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电化学(中英文) ›› 2014, Vol. 20 ›› Issue (4): 377-381.  doi: 10.13208/j.electrochem.131171

• 电化学近期研究专辑(厦门大学 姜艳霞教授主编) • 上一篇    下一篇

Pt-TiO2/Graphene催化剂的氧还原和甲醇氧化电催化性能研究

戚利1,2,3,殷瑛1,2,3,涂文广1,吴兵兵1,2,3,王兆生5,刘建国1,2,3,4*,顾军1,3,4,邹志刚1,2,3,4   

  1. 1. 南京大学物理学院环境材料与再生能源研究中心,江苏 南京 210093;2. 南京大学现代工程与应用科学学院,江苏 南京 210093;3. 江苏省纳米技术重点实验室,江苏 南京 210093;4. 南京大学昆山创新研究院,江苏 南京 210093;5. 浙江省绍兴县永利新能源研究院有限公司,浙江 绍兴 312028
  • 收稿日期:2014-01-17 修回日期:2014-03-10 出版日期:2014-08-28 发布日期:2014-03-20
  • 通讯作者: 刘建国 E-mail:jianguoliu@nju.edu.cn
  • 基金资助:

    国家自然科学基金项目(No. 21176111)、浙江省重大科技专项(No. 2012C11014)和绍兴县科技攻关计划项目(No. 2012506)资助

Preparation of Pt-TiO2/Graphene Composites with High Catalytic Activity towards Methanol Oxidation and Oxygen Reduction Reaction

QI Li 1,2,3, YIN Ying1,2,3, TU Wen-guang1, WU Bing-bing1,2,3, WANG Zhao-sheng5, LIU Jian-guo1,2,3,4*, GU Jun1,3,4, ZOU Zhi-gang1,2,3,4   

  1. 1. Eco-materials and Renewable Energy Research Center, Nanjing University, Nanjing 210093, China; 2. College of Engineering and Applied sciences, Nanjing University, Nanjing 210093, China; 3. Jiangsu Key Laboratory for Nano Technology, Nanjing University, Nanjing 210093, China; 4. Kunshan Innovation Institute of Nanjing University, Nanjing 210093; 5. Yong Li New Technology Research Institute Company Limited, Shaoxing 312028, Zhejiang, China
  • Received:2014-01-17 Revised:2014-03-10 Published:2014-08-28 Online:2014-03-20
  • Contact: LIU Jian-guo E-mail:jianguoliu@nju.edu.cn

摘要: 以二(2-羟基丙酸)二氢氧化二铵合钛(TBA)和氧化石墨烯(GO)为前驱体,通过水热法合成出不同TiO2含量的TiO2/Graphene(TiO2/G)复合材料,随之用微波醇热法还原Pt前驱体可得Pt-TiO2/G催化剂. 实验结果表明,TiO2可与Pt相互作用,添入适量TiO2的Pt-TiO2/G催化剂具有较高的氧还原电催化活性及甲醇氧化的电催化活性与稳定性. 但TiO2电导率偏低,过量TiO2的添入反而使其电催化性能降低.

关键词: TiO2, 石墨烯, 氧还原, 甲醇氧化

Abstract: A series of graphene-supported TiO2 nanoparticles (TiO2/G) with different TiO2 contents were prepared by a facile hydrothermal method, and then the Pt-TiO2/G catalysts were successfully prepared by reducing Pt-precursor with microwave technique. Compared with Pt-G catalysts, the catalytic performance toward oxygen reduction reaction (ORR) and methanol oxidation reaction (MOR) of Pt-TiO2/G catalysts was improved due to the addition of TiO2. However, the excessive TiO2 would lead to a poor catalytic performance of Pt-TiO2/G catalysts because of the low electrical conductivity of TiO2.

Key words: TiO2, graphene, ORR, methanol oxidation

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