锌多面体微球制备及其在碱性锌锰电池中的应用

电化学（中英文） ›› 2006, Vol. 12 ›› Issue (2): 140-143.

锌多面体微球制备及其在碱性锌锰电池中的应用

马华;李春生;程方益;周春远;高峰;陈军;

南开大学新能源材料化学研究所,南开大学新能源材料化学研究所,南开大学新能源材料化学研究所,南开大学新能源材料化学研究所,南开大学新能源材料化学研究所,南开大学新能源材料化学研究所天津300071,天津300071,天津300071,天津300071,天津300071,天津300071

收稿日期:2006-05-28 修回日期:2006-05-28 出版日期:2006-05-28 发布日期:2006-05-28

Synthesis of Zinc Polyhedral Microspheres and Applications in Alkaline Zn-MnO_(2)Battery

MA Hua,LI Chun-sheng,CHENG Fang-yi,ZHOU Chun-yuan,GAO Feng,CHEN Jun~

(*)(Institute of New Energy Material Chemistry,Nankai University,Tianjin 300071,China

Received:2006-05-28 Revised:2006-05-28 Published:2006-05-28 Online:2006-05-28

摘要/Abstract

摘要： 应用加热蒸发高纯锌粉气相传输法,制备锌多面体微球.产物的结构和形貌经XRD、SEM等测试表征,结果表明与该产物为结晶度较好的直径2~3μm的多面体微球.分别以所制锌微球或市售熔融锌作负极,γ-MnO2纳米线为正极,组装AA型碱性锌锰电池.电化学测试表明以锌微球为负极的碱性锌锰电池能显著提高其放电性能,100 mA下的放电容量达到3.14 Ah,显示出它在高能化学电源领域的应用前景.

关键词: 锌, 微球, 锌锰电池, 气相传输

Abstract: The zinc polyhedral microspheres were synthesized by evaporation of pure zinc powders via a vapor-transport process.The results characterized by XRD and SEM show that the as-synthesized zinc powders are polyhedral microspheres with the diameter of 2~3 μm.The electrochemical investigation showed that the capacity of the as-assembled AA-size primary alkaline Zn-MnO_(2)battery was increased to 3.14 Ah under the constant discharge current of 100 mA by using the as-deposited microspherical zinc powders as the anode active materials and γ-MnO_(2)nanowires as the cathode active materials,indicating their potential application in high-energy batteries.

Key words: Zinc, Microsphere, Zn-MnO_(2)battery, Vapor-transport

中图分类号:

TM911

马华;李春生;程方益;周春远;高峰;陈军;. 锌多面体微球制备及其在碱性锌锰电池中的应用[J]. 电化学（中英文）, 2006, 12(2): 140-143.

MA Hua,LI Chun-sheng,CHENG Fang-yi,ZHOU Chun-yuan,GAO Feng,CHEN Jun~. Synthesis of Zinc Polyhedral Microspheres and Applications in Alkaline Zn-MnO_(2)Battery[J]. Journal of Electrochemistry, 2006, 12(2): 140-143.

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链接本文: https://electrochem.xmu.edu.cn/CN/

https://electrochem.xmu.edu.cn/CN/Y2006/V12/I2/140

参考文献

[1]W inter M,B rodd R J.W hat are batteries,fuel cells,and supercapac itors?[J].Chem.Rev.,2004,104(10):4245~4269. [2]Yang C C,L in S J.Improvem ent of h igh-rate capalilityof alkaline Zn-MnO2battery[J].J.Power Sources,2002,112(1):174~783. [3]Yuan Guo-Hu i(袁国辉),Chu De-W e i(褚德威),ShenR i-Hu i(申日辉),et al.Study of the mod ified electro-lytic m anganese d ioxide[J].E lectrochem istry(in Ch i-nese),1995,1(4):446~450. [4]L iu L ing(刘玲),X ia X i(夏熙).Stud ies on the prepa-ration of nanophase electrode m aterials and its electro-chem ical properties(Ш)[J].E lectrochem istry(in Ch i-nese),1998,4(3):328~333. [5]L iang H P,Zhang H M,Hu J S,et al.Pt hollow nano-spheres:fac ile synthesis and enhanced electrocatalysts[J].Angew.Chem.Int.Ed.,2004,43(12):1540~1543. [6]Chen W,Sun S G,S i D,et al.E lectrocatalytic proper-ties of agglom erates of Pt nanopartic les in m ethanol oxi-dation[J].Acta Phys.-Ch im.S in.,2003,19(5):441~444. [7]Zhao J,Gao Q Y,Gu C,et al.Preparation of mu lti-walled carbon nanotube array electrodes and its electro-chem ical intercalation behavior of L i ions[J].Chem.Phys.Lett.,2002,358(1~2):77~82. [8]Chen J,Xu L N,L iW Y,et al.α-Fe2O3nanotubes ingas sensor and lith ium-ion battery app lications[J].Adv.M ater.,2005,17(5):582~586. [9]Cai F S,Zhang G Y,Chen J,et al.N i(OH)2tubesw ith m esoscale d im ensions as positive-electrode m aterialsof alkaline rechargeab le batteries[J].Angew.Chem.Int.Ed.,2004,43(32):4212~4216. [10]Cheng F Y,Chen J,Gou X L,et al.H igh-power alka-line Zn-MnO2batteries usingγ-MnO2nanow ires/nano-tubes and electrolytic zinc powder[J].Adv.M ater.,2005,17(22):2753~2756. [11]W en X G,Fang Y P,Yang S H.Synthesis of u ltrath inzinc nanow ires and nanotubes by vapor transport[J].Angew.Chem.Int.Ed.,2005,44(23):3562~3565. [12]Yang H X,Cao Y L,A i X P,et al.Improved d is-charge capac ity and suppressed surface passivation ofzinc anode in d ilute alkaline solution using surfactantadd itives[J].J.Power Sources,2004,128(1):97~101. [13]Ravindran V,Muralidharan V S,Cathod ic processeson zinc in alkaline zincate solutions[J].J.PowerSources,1995,55(2):237~241.

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