电化学阻抗谱在质子交换膜燃料电池动态的先导应用

doi:10.13208/j.electrochem.180854

摘要/Abstract

摘要： 通过分析电化学阻抗（EIS）在质子交换膜燃料电池（PEMFC）动态应用，本文指出制约EIS 工具发展的瓶颈问题. EIS 高频电阻确定电池内阻已成普遍方法，但仅在小电流电池可以应用；低频分析因涉及物质传输仍是难点和重点；EIS 改进型Randles 等效电路分析已初步建立，并深入至物质传输-反应、电池操作/衰减、高温电池研究；EIS 正发展为电堆分析工具、电动汽车控制核心. 然而多学科交叉的暂态EIS 发展，仍是前沿突破难点.

关键词: 交流阻抗谱, 质子交换膜燃料电池, 动态运行, 电动汽车, 等效电路

Abstract: By analyzing Electrochemical Impedance Spectroscopy (EIS) in applications of dynamic proton exchange membrane fuel cell (PEMFC), bottlenecks which restrict EIS tool development have been pointed out in this paper. Though the high-frequency resistance in EIS is largely accepted as cell inner-resistance, this can only be applied for cell with low current. The low-frequency resistance is difficult to be realized due to its relation with mass transfer. Furthermore, the improved Randles equivalent circuits are built up preliminarily, thus, penetrating into studies for mass transfer reaction, cell operation/degeneration, and high temperature fuel cell. Inspiringly, EIS is becoming an analyzing tool for stack and control core for electric-vehicle. Nevertheless, it is still pioneer challenge to make breakthrough towards transient EIS method based on multi-discipline convergence

Key words: electrochemical impedance spectroscopy, proton exchange membrane fuel cell, dynamic operation, electric-vehicle;equivalent circuit

中图分类号:

O646
TM911.4

郭建伟，王建龙. 电化学阻抗谱在质子交换膜燃料电池动态的先导应用[J]. 电化学（中英文）, 2018, 24(6): 687-696.

GUO Jian-wei, WANG Jian-long . The Pilot Application of Electrochemical Impedance Spectroscopy on Dynamic Proton Exchange Membrane Fuel Cell[J]. Journal of Electrochemistry, 2018, 24(6): 687-696.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.180854

