固体氧化物电解池直接电解CO2的研究进展

doi:10.13208/j.electrochem.191141

摘要/Abstract

摘要：

固体氧化物电解池是一种高效、环境友好型的能量转换器件,可以直接将电能转化为化学能. 本文介绍了近年来作者课题组在固体氧化物电解池直接用于CO₂还原的研究进展,并以阴极材料为主着重讨论了金属陶瓷电极和混合导电型钙钛矿氧化物电极的研究工作,最后展望了未来固体氧化物电解池直接电解CO₂的研究思路和方向.

关键词: 固体氧化物电解池, CO₂还原, 阴极, 金属陶瓷, 钙钛矿

Abstract:

Solid oxide electrolysis cells (SOECs) have stimulated wide interests for their promising application in the reduction of CO₂ emissions and the storage of renewable energy. Here, the advances made in the development of cathode materials including cermets and perovskite oxides in our research group, are summarized, along with the design of cell configurations. The electrochemical kinetics and performances of cathodes and cells are discussed and analyzed. It is expected that this brief review offers critical insights and useful guidelines for developing superior electrodes and SOECs in the future.

Key words: solid oxide electrolysis cells, CO₂ reduction, cathodes, cermets, perovskites

中图分类号:

O646

李一航, 夏长荣. 固体氧化物电解池直接电解CO₂的研究进展[J]. 电化学（中英文）, 2020, 26(2): 162-174.

LI Yi-hang, XIA Chang-rong. Recent Advances of CO₂ Electrochemical Reduction in Solid Oxide Electrolysis Cells[J]. Journal of Electrochemistry, 2020, 26(2): 162-174.

