欢迎访问《电化学(中英文)》期刊官方网站,今天是

电化学(中英文) ›› 2011, Vol. 17 ›› Issue (4): 363-365.  doi: 10.61558/2993-074X.2855

• 研究快讯 • 上一篇    下一篇

锂离子电池纳米氧化镍负极的制备及应用

白成栋,  陈嘉嘉,  张琦, 郑明森,  董全峰*   

  1. 厦门大学固体表面物理化学国家重点实验室,福建厦门361005
  • 收稿日期:2011-07-27 修回日期:2011-08-06 出版日期:2011-11-28 发布日期:2011-09-10
  • 通讯作者: 董全峰 E-mail:qfdong@xmu.edu.cn

Preparation and Application of nano-NiO as Anode in Lithium-ion Batteries

 BAI  Cheng-Dong, CHEN  Jia-Jia, ZHANG  Qi, ZHENG  Ming-Sen, DONG  Quan-Feng*   

  1. Chemistry department, College of Chemistry and Chemical Engineering, Xiamen University, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen, Fujian,361005 ,China
  • Received:2011-07-27 Revised:2011-08-06 Published:2011-11-28 Online:2011-09-10
  • Contact: DONG Quan-Feng E-mail:qfdong@xmu.edu.cn

摘要: 通过水热法制备了纳米氧化镍,并观察了样品形貌及研究电极电化学性能。在水热合成过程加入表面活性剂,可形成疏松多孔,表面呈蜂窝状,颗粒均匀(100-200nm)的纳米氧化镍。结果表明:0.1A/g电流密度,纳米NiO电极首周期放电比容量高达2385.7 mAh/g, 100周期之后电极比容量仍然稳定于1100mAh/g。2.0A/g电流密度,电极放电比容量为600mAh/g。又调回0.1A/g电流密度,电极放电比容量仍可恢复至1050mAh/g。该电极有优异的循环寿命和倍率性能。

关键词: 纳米氧化镍, 锂离子电池, 负极材料

Abstract: In this work, the nano-NiO material was prepared by hydrothermal method. The surface morphologies and electrochemical properties of nano-NiO material were investigated. The special nano-NiO material with porous surface assembling honeycombs(100-200nm) was obtained by using surface active agents. The discharge capacity of nano-NiO electrode up to 2385.7 mAh/g was achieved at current density of 0.1A/g in the first circle,while 1100mAh/g could be maintained after 100 circles. At current density of 2.0A/g, the discharge capacity of 600 mAh/g was obtained. And when the current density was reduced to 0.1A/g, the discharge capacity was restored to 1050 mAh/g. The nano-NiO electrode exhibited excellent cycling performance and rate capability.

中图分类号: