用于光催化和电化学应用的纳米结构石墨氮化碳

doi:10.61558/2993-074X.3498

电化学（中英文） ›› 2025, Vol. 31 ›› Issue (1): 2416001. doi: 10.61558/2993-074X.3498

• 综述 • 上一篇

用于光催化和电化学应用的纳米结构石墨氮化碳

Muhammad Abdul Qadeer^a^,^b^,^c, Iqra Fareed^d, Asif Hussain^e, Muhammad Asim Farid^f, Sadia Nazir^e, Faheem K. Butt^g, 邹吉军^a^,^*(), Muhammad Tahir^g^,^h^,^*, Shangfeng Du^h

^a天津大学化工学院，天津 300072，中国
^b西安交通大学化学工程与技术学院，西安 710049，中国
^c奇纳布大学物理科学系，古吉拉特邦 50700，旁遮普邦，巴基斯坦
^d生态材料和可持续技术实验室（LEMST），自然科学和人文系，新校区，UET 拉合尔，54890，巴基斯坦
^e拉合尔大学物理系，巴基斯坦拉合尔
^f教育大学科学技术部化学系，54770 拉合尔，巴基斯坦
^g教育大学科学技术部物理系，54770 拉合尔，巴基斯坦
^h伯明翰大学化学工程学院，伯明翰 B15 2TT，英国

收稿日期:2024-05-30 修回日期:2024-08-07 接受日期:2024-09-25 出版日期:2024-09-25 发布日期:2024-09-25
通讯作者: 邹吉军,Muhammad Tahir E-mail:jj_zou@tju.edu.cn

Nanostructured Graphitic Carbon Nitride for Photocatalytic and Electrochemical Applications

Abdul Qadeer Muhammad^a^,^b^,^c, Fareed Iqra^d, Hussain Asif^e, Asim Farid Muhammad^f, Nazir Sadia^e, K. Butt Faheem^g, Zou Ji-Jun^a^,^*(), Tahir Muhammad^g^,^h^,^*, Du Shang-Feng^h

^aSchool of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
^bSchool of Chemical Engineering and Technology, Xi’an Jiaotong University, Xi’an 710049, China
^cDepartment of Physical Sciences, The University of Chenab Adjacent Chenab Bridge, Gujrat 50700, Punjab, Pakistan
^dLaboratory of Eco-Materials and Sustainable Technology (LEMST), Natural Sciences and Humanities Department, New Campus, UET Lahore, 54890, Pakistan
^eDepartment of Physics, The University of Lahore, Lahore, Pakistan
^fDepartment of Chemistry, Division of Science & Technology, University of Education, 54770 Lahore, Pakistan
^gDepartment of Physics, Division of Science & Technology, University of Education, 54770 Lahore, Pakistan
^hSchool of Chemical Engineering, University of Birmingham, Birmingham B15 2TT, UK.

Received:2024-05-30 Revised:2024-08-07 Accepted:2024-09-25 Published:2024-09-25 Online:2024-09-25
Contact: Zou Ji-Jun, Tahir Muhammad E-mail:jj_zou@tju.edu.cn
About author:First author contact:
^#Muhammad Abdul Qadeer, Iqra Fareed, these authors contributed equally.

摘要/Abstract

摘要：

石墨氮化碳（g-C₃N₄）因其出色的机械和热学特性而成为一种有价值的材料，可应用于光电转换器件、有机化合物合成的加速器、燃料电池应用或电源的电解质，以及储氢物质和荧光检测器等领域。g-C₃N₄可以采用不同的方法制备，且可得到多种形态和纳米结构，如为不同用途而设计的零到三维材料。近年来关于g-C₃N₄的报道很多，但缺乏涵盖纳米结构尺寸及其性质的全面综述。本文旨在对g-C₃N₄的光催化和电催化用途提供基本和全面的了解。通过涵盖合成方法、尺寸、形貌、应用和性能，重点介绍了g-C₃N₄纳米结构设计的最新进展。除了总结之外，我们还将讨论挑战和前景。从事g-C₃N₄纳米结构相关研究及各种应用的科学家、研究人员和工程师可能会发现我们的综述论文是有用的资源。