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.191141

https://electrochem.xmu.edu.cn/CN/Y2020/V26/I2/162

图/表 10

图1

表1

表2

图2

图3

表3

图4

图5

图6

图7

参考文献 67

[1]	Zhang L X, Hu S Q, Zhu X F , et al. Electrochemical reduction of CO₂ in solid oxide electrolysis cells[J]. Journal of Energy Chemistry, 2017,26(4):593-601.
[2]	Chen L, Chen F L, Xia C R . Direct synjournal of methane from CO₂-H₂O co-electrolysis in tubular solid oxide electrolysis cells[J]. Energy & Environmental Science, 2014,7(12):4018-4022.
[3]	Kondratenko E V, Mul G, Baltrusaitis J , et al. Status and perspectives of CO₂ conversion into fuels and chemicals by catalytic, photocatalytic and electrocatalytic processes[J]. Energy & Environmental Science, 2013,6(11):3112-3135.
[4]	Graves C, Ebbesen S D, Mogensen M , et al. Sustainable hydrocarbon fuels by recycling CO₂ and H₂O with renewable or nuclear energy[J]. Renewable and Sustainable Energy Reviews, 2011,15(1):1-23.
[5]	Zheng Y, Wang J C, Yu B , et al. A review of high temperature co-electrolysis of H₂O and CO₂ to produce sustainable fuels using solid oxide electrolysis cells (SOECs): advanced materials and technology[J]. Chemical Society Reviews, 2017,46(5):1427-1463. doi: 10.1039/C6CS00403B URL
[6]	Ebbesen S D, Jensen S H, Hauch A , et al. High temperature electrolysis in alkaline cells, solid proton conducting cells, and solid oxide cells[J]. Chemical Reviews, 2014,114(21):10697-10734. doi: 10.1021/cr5000865 URL
[7]	Sridhar K R, Vaniman B T . Oxygen production on Mars using solid oxide electrolysis[J]. Solid State Ionics, 1997,93(3/4):321-328.
[8]	Guan J, Doshi R, Lear G , et al. Ceramic oxygen generators with thin-film zirconia electrolytes[J]. Journal of the Ame-rican Ceramic Society, 2002,85(11):2651-2654.
[9]	Stempien J P, Liu Q L. Ni, M. , et al. Physical principles for the calculation of equilibrium potential for co-electrolysis of steam and carbon dioxide in a solid oxide electrolyzer cell (SOEC)[J]. Electrochimica Acta, 2014,147:490-497. doi: 10.1016/j.electacta.2014.09.144 URL
[10]	Hansen J B . Solid oxide electrolysis - a key enabling technology for sustainable energy scenarios[J]. Faraday Discussions, 2015,182:9-48.
[11]	Cheng C Y, Kelsall G H, Kleiminger L . Reduction of CO₂ to CO at Cu-ceria-gadolinia (CGO) cathode in solid oxide electrolyser[J]. Journal of Applied Electrochemistry, 2013,43(11):1131-1144.
[12]	Wang S J, Inoishi A, Hong J , et al. Ni-Fe bimetallic cathodes for intermediate temperature CO₂ electrolyzers using a La_0.9Sr_0.1Ga_0.8Mg_0.2O₃ electrolyte[J]. Journal of Materials Chemistry A, 2013,1(40):12455-12461.
[13]	Wang Y, Liu T, Lei L B , et al. High temperature solid oxide H₂O/CO₂ co-electrolysis for syngas production[J]. Fuel Processing Technology, 2017,161:248-258.
[14]	Zhang Y, Knibbe R, Sunarso J , et al. Recent progress on advanced materials for solid-oxide fuel cells operating below 500 °C[J]. Advanced Materials, 2017,29(48):1700132.
[15]	Tao G, Sridhar K R, Chan C L . Study of carbon dioxide electrolysis at electrode/electrolyte interface: Part I. Pt/YSZ interface[J]. Solid State Ionics, 2004,175(1/4):615-619. doi: 10.1016/j.ssi.2004.01.077 URL
[16]	Tao G, Sridhar K R, Chan C L . Study of carbon dioxide electrolysis at electrode/electrolyte interface: Part II. Pt-YSZ cermet/YSZ interface[J]. Solid State Ionics, 2004,175(1/4):621-624.
[17]	Xie Y M, Xiao J, Liu D D , et al. Electrolysis of carbon dioxide in a solid oxide electrolyzer with silver-gadolinium-doped ceria cathode[J]. Journal of The Electrochemical Society, 2015,162(4):F397-F402.
[18]	Green R D, Liu C C, Adler S B . Carbon dioxide reduction on gadolinia-doped ceria cathodes[J]. Solid State Ionics, 2008,179(17/18):647-660. doi: 10.1016/j.ssi.2008.04.024 URL
[19]	Ebbesen S D, Mogensen M . Electrolysis of carbon dioxide in solid oxide electrolysis cells[J]. Journal of Power Sources, 2009,193(1):349-358.
[20]	Kleiminger L, Li T, Li K , et al. CO₂ splitting into CO and O₂ in micro-tubular solid oxide electrolysers[J]. RSC Advances, 2014,4(91):50003-50016.
[21]	Dong D H, Xu S S, Shao X , et al. Hierarchically ordered porous Ni-based cathode-supported solid oxide electrolysis cells for stable CO₂ electrolysis without safe gas[J]. Journal of Materials Chemistry A, 2017,5(46):24098-24102.
[22]	Luo Y, Li W Y, Shi Y X , et al. Mechanism for reversible CO/CO₂ electrochemical conversion on a patterned nickel electrode[J]. Journal of Power Sources, 2017,366:93-104. doi: 10.1016/j.jpowsour.2017.09.019 URL
[23]	Nepomuceno M A, Kato Y . Development of disk-type solid oxide electrolysis cell for CO₂ reduction in an active carbon recycling energy system[J]. Energy Procedia, 2017,131:101-107. doi: 10.1016/j.egypro.2017.09.480 URL
[24]	Skafte T L, Blennow P, Hjelm J , et al. Carbon deposition and sulfur poisoning during CO₂ electrolysis in nickel-based solid oxide cell electrodes[J]. Journal of Power Sour-ces, 2018,373:54-60.
