O/CO₂ co-electrolysis in solid oxide electrolysis cells[J]. Engineering Sciences, 2014, 12(1)1:43-50.
[17]	Jiao F, Pan X L, Gong K , et al. Shape-selective zeolites promote ethylene formation from syngas via a ketene intermediate[J]. Angewandte Chemie International Edition, 2018,57(17):4692-4696.
[18]	Herring J S, James EO’Brien, Stoots CM , et al. Progress in high-temperature electrolysis for hydrogen production using planar SOFC technology[J]. International Journal of Hydrogen Energy, 2007,32(4):440-450. doi: 10.1016/j.ijhydene.2006.06.061 URL
[19]	Laosiripojana N, Assabumrungrat S . Hydrogen production from steam and autothermal reforming of LPG over high surface area ceria[J]. Journal of Power Sources, 2006,158(2):1348-1357.
[20]	Liu M, Aravind P V, Woudstra T , et al. Development of an integrated gasifier-solid oxide fuel cell test system: A detailed system study[J]. Journal of Power Sources, 2011,196(17):7277-7289.
[21]	Ishihara T, Jirathiwathanakul N, Zhong H . Intermediate temperature solid oxide electrolysis cell using LaGaO₃ based perovskite electrolyte[J]. Energy & Environmental Science, 2010,3(5):665-672.
[22]	Ishihara T, Matsushita S, Sakai T , et al. Intermediate temperature solid oxide electrolysis cell using LaGaO₃[J]. Solid State Ionics, 2012,255(4):77-80.
[23]	Guan J, Doshi R, Lear G , et al. Ceramic oxygen generators with thin-film zirconia electrolytes[J]. Journal of the American Ceramic Society, 2004,85(11):2651-2654.
[24]	Tao G, Sridhar K R, Chan C . Study of carbon dioxide electrolysis at electrode/electrolyte interface: Part I. Pt/YSZ interface[J]. Solid State Ionics, 2004,175(1/4):615-619. doi: 10.1016/j.ssi.2004.01.077 URL
[25]	Tao G, Sridhar K R, Chan C L . Study of carbon dioxide electrolysis at electrode/electrolyte interface: Part II. Pt-YSZ cermet/YSZ interface[J]. Solid State Ionics, 2004,175(1/4):621-624.
[26]	Hauch A, Ebbesen S D, Jensen S H , et al. Highly efficient high temperature electrolysis[J]. Journal of Materials Che-mistry, 2008,18(20):2331-2340.
[27]	Hauch A, Mogensen M, Hagen A . Ni/YSZ electrode de-gradation studied by impedance spectroscopy-effect of p(H₂O)[J]. Solid State Ionics, 2011,192(1):547-551. doi: 10.1016/j.ssi.2010.01.004 URL
[28]	Kim S D, Seo D W, Dorai A K , et al. The effect of gas compositions on the performance and durability of solid oxide electrolysis cells[J]. International Journal of Hydrogen Energy, 2013,38(16):6569-6576. doi: 10.1016/j.ijhydene.2013.03.115 URL
[29]	Keane M, Fan H, Han M F , et al. Role of initial microstructure on nickel-YSZ cathode degradation in solid oxide electrolysis cells[J]. International Journal of Hydrogen Energy, 2014,39(33):18718-18726. doi: 10.1016/j.ijhydene.2014.09.057 URL
[30]	Bostani B, Ahmadi NP, Yazdani S , et al. Co-electrodeposition of functionally graded Ni-NCZ (nickel coated ZrO₂) composite coating[J]. Journal of Materials Engineering & Performance, 2016,26(2):1-9.
[31]	Jensen S H, Larsen P H, Mogensen M . Hydrogen and synthetic fuel production from renewable energy sources[J]. International Journal of Hydrogen Energy, 2007,32(15):3253-3257. doi: 10.1016/j.ijhydene.2007.04.042 URL
[32]	Ebbesen S D, Mogensen M . Electrolysis of carbon dioxide in solid oxide electrolysis cells[J]. Journal of Power Sources, 2009,193(1):349-358. doi: 10.1016/j.jpowsour.2009.02.093 URL
[33]	Singh V, Muroyama H, Matsui T , et al. Performance comparison between Ni-SDC and Ni-YSZ Cermet electrodes for carbon dioxide electrolysis on solid oxide electrolysis cell[J]. ECS Transactions, 2014,64(2):53-64.