https://electrochem.xmu.edu.cn/CN/Y2018/V24/I6/687

参考文献

[1] Shi K M(史坤明), Guo J M(郭建伟), Wang J(王佳). Impedance of oxygen reduction reaction on Pt catalyst Pt/C[J]. Journal of Electrochemistry(电化学), 2016, 22(5): 542-548.
[2] Cai G X(蔡光旭), Guo J W(郭建伟), Wang J(王佳). The progress of electrochemical impedance spectroscopy (EIS) on the study of proton exchange membrane fuel cell[J]. Chemical Industry and Engineering Progress(化工进展), 2014, 33(1): 56-63.
[3] Cai G X, Guo J W, Wang J, et al. Negative resistance for methanol electro-oxidation on platinum/carbon (Pt/C) catalyst investigated by an electrochemical impedance spectroscopy[J]. Journal of Power Sources, 2015, 276(1): 279-290.
[4] Cao C N (曹楚南), Zhang J Q(张鉴清). An introduction to electrochemical impedance spectroscopy(电化学阻抗谱导论)[M]. Beijing: Science Press(科学出版社), 2002: 2.
[5] Giner-Sanz J J, Ortega E M, Pérez-Herranz V. Optimization of the electrochemical impedance spectroscopy measurement parameters for PEM fuel cell spectrum determination[J]. Electrochimica Acta, 2015, 174(1): 1290-1298.
[6] Xia S X, Lin R, Cui X, et al. The application of orthogonal test method in the parameters optimization of PEMFC under steady working condition[J]. International Journal of Hydrogen Energy, 2016, 41(26): 11380-11390.
[7] Rezaei Niya S M, Phillips R K, Hoorfar M. Sensitivity analysis of the impedance characteristics of proton exchange membrane fuel cells[J]. Fuel Cells, 2016, 16(5): 547-556.
[8] Chandesris M, Robin C, Gerard M, et al. Investigation of the difference between the low frequency limit of the impedance spectrum and the slope of the polarization curve[J]. Electrochimica Acta, 2015, 180(1): 581-590.
[9] Dotelli G, Ferrero R, Stampino P G, et al. Analysis and compensation of PEM fuel cell instabilities in low-frequency EIS Measurements[J]. IEEE Transactions on Instrumentation and Measurement, 2014, 63(7): 1693-1700.
[10] Guo J W(郭建伟)，Mao Z Q(毛宗强)，Xu J M(徐景明). Studies on the electrochemical behavior of polymer electrolyte membrane fuel cell (PEMFC) by AC impedance method[J]. Chemical Journal of Chinese Universities(高等学校化学学报), 2003, 24(8): 1477-1481.
[11] Li G C, Pickup P G. Measurement of single electrode potentials and impedances in hydrogen and direct methanol PEM fuel cells[J]. Electrochimica Acta, 2004, 49(24): 4119-4126.
[12] Engebretsen E, Hinds G, Meyer Q, et al. Localised electrochemical impedance measurements of a polymer electrolyte fuel cell using a reference electrode array to give cathode-specific measurements and examine membrane hydration dynamics[J]. Journal of Power Sources, 2018, 382(1): 38-44.
[13] Narayanan H, Basu S. Development of simple diagnostic tool for proton exchange membrane fuel cell using reference electrodes in sub cells in series[J]. International Journal of Hydrogen Energy, 2016, 41(18): 7659-7665.
[14] Mainka J, Maranzana G, Dillet J, et al. S. On the estimation of high frequency parameters of Proton Exchange Membrane Fuel Cells via Electrochemical Impedance Spectroscopy[J]. Journal of Power Sources, 2014, 253(1): 381-391.
[15] Mohammad S, Niya R, Hoorfar M. Process modeling of the ohmic loss in proton exchange membranefuel cells[J]. Electrochimica Acta, 2014, 120(1): 193-203.
[16] Depernet D, Narjiss A, Gustin F, et al. Integration of electrochemical impedance spectroscopy functionality in proton exchange membrane fuel cell power converter[J]. International Journal of Hydrogen Energy, 2016, 41(11): 5378-5388.
[17] Futter G A, Gazdzicki P, Friedrich K A, et al. Physical modeling of polymer-electrolyte membrane fuel cells: Understanding water management and impedance spectra[J]. Journal of Power Sources, 2018, 391(1): 148-161.
[18] Jin B D(金宝舵), Guo J W(郭建伟), Xie X F(谢晓峰), et al. Effect of operating condition on cathodic EIS parameters in a DMFC[J]. Chemical Journal of Chinese Universities(高等学校化学学报), 2008, 29(11): 2258-2261.
[19] Li J C(黎家纯), Xie X F(谢晓峰), Guo J W(郭建伟), et al. Research of AC impedance of dynamic behavior of direct methanol fuel cell[J]. Chemical Journal of Chinese Universities(高等学校化学学报), 2008, 29(3): 564-568.
[20] Yang D J(杨代军), Wang F J(汪飞杰), Li B(李冰), et al. Accelerated aging test and performance recovery analysis of PEMFC stack[J]. Journal of TongJi University(Natural Science) (同济大学学报(自然科学版)), 2015, 43(2): 273-278.