[25]	Song Y F, Zhang X M, Zhou Y J , et al. Promoting oxygen evolution reaction by RuO₂ nanoparticles in solid oxide CO₂ electrolyzer[J]. Energy Storage Materials, 2018,13:207-214. doi: 10.1016/j.ensm.2018.01.013 URL
[26]	Yu L B, Wang J J, Ye Z M , et al. Electrochemical conversion of CO₂ over microchanneled cathode supports of solid oxide electrolysis cells[J]. Journal of CO₂ Utilization, 2018,26:179-183.
[27]	Zheng M H, Wang S, Yang Y , et al. Barium carbonate as a synergistic catalyst for the H₂O/CO₂ reduction reaction at Ni-yttria stabilized zirconia cathodes for solid oxide electrolysis cells[J]. Journal of Materials Chemistry A, 2018,6(6):2721-2729.
[28]	Yu L B, Wang J J, Hu X , et al. A nanocatalyst network for electrochemical reduction of CO₂ over microchanneled solid oxide electrolysis cells[J]. Electrochemistry Communications, 2018,86:72-75.
[29]	Song Y F, Zhou Z W, Zhang X M , et al. Pure CO₂ electrolysis over an Ni/YSZ cathode in a solid oxide electrolysis cell[J]. Journal of Materials Chemistry A, 2018,6(28):13661-13667. doi: 10.1039/C8TA02858C URL
[30]	Liu T, Chen X, Wu J J , et al. A highly-performed, dual-layered cathode supported solid oxide electrolysis cell for efficient CO₂ electrolysis fabricated by phase inversion co-tape casting method[J]. Journal of The Electrochemical Society, 2017,164(12):F1130-F1135. doi: 10.1149/2.0841712jes URL
[31]	Kleiminger L, Kelsall G H, Li T , et al. Effects of current collector materials on performances of micro-tubular solid oxide electrolysers for splitting CO₂[J]. High Temperature Experimental Techniques and Measurements, 2015,68(1):3449-3458.
[32]	Singh V, Muroyama H, Matsui T , et al. Performance and stability of solid oxide electrolysis cell for CO₂ reduction under various operating conditions[J]. Electrochemistry, 2014,82(10):839-844. doi: 10.5796/electrochemistry.82.839 URL
[33]	Li S S, Li Y X, Gan Y , et al. Electrolysis of H₂O and CO₂ in an oxygen-ion conducting solid oxide electrolyzer with a La_0.2Sr_0.8TiO₃+_δ composite cathode[J]. Journal of Power Sources, 2012,218:244-249. doi: 10.1016/j.jpowsour.2012.06.046 URL
[34]	Li Y X, Zhou J E, Dong D H , et al. Composite fuel electrode La_0.2Sr_0.8TiO₃-_δ-Ce_0.8Sm_0.2O₂-_δ for electrolysis of CO₂ in an oxygen-ion conducting solid oxide electrolyser[J]. Physical Chemistry Chemical Physics, 2012,14(44):15547-15553. doi: 10.1039/c2cp42232h URL
[35]	Qi W T, Gan Y, Yin D ., et al. Remarkable chemical adsorption of manganese-doped titanate for direct carbon dioxide electrolysis[J]. Journal of Materials Chemistry A, 2014,2(19):6904-6915. doi: 10.1039/c4ta00344f URL
[36]	Xu S S, Li S S, Yao W T , et al. Direct electrolysis of CO₂ using an oxygen-ion conducting solid oxide electrolyzer based on La_0.75Sr_0.25Cr_0.5Mn_0.5O₃-_δ electrode[J]. Journal of Power Sources, 2013,230:115-121.
[37]	Yue X L, Irvine J T S . (La,Sr)(Cr,Mn)O₃/GDC cathode for high temperature steam electrolysis and steam-carbon dioxide co-electrolysis[J]. Solid State Ionics, 2012,225:131-135. doi: 10.1016/j.ssi.2012.06.015 URL
[38]	Yue X L, Irvine J T S . Modification of LSCM-GDC cathodes to enhance performance for high temperature CO₂ electrolysis using solid oxide electrolysis cells (SOECs)[J]. Journal of Materials Chemistry A, 2017,5(15):7081-7090.
[39]	Yang Y, Li Y H, Jiang Y A , et al. The electrochemical performance and CO₂ reduction mechanism on strontium doped lanthanum ferrite fuel electrode in solid oxide electrolysis cell[J]. Electrochimica Acta, 2018,284:159-167. doi: 10.1016/j.electacta.2018.07.187 URL
[40]	Wang S J, Tsuruta H, Asanuma M , et al. Ni-Fe-La(Sr)Fe-(Mn)O₃ as a new active cermet cathode for intermediate-temperature CO₂ electrolysis using a LaGaO₃-based electrolyte[J]. Advanced Energy Materials, 2015,5(2):1401003.
[41]	Tian Y F, Zheng H Y, Zhang L L , et al. Direct electrolysis of CO₂ in symmetrical solid oxide electrolysis cell based on La_0.6Sr_0.4Fe_0.8Ni_0.2O₃-_δ electrode[J]. Journal of The Electrochemical Society, 2018,165(2):F17-F23.
[42]	Liu SBA, Liu Q X, Luo J L . The excellence of La(Sr)Fe-(Ni)O₃ as an active and efficient cathode for direct CO₂ electrochemical reduction at elevated temperatures[J]. Journal of Materials Chemistry A, 2017,5(6):2673-2680.
[43]	Addo P, Molero-Sanchez B, Chen M , et al. CO/CO₂ study of high performance La_0.3Sr_0.7Fe_0.7Cr_0.3O₃-_δ reversible SOFC electrodes[J]. Fuel Cells, 2015,15(5):689-696. doi: 10.1002/fuce.v15.5 URL
[44]	Molero-Sánchez B, Addo P, Buyukaksoy A , et al. Electrochemistry of La_0.3Sr_0.7Fe_0.7Cr_0.3O₃-_δ as an oxygen and fuel electrode for RSOFCs[J]. Faraday Discussions, 2015,182:159-175. doi: 10.1039/C5FD00029G URL
[45]	Cao Z Q, Wei B, Miao J P , et al. Efficient electrolysis of CO₂ in symmetrical solid oxide electrolysis cell with highly active La_0.3Sr_0.7Fe_0.7Ti_0.3O₃ electrode material[J]. Electrochemistry Communications, 2016,69:80-83. doi: 10.1016/j.elecom.2016.06.008 URL
