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电化学(中英文) ›› 2016, Vol. 22 ›› Issue (1): 1-19.  doi: 10.13208/j.electrochem.150847

• 邀请论文 •    下一篇

电化学法制备石墨烯及其复合材料

赵 波1,2,姜 莉1,袁铭辉3,符显珠1*,孙 蓉1*,汪正平4   

  1. 1. 中国科学院深圳先进技术研究院,深圳市高密度电子封装材料与器件重点实验室,广东 深圳 518055;2. 中国科学院大学深圳先进技术学院,北京 100049;3. 香港科技大学机械工程学院,香港 999077;4. 佐治亚理工学院材料科学与工程系,美国 亚特兰大 30332
  • 收稿日期:2015-11-07 修回日期:2015-12-07 出版日期:2016-02-29 发布日期:2016-02-29
  • 通讯作者: 符显珠,孙 蓉 E-mail:xz.fu@siat.ac.cn, rong.sun@siat.ac.cn
  • 基金资助:

    国家自然科学基金项目(No. 21203236)、广东省引进创新科研团队计划项目(No. 2011D052,No. KYPT20121228160843692)、深圳市高密度电子封装材料与器件重点实验室项目(No. ZDSYS20140509174237196)及深圳市孔雀计划项目(No. KQCX2015033117354154)资助

Electrochemical Syntheses of Graphene and Its Composites

ZHAO Bo1,2, JIANG Li1, YUEN Ming-hui3, FU Xian-zhu1*, SUN Rong1*, WONG Ching-Ping4   

  1. 1. Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China; 2. Shenzhen College of Advanced Technology,University of Chinese Academy of Sciences,Beijing 100049, China; 3. Department of Mechanical Engineering, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong 999077, China; 4. School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, United States
  • Received:2015-11-07 Revised:2015-12-07 Published:2016-02-29 Online:2016-02-29
  • Contact: FU Xian-zhu, SUN Rong E-mail:xz.fu@siat.ac.cn, rong.sun@siat.ac.cn

摘要:

石墨烯是一种具有优异物理和化学性质的新型二维碳纳米材料,大规模低成本制备高品质石墨烯的方法是其能够得到广泛实际应用的重要前提. 电化学方法可以快捷、绿色无污染、批量制备高质量的石墨烯及其复合材料. 本综述在对石墨烯各种制备方法进行简要比较之后,对近年来石墨烯、石墨烯/无机纳米复合材料、石墨烯/聚合物复合材料以及类石墨烯材料的电化学法制备进展进行介绍并作了展望.

关键词: 石墨烯, 石墨烯复合材料, 电化学剥离, 电化学氧化, 电化学还原

Abstract:

Graphene is a kind of ideal two-dimensional flat carbon nanomaterials which have unique chemical and physical properties. The attractive potential applications must be based on the high quality mass production of graphene. However, it remains a huge challenge.An electrochemical approach is a fast, environmental friendly and easy-operating method. single- or multi-layered graphene flakes can easily be produced in short periods of time. In this review, the structure, properties and preparation methods of graphene are first introduced. Accordingly,  the electrochemical approaches used for the productions of graphene flakes,graphene/inorganic nanocomposites, graphene/polymer composites and graphene analogues are highlighted. Finally, challenges and opportunities are briefly outlined on the graphene flakes and their composites synthesized by electrochemical methods.

Key words: graphene, graphene composites, electrochemically exfoliation, electrochemically oxidation, electrochemically reduction

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