[21] Hong P, Li J Q, Xu L F, et al. Modeling and simulation of parallel DC/DC converters for online AC impedance estimation of PEM fuel cell stack[J]. International Journal of Hydrogen Energy, 2016, 41(4): 3004-3014.
[22] Ferreira R B, Falc?觔o D S, Oliveira V B, et al. Experimental study on the membrane electrode assembly of a proton exchange membrane fuel cell: Effects of microporous layer, membrane thickness and gas diffusion layer hydrophobic treatment[J]. Electrochimica Acta, 2017, 224 (1): 337-345.
[23] Latorrata S, Pelosato R, Stampino P G, et al. Use of electrochemical impedance spectroscopy for the evaluation of performance of PEM fuel cells based on carbon cloth gas diffusion electrodes[J]. Journal of Spectroscopy, 2018, 3254375.
[24] Boaventura M, Alves I, Ribeirinha P, et al. The influence of impurities in high temperature polymer electrolyte membrane fuel cells performance[J]. International Journal of Hydrogen Energy, 2016, 41(43): 19771-19780.
[25] Park T, Chang I, Lee Y H, et al. Analysis of operational characteristics of polymer electrolyte fuel cell with expanded graphite flow-field plates via electrochemical impedance investigation[J]. Energy, 2014, 66(1): 77-81.
[26] Hu M, Cao G. Research on the performance differences between a standard PEMFC single cell and transparent PEMFC single cells using optimized transparent flow field unite Part I: Design optimization of a transparent flow field unit[J]. International Journal of Hydrogen Energy, 2016 ,41(4): 2955 -2966.
[27] Hu M, Cao G. Research on the performance differences between a standard PEMFC single cell and transparent PEMFC single cells using optimized transparent flow field unite，Part II: Performance comparison and explanation[J]. International Journal of Hydrogen Energy, 2016, 41(4): 2967-2980.
[28] Antonacci P, Leea J, Yip R, et al. Identifying water thickness in various layers in PEMFCs through EIS and X-ray radiography[J]. ECS Transactions, 2014, 61(12): 57-67.
[29] Kong I M, Jung A, Kim M S. Investigations on the double gas diffusion backing layer for performance improvement of self-humidified proton exchange membrane fuel cells[J]. Applied Energy, 2016, 176(1): 149-156.
[30] Wang Z Q, Qu L J, Zeng Y C, et al. Investigation of water transport in fuel cells using water transport plates and solid plates[J]. RSC Advances, 2018, 8(3): 1503-1510.
[31] Jao T C, Sasabe T, Uemura S, et al. Temperature and humidification effect on mass transfer of PEMFC via EIS and soft X-ray measurement[J]. ECS Transactions, 2016, 75(14): 179-188.
[32] Tant S, Rosini S, Thivel P X, et al. An algorithm for diagnosis of proton exchange membrane fuel cells by electrochemical impedance spectroscopy[J]. Electrochimica Acta, 2014, 135(1): 368-379.
[33] Zhiani M, Majidi S, Silva V B, et al. Comparison of the performance and EIS (electrochemical impedance spectroscopy) response of an activated PEMFC (proton exchange membrane fuel cell) under low and high thermal and pressure stresses[J]. Energy, 2016, 97(1): 560-567.
[34] Zhang Q, Lin R, Techer L, et al. Experimental study of variable operating parameters effects on overall PEMFC performance and spatial performance distribution[J]. Energy, 2016, 115(1): 550-560.
[35] Rohendi D, Majlan E H, Mohamad A B, et al. Effects of temperature and backpressure on the performance degradation of MEA in PEMFC[J]. International Journal of Hydrogen Energy, 2015, 40(34): 10960-10968.
[36] Asghari S, Reza M, Khorasani A, et al. Investigation of self-humidified and dead-ended anode proton exchange membrane fuel cell performance using electrochemical impedance spectroscopy[J]. International Journal of Hydrogen Energy, 2016,41(28): 12347-12357.
[37] Strahl S, Husar A, Riera J. Experimental study of hydrogen purge effects on performance and efficiency of an open-cathode proton exchange membrane fuel cell system[J]. Journal of Power Sources, 2014, 248(1): 474-482.
[38] Tang Y F, Mu S C, Yu S X, et al. In situ and ex situ studies on the degradation of Pd/C catalyst for proton exchange membrane fuel cells[J]. Journal of Fuel Cell Science and Technology, 2014, 11(5): 051004.
[39] Zhang X, Guo L J, Liu H T. Recovery mechanisms in proton exchange membrane fuel cells after accelerated stress tests[J]. Journal of Power Sources, 2015, 296(1): 327-334.