[46]	Zhou Y J, Zhou Z W, Song Y F , et al. Enhancing CO₂ electrolysis performance with vanadium-doped perovskite cathode in solid oxide electrolysis cell[J]. Nano Energy, 2018,50:43-51. doi: 10.1016/j.nanoen.2018.04.054 URL
[47]	Wang Y, Liu T, Fang S M , et al. Syngas production on a symmetrical solid oxide H₂O/CO₂ co-electrolysis cell with Sr₂Fe_1.5Mo_0.5O₆-Sm_0.2Ce_0.8O_1.9 electrodes[J]. Journal of Power Sources, 2016,305:240-248. doi: 10.1016/j.jpowsour.2015.11.097 URL
[48]	Li Y H, Chen X R, Yang Y , et al. Mixed-conductor Sr₂Fe_1.5Mo_0.5O₆-_δ as robust fuel electrode for pure CO₂ reduction in solid oxide electrolysis cell[J]. ACS Sustainable Chemistry & Engineering, 2017,5(12):11403-11412.
[49]	Li Y H, Zou S X, Ju J W , et al. Characteristics of nano-structured SFM infiltrated onto YSZ backbone for symmetrical and reversible solid oxide cells[J]. Solid State Ionics, 2018,319:98-104.
[50]	Li Y H, Zhan Z L, Xia C R . Highly efficient electrolysis of pure CO₂ with symmetrical nanostructured perovskite electrodes[J]. Catalysis Science & Technology, 2018,8(4):980-984.
[51]	Adler S B, Lane J, Steele B . Electrode kinetics of porous mixed-conducting oxygen electrodes[J]. Journal of The Electrochemical Society, 1996,143(11):3554-3564.
[52]	Tao S W, Irvine J T S . A redox-stable efficient anode for solid-oxide fuel cells[J]. Nature Materials, 2003,2(5):320-323. doi: 10.1038/nmat871 URL
[53]	Wang S J, Ishihara T . La_0.6Sr_0.4Fe_0.9Mn_0.1O₃ oxide cathode for the high temperature CO₂ electrolysis using LSGM electrolyte[J]. High Temperature Experimental Techniques and Measurements, 2013,57(1):3171-3176.
[54]	Zhang Y Q, Li J H, Sun Y F , et al. Highly active and redox-stable Ce-doped LaSrCrFeO-based cathode catalyst for CO₂ SOECs[J]. Acs Applied Materials & Interfaces, 2016,8(10):6457-6463.
[55]	Ding D, Li X X, Lai S Y , et al. Enhancing SOFC cathode performance by surface modification through infiltration[J]. Energy & Environmental Science, 2014,7(2):552-575.
[56]	Huang H, Lin J, Wang Y L , et al. Facile one-step forming of NiO and yttrium-stabilized zirconia composite anodes with straight open pores for planar solid oxide fuel cell using phase-inversion tape casting method[J]. Journal of Power Sources, 2015,274:1114-1117. doi: 10.1016/j.jpowsour.2014.10.190 URL
[57]	Li Y H, Li P, Hu B B , et al. A nanostructured ceramic fuel electrode for efficient CO₂/H₂O electrolysis without safe gas[J]. Journal of Materials Chemistry A, 2016,4(23):9236-9243.
[58]	Neagu D, Oh T S, Miller D N , et al. Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution[J]. Nature Communications, 2015,6:8120. doi: 10.1038/ncomms9120 URL
[59]	Neagu D, Tsekouras G, Miller D N , et al. In situ growth of nanoparticles through control of non-stoichiometry[J]. Nature Chemistry, 2013,5(11):916-923. doi: 10.1038/nchem.1773 URL
[60]	Neagu D, Papaioannou E I, Ramli W K W , et al. Demonstration of chemistry at a point through restructuring and catalytic activation at anchored nanoparticles[J]. Nature Communications, 2017,8(1):1855. doi: 10.1038/s41467-017-01880-y URL
[61]	Lai K Y, Manthiram A . Self-regenerating Co-Fe nanoparticles on perovskite oxides as a hydrocarbon fuel oxidation catalyst in solid oxide fuel cells[J]. Chemistry of Materials, 2018,30(8):2515-2525.
[62]	Li Y H, Hu B B, Xia C R , et al. A novel fuel electrode enabling direct CO₂ electrolysis with excellent and stable cell performance[J]. Journal of Materials Chemistry A, 2017,5(39):20833-20842.
[63]	Opitz A K, Nenning A, Rameshan C , et al. Surface chemistry of perovskite-type electrodes during high temperature CO₂ electrolysis investigated by operando photoelectron spectroscopy[J]. ACS Applied Materials & Interfaces, 2017,9(41):35847-35860.
[64]	Feng Z L A, Machala M L, Chueh W C . Surface electrochemistry of CO₂ reduction and CO oxidation on Sm-doped CeO₂-_x: coupling between Ce ³+ and carbonate adsorbates [J]. Physical Chemistry Chemical Physics, 2015,17(18):12273-12281.
[65]	Yu Y, Mao B H, Geller A , et al. CO₂ activation and carbonate intermediates: an operando AP-XPS study of CO₂ electrolysis reactions on solid oxide electrochemical cells[J]. Physical Chemistry Chemical Physics, 2014,16(23):11633-11639. doi: 10.1039/C4CP01054J URL
[66]	Duboviks V, Maher R, Kishimoto M , et al. A Raman spe-ctroscopic study of the carbon deposition mechanism on Ni/CGO electrodes during CO/CO₂ electrolysis[J]. Physical Chemistry Chemical Physics, 2014,16(26):13063-13068. doi: 10.1039/c4cp01503g URL
[67]	Itoh T, Abe K, Dokko K , et al. In situ Raman spectroelectrochemistry of oxygen species on gold electrodes in high temperature molten carbonate melts[J]. Journal of The Electrochemical Society, 2004,151(12):A2042-A2046. doi: 10.1149/1.1812735 URL