[34]	Ebbesen S D, Graves C, Mogensen M . Production of synthetic fuels by co-electrolysis of steam and carbon dioxide[J]. International Journal of Green Energy, 2009,6(6):646-660. doi: 10.1080/15435070903372577 URL
[35]	Mahmood A, Bano S, Yu J H , et al. Effect of operating conditions on the performance of solid electrolyte membrane reactor for steam and CO₂ electrolysis[J]. Journal of Membrane Science, 2015,473:8-15. doi: 10.1016/j.memsci.2014.09.002 URL
[36]	Bierschenk D M, Wilson J R, Barnett S A . High efficiency electrical energy storage using a methane-oxygen solid oxide cell[J]. Energy & Environmental Science, 2011,4(3):944-951.
[37]	Nishida R, Puengjinda P, Nishino H , et al. High-performance electrodes for reversible solid oxide fuel cell/solid oxide electrolysis cell: Ni-Co dispersed ceria hydrogen electrodes[J]. RSC Advances, 2014,4(31):16260-16266. doi: 10.1039/C3RA47089J URL
[38]	Gaudillere C, Navarrete L, Serra J . Syngas production at intermediate temperature through H₂O and CO₂ electrolysis with a Cu-based solid oxide electrolyzer cell[J]. International Journal of Hydrogen Energy, 2014,39(7):3047-3054. doi: 10.1016/j.ijhydene.2013.12.045 URL
[39]	Xing R M, Wang Y R, Zhu Y Q , et al. Co-electrolysis of steam and CO₂ in a solid oxide electrolysis cell with La_0.75Sr_0.25Cr_0.5Mn_0.5O₃-_δ-Cu ceramic composite electrode[J]. Journal of Power Sources, 2015,274:260-264. doi: 10.1016/j.jpowsour.2014.10.066 URL
[40]	Yang X, Irvine J T S . (La_0.75Sr_0.25)_0.95Mn_0.5Cr_0.5O₃ as the cathode of solid oxide electrolysis cells for high temperature hydrogen production from steam[J]. Journal of Materials Chemistry, 2008,18(20):2349-2354. doi: 10.1039/b800163d URL
[41]	Tao S, Irvine J . Synjournal and characterization of (La_0.75Sr_0.25)Cr_0.5Mn_0.5O₃-_δ, a redox-stable, efficient perovskite anode for SOFCs[J]. Journal of The Electrochemical Society, 2004,151(2):A252-A259. doi: 10.1149/1.1639161 URL
[42]	Tietz F, Sebold D, Brisse A , et al. Degradation phenomena in a solid oxide electrolysis cell after 9000h of operation[J]. Journal of Power Sources, 2013,223:129-135. doi: 10.1016/j.jpowsour.2012.09.061 URL
[43]	Gan L Z, Ye L T, Tao S W , et al. Titanate cathodes with enhanced electrical properties b achieved via growing surface Ni particles toward efficient carbon dioxide electrolysis[J]. Physical Chemistry Chemical Physics, 2016,18(4):3137-3143.
[44]	Torrell M, García-Rodríguez S, Morata A , et al. Co-electrolysis of steam and CO₂ in full-ceramic symmetrical SOECs: a strategy for avoiding the use of hydrogen as a safe gas[J]. Faraday Discussions, 2015,182:241-255.
[45]	Zhu C L, Hou L X, Li S S , et al. Efficient carbon dioxide electrolysis with metal nanoparticles loaded La_0.75Sr_0.25Cr_0.5-Mn_0.5O₃-_δ cathodes[J]. Journal of Power Sources, 2017,363:177-184.
[46]	Ruan C, Xie K, Yang L , et al. Efficient carbon dioxide electrolysis in a symmetric solid oxide electrolyzer based on nanocatalyst-loaded chromate electrodes[J]. International Journal of Hydrogen Energy, 2014,39(20):10338-10348.
[47]	Morales R, Carlos J, Vázquez C , et al. Disruption of extended defects in solid oxide fuel cell anodes for methane oxidation[J]. Nature, 2006,439(7076):568-571.
[48]	Marina O, Canfield N, Stevenson J . Thermal, electrical, and electrocatalytical properties of lanthanum-doped strontium titanate[J]. Solid State Ionics, 2002,149(1/2):21-28.
[49]	Li X, Zhao H L, Zhou X O , et al. Electrical conductivity and structural stability of La-doped SrTiO₃ with A-site deficiency as anode materials for solid oxide fuel cells[J]. International Journal of Hydrogen Energy, 2010,35(15):7913-7918.