关键词: 石墨氮化碳, 氢析出反应, 氧析出反应, 燃料电池, 可持续能源, 电催化剂

Abstract:

Graphitic carbon nitride (g-C₃N₄) exhibits great mechanical as well as thermal characteristics, making it a valuable material for use in photoelectric conversion devices, an accelerator for synthesis of organic compounds, an electrolyte for fuel cell applications or power sources, and a hydrogen storage substance and a fluorescence detector. It is fabricated using different methods, and there is a variety of morphologies and nanostructures such as zero to three dimensions that have been designed for different purposes. There are many reports about g-C₃N₄in recent years, but a comprehensive review which covers nanostructure dimensions and their properties are missing. This review paper aims to give basic and comprehensive understanding of the photocatalytic and electrocatalytic usages of g-C₃N₄. It highlights the recent progress of g-C₃N₄nanostructure designing by covering synthesis methods, dimensions, morphologies, applications and properties. Along with the summary, we will also discuss the challenges and prospects. Scientists, investigators, and engineers looking at g-C₃N₄nanostructures for a variety of applications might find our review paper to be a useful resource.

Key words: Graphitic carbon nitride, HER, OER, Fuel Cell, Sustainable energy, electrocatalyst

Muhammad Abdul Qadeer, Iqra Fareed, Asif Hussain, Muhammad Asim Farid, Sadia Nazir, Faheem K. Butt, 邹吉军, Muhammad Tahir, Shangfeng Du. 用于光催化和电化学应用的纳米结构石墨氮化碳[J]. 电化学（中英文）, 2025, 31(1): 2416001.

Abdul Qadeer Muhammad, Fareed Iqra, Hussain Asif, Asim Farid Muhammad, Nazir Sadia, K. Butt Faheem, Zou Ji-Jun, Tahir Muhammad, Du Shang-Feng. Nanostructured Graphitic Carbon Nitride for Photocatalytic and Electrochemical Applications[J]. Journal of Electrochemistry, 2025, 31(1): 2416001.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.61558/2993-074X.3498

https://electrochem.xmu.edu.cn/CN/Y2025/V31/I1/2416001

图/表 10

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Catalyst	Synthesis Method	Junction Type	Pollutant Type with Efficiency	Ref.
Gr/g-C₃N₄	Calcination	2D/2D, Heterojunction	Nizatidine, 87% Ranitidine, 85%	[97]
GO/g-C₃N₄-ZnO	Hydrothermal	2D Heterojunction-n	MB, 93.9%	[98]
BiOBr/rGO/pg-C₃N₄	Solvothermal	Z- scheme	rhodamine B 88% tetracycline 59%	[99]
³D-²D-3D BiOI/porous gC₃N₄/graphene hydrogel	Ultrasonication/ hydrothermal	³D-²D-3D Heterojunction-n	MB, 28.1	[99]
g-C₃N_4/rGO	Hydrazine hydrate method	2D/2D, Heterojunction	Methyl orange, 92% Tetracycline, 90%	[100]

Catalyst	Cocatalyst/ Counter/Ref. Electrode	Junction Type/Doping	HER Activity/(μmol·h⁻¹·g⁻¹)	Ref.
g-C₃N₄/NiTe₂	TEOA	S-scheme	2540.4	[114]
GO/g-C₃N₄-ZnO	3 wt% Pt	Doping	1021	[115]
Ru/TP-Ru/EC₃N₄	3 wt% Pt		2562.5	[116]
Au-Pd_0.6/COCN-2	Pt and an Ag/AgCl	Loading	5089	[117]
g-C₃N₄/BiVO₄	Hydrothermal	Z-scheme	80.7	[118]
COF/g-C₃N₄	Hydrazine hydrate method	Covalent Organic Framework	27540	[119]
IEF-11/g-C₃N₄	No. catalysts	S-Scheme Heterojunction	576	[120]
g-C₃N₄	TEOA; 5wt% chloroplatinic acid	Carbon vacancies	972.3	[121]

用于光催化和电化学应用的纳米结构石墨氮化碳

Nanostructured Graphitic Carbon Nitride for Photocatalytic and Electrochemical Applications

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