Cell component	Temperature/^oC	Inlet gas	Current density/ (A·cm^-2)	Ref.
Ni-YSZ//YSZ//La_0.8Sr_0.2MnO_3-_δ-YSZ	800	70%CO₂-30%CO	0.27	[27]
BaCO₃-Ni-YSZ//YSZ//La_0.8Sr_0.2MnO_3-_δ-YSZ	800	70%CO₂-30%CO	0.55	[27]
Ni-YSZ//YSZ//(La_0.75Sr_0.25)_0.95MnO₃-YSZ	850	70%CO₂-30%CO	1.05	[19]
Ni-YSZ//YSZ// La_0.8Sr_0.2MnO_3-_δ-YSZ	750	90%CO₂-10%CO	0.3	[20]
Ni-YSZ//YSZ// La_0.8Sr_0.2MnO_3-_δ-YSZ	800	90%CO₂-10%CO	0.7	[31]
Ni-YSZ//YSZ//(La_0.75Sr_0.25)_0.95MnO₃-YSZ	1000	34%CO₂-66%CO	0.25	[32]
Ni-YSZ//YSZ//PrBaCo₂O₅₊_δ-GDC	700	67%CO₂-33%CO	1.1	[30]

Code	Elementary step	R_p
C-1	CO_2(g) ? CO_2(s)	p
C-2	CO_2(s) + e ? CO_(s) + O	pp
C-3	O + e ? O	pp
C-4	O + V? O	-
C-5	CO_(s) ? CO_(g)	p