[50]	Tsekouras G, Irvine J T S . The role of defect chemistry in strontium titanates utilised for high temperature steam electrolysis[J]. Journal of Materials Chemistry, 2011,21(25):9367-9376.
[51]	Xie K, Zhang Y Q, Meng G Y , et al. Direct synjournal of methane from CO₂/H₂O in an oxygen-ion conducting solid oxide electrolyser[J]. Energy & Environmental Science, 2011,4(6):2218-2222.
[52]	Li Y X, Zhou J E, Dong D H , et al. Composite fuel electrode La_0.2Sr_0.8TiO₃-_δ-Ce_0.8Sm_0.2O₂-_δ for electrolysis of CO₂ in an oxygen-ion conducting solid oxide electrolyser[J]. Physical Chemistry Chemical Physics, 2012,14(44):15547-15553.
[53]	Li S S, Li Y X, Gan Y , et al. Electrolysis of H₂O and CO₂ in an oxygen-ion conducting solid oxide electrolyzer with a La_0.2Sr_0.8TiO₃+_δ, composite cathode[J]. Journal of Power Sources, 2012,218:244-249.
[54]	Qi W T, Gan Y, Yin D , et al. Remarkable chemical adsorption of manganese-doped titanate for direct carbon dioxide electrolysis[J]. Journal of Materials Chemistry A, 2014,2(19):6904-6915.
[55]	Li Z, Li S S, Tseng CJ , et al. Redox-reversible perovskite ferrite cathode for high temperature solid oxide steam electrolyser[J]. Electrochimica Acta, 2017,229:48-54.
[56]	Ye L T, Zhang M Y, Huang P , et al. Enhancing CO₂ electrolysis through synergistic control of non-stoichiometry and doping to tune cathode surface structures[J]. Nature Communications, 2017,8:14785.
[57]	Miller D N, Irvine J T S . B-site doping of lanthanum strontium titanate for solid oxide fuel cell anodes[J]. Journal of Power Sources, 2011,196(17):7323-7327.
[58]	Neagu D, Tsekouras G, Miller DN , et al. In situ growth of nanoparticles through control of non-stoichiometry[J]. Nature Chemistry, 2013,5(11):916-923.
[59]	Xu S S, Dong D H, Wang Y , et al. Perovskite chromates cathode with resolved and anchored nickel nano-particles for direct high-temperature steam electrolysis[J]. Journal of Power Sources, 2014,246(3):346-355.
[60]	Gan L Z, Ye L T, Ruan C , et al. Redox-reversible iron orthovanadate cathode for solid oxide steam electrolyzer[J]. Advanced Science, 2016,3(2):1500186.
[61]	Li S S, Qin Q Q, Xie K , et al. High-performance fuel electrodes based on NbTi_0.5M_0.5O₄ (M = Ni, Cu) with rever-sible exsolution of the nano-catalyst for steam electrolysis[J]. Journal of Materials Chemistry A, 2013,1(31):8984-8993.
[62]	Shin T H, Myung J H, Verbraeken M , et al. Oxygen deficient layered double perovskite as an active cathode for CO₂ electrolysis using a solid oxide conductor[J]. Faraday Discussions, 2015,182:227-239.
[63]	Ye L T, Pan C C, Zhang M Y , et al. Highly efficient CO₂ electrolysis on cathodes with exsolved alkaline earth oxide nanostructures[J]. ACS Applied Materials & Interfaces, 2017,9(30):25350-25357.

Cathode material	Temperature/^oC	Voltage/V	Current density/(A·cm^-2)	Reference
Ni/YSZ	750	1.29	0.29	[28]
Cu/La_0.75Sr_0.25Cr_0.5Mn_0.5O_3-_δ	750	1.65	1.82	[39]
La_0.75Sr_0.25Cr_0.5Mn_0.5O_3-_δ	850	1.7	0.75	[44]
La_0.2Sr_0.8Ti_0.9Mn_0.1O₃₊_δ	800	2.0	0.25	[54]
Sr_1-_xPr_xFeO_3-_δ	800	2.0	1.64	[55]
(La_0.2Sr_0.8)_0.95Ti_0.85Mn_0.1Ni_0.05O₃₊_δ	800	2.0	0.87	[56]
Fe/FeV₂O₄	800	1.5	0.12	[60]