Li2FeSiO4/C正极材料的固相合成及电化学性能

doi:10.13208/j.electrochem.130352

电化学（中英文） ›› 2013, Vol. 19 ›› Issue (6): 575-578. doi: 10.13208/j.electrochem.130352

• 锂离子电池近期研究专辑 (厦门大学杨勇教授主编) • 上一篇下一篇

Li₂FeSiO₄/C正极材料的固相合成及电化学性能

孙姣丽¹，陈志娇¹，李益孝²，程琥^1*

1. 贵州师范大学化学与材料科学学院，贵州贵阳 550001；2. 厦门大学化学化工学院化学系，福建厦门 361005

收稿日期:2013-03-05 修回日期:2013-05-27 出版日期:2013-12-28 发布日期:2013-12-23
通讯作者: 程琥 E-mail:chenghu8802@163.com
基金资助:
贵州省重大专项（黔科合重大专项字[2011]6015）及贵州省科学技术基金（黔科合J字[2012]2284）资助

Synthesis and Electrochemical Property of Li₂FeSiO₄/C Cathode Material by Solid State Method

SUN Jiao-li¹, CHEN Zhi-jiao¹, LI Yi-xiao², CHENG Hu^1*

1. School of Chemistry and Material Science, Guizhou Normal University, Guiyang 550001, Guizhou, China; 2. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China

Received:2013-03-05 Revised:2013-05-27 Published:2013-12-28 Online:2013-12-23
Contact: CHENG Hu E-mail:chenghu8802@163.com

摘要/Abstract

摘要： 以偏硅酸锂、草酸亚铁为原料，通过机械球磨-固相烧结法制得了Li₂FeSiO₄/C正极材料. 用X射线衍射（XRD）和扫描电子显微镜（SEM）表征观察材料的结构和形貌.恒流充放电测试电极电化学性能. 结果表明，30 oC下，1.5 V ～ 4.8 V电位范围，于10 mAg^-1电流密度恒流充放电测试，Li₂FeSiO₄/C电极首次放电容量达167 mAhg^-1，有良好的电化学性能.

关键词: Li2FeSiO4, 正极材料, 锂离子电池

Abstract: Li2FeSiO4/C cathode material was synthesized using Li₂SiO₃ and FeC₂O₄ as raw materials by solid state method. The structure and morphology of the material were characterized by XRD and SEM. The electrochemical properties of the material were studied by constant-current cyclic testing. The results show that Li₂FeSiO₄/C has a good electrochemical performance. The first discharge capacity of Li₂FeSiO₄/C cathode material at 30oC reached 167 mAhg^-1 when cycled at 10 mAg^-1 between 1.5 and 4.8 V.

Key words: Li2FeSiO4, cathode material, lithium ion battery

中图分类号:

O646.54

孙姣丽，陈志娇，李益孝，程琥*. Li₂FeSiO₄/C正极材料的固相合成及电化学性能[J]. 电化学（中英文）, 2013, 19(6): 575-578.

SUN Jiao-li, CHEN Zhi-jiao, LI Yi-xiao, CHENG Hu*. Synthesis and Electrochemical Property of Li₂FeSiO₄/C Cathode Material by Solid State Method[J]. Journal of Electrochemistry, 2013, 19(6): 575-578.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.130352

https://electrochem.xmu.edu.cn/CN/Y2013/V19/I6/575

参考文献

[1] Padhi A K, Nanjundaswamy K S, Goodenough J B. Phospho-olivines as positive-electrode materials for rechargeable lithium batteries[J]. Journal of Electrochemical Society, 1997, 144(4): 1188-1194.
[2] Nyten A, Abouimrane A, Armand M. Electrochemical performance of Li2FeSiO4 as a new Li-battery cathode material[J]. Electrochemistry Communications, 2005, 7(2): 156-160.
[3] Arroyo-de Dompablo M E, Armand M, Tarascon J M. On-demand design of polyoxianionic cathode materials based on electronegativity correlations: An exploration of the Li2MSiO4 system (M = Fe, Mn, Co, Ni)[J]. Electrochemistry Communications, 2006, 8(8): 1292-1298.
[4] Dominko R, Bele M, Gaberscek M. Structure and electrochemical performance of Li2MnSiO4 and Li2FeSiO4 as potential Li-battery cathode materials[J]. Electrochemistry Communications, 2006, 8(2): 217-222.
[5] Armand M, Michot C, Ravet N, et al. Lithium insertion electrode material based on orthosilicate derives: US, 6085015[P]. 2000-07-04.
[6] Zaghib K, Salah A A, Ravet N, et al. Structure, magnetic and electrochemical properties of lithium iron orthosilicate[J]. Journal of Power Sources, 2006, 160(2): 1381-1386.
[7] Kam K C, Gustafsson T, Thomas J O. Synthesis and electrochemical properties of nanostructured Li2FeSiO4/C cathode material for Li-ion batteries[J]. Solid State Ionics, 2011, 192(S1): 356-359.
[8] Guo H J, Xiang K X, Cao X, et al. Preparation and characteristics of Li2FeSiO4/C composite for cathode of lithium ion batteries[J]. Transactions of Nonferrous Metals Society of China, 2009, 19(1): 166-169.
[9] Nyten A, Kamali S, Gustafsson T, et al. The lithium extraction/insertion mechanism in Li2FeSiO4[J]. Journal of Materials Chemistry, 2006, 16(23): 2266-2272.
[10] Dominko R. Li2MSiO4 (M = Fe and/ or Mn) cathode materials[J]. Journal of Power Sources, 2008, 184(2): 462-468.
[11] Gong Z L, Li Y X, He G N, et al. Nanostructured Li2FeSiO4 electrode material synthesized through hydrothermal-assisted sol-gel process[J]. Electrochemical and Solid-State Letters, 2008, 11(5): A60-A63.
[12] Deng C, Zhang S, Fu B L, et al. Characterization of Li2MnSiO4 and Li2FeSiO4 cathode materials synthesized via a citric acid assisted sol-gel method[J]. Materials Chemistry and Physics, 2010, 120(1): 14-17.
[13] Lv D P, Wen W, Yang Y, et al. A novel Li2FeSiO4/C composite: Synthesis, characterization and high storage capacity[J]. Journal of Materials Chemistry, 2011, 21(26): 9506-9512.
[14] Dominko R, Conte D E, Hanzel D, et al. Impact of synthesis conditions on the structure and performance of Li2FeSiO4[J]. Journal of Power Sources, 2008, 178(2): 842-847.
[15] Yabuuchi N, Yamakawa Y, Yoshii K, et al. Hydrothermal synthesis and characterization of Li2FeSiO4 as positive electrode materials for Li-ion batteries[J]. Electrochemistry, 2010, 78(5): 363-366.
[16] Peng Z D, Cao Y B, Hu G R, et al. Microwave synthesis of Li2FeSiO4 cathode materials for lithium-ion batteries[J]. Chinese Chemical Letters, 2009, 20(8): 1000-1004.

Li₂FeSiO₄/C正极材料的固相合成及电化学性能

Synthesis and Electrochemical Property of Li₂FeSiO₄/C Cathode Material by Solid State Method

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