Cell component	Temperature/ ^oC	Inlet gas	Current density/ (A·cm^-2)	Ref.
La_0.2Sr_0.8TiO₃₊_δ-GDC//YSZ//(La_0.8Sr_0.2)_0.95MnO_3-_δ-GDC	700	CO₂	0.05	[33]
La_0.2Sr_0.8Ti_0.9Mn_0.1O₃₊_δ//YSZ//(La_0.8Sr_0.2)_0.95MnO_3-_δ-SDC	800	CO₂	0.15	[35]
La_0.75Sr_0.25Cr_0.5Mn_0.5O_3-_δ-SDC//YSZ//La_0.75Sr_0.25Cr_0.5Mn_0.5O_3-_δ-SDC	800	CO₂	0.09	[36]
La_0.75Sr_0.25Cr_0.5Mn_0.5O_3-_δ-GDC//YSZ//La_0.8Sr_0.2MnO_3-_δ-ScSZ	800	70%CO₂-30%CO	0.16	[37]
LSF//LSGM//LSCF-SDC	800	CO₂	0.76	[39]
SFM//LSGM//LSCF-SDC	800	CO₂	0.71	[48]
SFM-SDC//LSGM//LSCF-SDC	800	CO₂	1.09	[48]
La_0.6Sr_0.4Fe_0.8Mn_0.2O_3-_δ//LSGM//Ba_0.6La_0.4CoO_3-_δ	800	50%CO₂-1%CO-49%Ar	0.21	[53]
La_0.3Sr_0.7Fe_0.7Cr_0.3O_3-_δ//YSZ//La_0.3Sr_0.7Fe_0.7Cr_0.3O_3-_δ	800	90%CO₂-10%CO	0.32	[43]
La_0.65Sr_0.3Ce_0.05Fe_0.7Cr_0.3O_3-_δ-YSZ//YSZ//LSCF-GDC	800	70%CO₂-30%CO	0.47	[54]
La_0.7Sr_0.3Fe_0.7Ti_0.3O_3-_δ//YSZ//La_0.7Sr_0.3Fe_0.7Ti_0.3O_3-_δ	800	CO₂	0.28	[45]
La_0.6Sr_0.4Fe_0.8Mn_0.2O_3-_δ//YSZ//La_0.6Sr_0.4Fe_0.8Mn_0.2O_3-_δ	800	CO₂	0.58	[41]
La_0.6Sr_0.4Fe_0.8Mn_0.2O_3-_δ//YSZ// LSCF-GDC	800	70%CO₂-30%CO	0.75	[42]
La_0.5Sr_0.5Fe_0.95V_0.05O_3-_δ-GDC//YSZ//La(Sr)MnO_3-_δ-YSZ	800	95%CO₂-5%N₂	0.55	[46]