[40] Wang F J, Yang D J, Li B, et al. Investigation of the recoverable degradation of PEM fuel cell operated under drive cycle and different humidities[J]. International Journal of Hydrogen Energy, 2014, 39(26): 14441-14447.
[41] Shi W Y(石伟玉), Liu C F(刘常福), Mu J Y(慕竣屹), et al. Long term test and analysis of PEMFCs under simulation on-road load cycles[J]. Chinese Journal of Power Sources(电源技术), 2016, 40(1): 77-80.
[42] Lin R, Cui X, Shan J, et al. Investigating the effect of start-up and shut-down cycles on the performance of the proton exchange membrane fuel cell by segmented cell technology[J]. International Journal of Hydrogen Energy, 2015, 40(43): 14952-14962.
[43] Liu M Y, Wang C, Zhang J B, et al. Diagnosis of membrane electrode assembly degradation with drive cycle test technique[J]. International Journal of Hydrogen Energy, 2014, 39(26): 14370-14375.
[44] Strahl S, Gasamans N, Llorca J, et al. Experimental analysis of a degraded open-cathode PEM fuel cell stack[J]. International Journal of Hydrogen Energy, 2014, 39(10): 5378-5387.
[45] Yang Y P, Zhang X, Guo L J, et al. Degradation mitigation effects of pressure swing in proton exchange membrane fuel cells with dead-ended anode[J]. International Journal of Hydrogen Energy, 2017, 42(38): 24435-24447.
[46] Zhou S(周苏), Han Q L(韩秋玲), Hu Z(胡哲). Pattern recognition method for proton exchange membrane fuel cell fault diagnosis[J]. Journal of TongJi University(Natural Science) (同济大学学报(自然科学版)), 2017, 45(3): 408-412.
[47] Su H, Jao T C, Barron O, et al. Low platinum loading for high temperature proton exchange membrane fuel cell developed by ultrasonic spray coating technique[J]. Journal of Power Sources, 2014, 267(1): 155-159.
[48] Mack F, Laukenmann R, Galbiati S, et al. Electrochemical impedance spectroscopy as a diagnostic tool for high-temperature PEM fuel cells[J]. ECS Transactions, 2015, 69(17): 1075-1087.
[49] Giotakos P I. Neophytides simulation of HT-PEMFC AC impedance spectra: Relaxation impedance and identification of oxygen reduction reaction mechanism[J]. ECS Transactions, 2017, 80(8): 37-56.
[50] Chen C Y, Huang K P, Yan W M, et al. Development and performance diagnosis of a high power air-cooled PEMFC stack[J]. International Journal of Hydrogen Energy, 2016, 41(27): 11784-11793.
[51] Shan J, Lin R, Xia S X, et al. Local resolved investigation of PEMFC performance degradation mechanism during dynamic driving cycle[J]. International Journal of Hydrogen Energy, 2016, 41(7): 4239 -4250.
[52] Meyer Q, Ashton S, Curnick O, et al. Dead-ended anode polymer electrolyte fuel cell stack operation investigated using electrochemical impedance spectroscopy, off-gas analysis and thermal imaging[J]. Journal of Power Sources, 2014, 254(1): 1-9.
[53] Lechartier E, Laffly E, Pera M C, et al. Proton exchange membrane fuel cell behavioral model suitable for prognostics[J]. International Journal of Hydrogen Energy, 2015, 40(26): 8384-8397.
[54] Chevalier S, Auvity B, Olivier J C, et al. Detection of cells state-of-health in PEM fuel cell stack using EIS measurements coupled with multi physics modeling[J]. Fuel Cells, 2014, 14(3): 416-429.
[55] Homayouni H, DeVaal J, Golnaraghi F, et al. Voltage reduction technique for use with electrochemical impedance spectroscopy in high-voltage fuel cell and battery systems[J]. IEEE Transactions on Transportation Electrification, 2018, 4(2): 418-431.
[56] Niya S M R, Hoorfar M. Measurement, semi-process and process modeling of proton exchange membrane fuel cells[J]. International Journal of Hydrogen Energy, 2015, 40(14): 4868-4873.
[57] Ritzberger D, Jakubek S. Nonlinear data-driven identification of polymer electrolyte membrane fuel cells for diagnostic purposes: A Volterra series approach[J]. Journal of Power Sources, 2017, 361(1): 144-152.
[58] Russo L, Sorrentino M, Polverino P, et al. Application of Buckingham π theorem for scaling-up oriented fast modelling of Proton Exchange Membrane Fuel Cell impedance[J]. Journal of Power Sources, 2017, 353(1): 277-286.
[59] Sorrentino A, Vidakovic-Kocha T, Hanke-Rauschenbachc R, et al. Concentration-alternating frequency response: A new method for studying polymer electrolyte membrane fuel cell dynamics[J]. Electrochimica Acta, 2017, 243(1): 53-64.