固体氧化物电解池直接电解CO₂的研究进展

Recent Advances of CO₂ Electrochemical Reduction in Solid Oxide Electrolysis Cells

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 10

参考文献 67

相关文章 15

Metrics

[1]	陈浩杰, 唐美华, 陈胜利. 质子交换膜燃料电池阴极催化层疏水性优化[J]. 电化学（中英文）, 2023, 29(9): 2207061-.
[2]	邹庚, 冯炜程, 宋月锋, 汪国雄. 固体氧化物电解池阳极材料研究进展[J]. 电化学（中英文）, 2023, 29(2): 2215006-.
[3]	汪恒吉, 陈文国, 全周益, 赵凯, 孙毅飞, 陈旻, 奥坚科·弗拉基米尔. 多孔陶瓷支撑型管式固体氧化物电解池性能研究[J]. 电化学（中英文）, 2023, 29(12): 2204131-.
[4]	梁宵, 张可新, 沈雨澄, 孙轲, 石磊, 陈辉, 郑克岩, 邹晓新. 钙钛矿型水氧化电催化剂[J]. 电化学（中英文）, 2022, 28(9): 2214004-.
[5]	王睿卿, 隋升. PEMFC阴极催化层结构分析[J]. 电化学（中英文）, 2021, 27(6): 595-604.
[6]	杜立群, 温义奎, 关发龙, 翟科, 叶作彦, 王超. 移动阴极式掩膜电解加工微沟槽阵列均匀性研究[J]. 电化学（中英文）, 2021, 27(6): 658-670.
[7]	董文霞, 温广明, 刘斌, 李忠平. 基于Zr-MOFs光电化学传感用于同型半胱氨酸的检测[J]. 电化学（中英文）, 2021, 27(6): 681-688.
[8]	王伟国, 白天, 薛高飞, 叶美丹. CsPbIBr₂钙钛矿太阳能电池中通过氧气诱导Spiro-OMeTAD快速氧化[J]. 电化学（中英文）, 2021, 27(2): 216-226.
[9]	俞成荣, 朱建国, 蒋聪盈, 谷宇晨, 周晔欣, 李卓斌, 邬荣敏, 仲政, 官万兵. 基于电-化-热耦合理论对称双阴极固体氧化物燃料电池堆的电流与温度场数值模拟[J]. 电化学（中英文）, 2020, 26(6): 789-796.
[10]	邓博文, 尹华意, 汪的华. CO₂高效资源化利用的高温熔盐电化学技术研究[J]. 电化学（中英文）, 2020, 26(5): 628-638.
[11]	叶灵婷, 谢奎. 氧离子传导型固体氧化物电解池燃料电极的研究进展[J]. 电化学（中英文）, 2020, 26(2): 253-261.
[12]	韦童, 李箭, 贾礼超, 池波, 蒲健. 钙钛矿材料在固体氧化物燃料电池燃料重整中的应用[J]. 电化学（中英文）, 2020, 26(2): 198-211.
[13]	鲍晓囡, 张广君, 王绍荣. 阴极支撑型固体氧化物燃料电池的制备与测试[J]. 电化学（中英文）, 2020, 26(2): 190-197.
[14]	张文强, 于波. 高温固体氧化物电解制氢技术发展现状与展望[J]. 电化学（中英文）, 2020, 26(2): 212-229.
[15]	郑志林，袁晓姿，尹屹梅，马紫峰. 燃料电池反应器在化学品与电能共生中应用[J]. 电化学（中英文）, 2018, 24(6): 615-627.