基于叶片状氧化铜纳米材料的无酶葡萄糖传感电极

doi:10.13208/j.electrochem.121025

电化学（中英文） ›› 2014, Vol. 20 ›› Issue (1): 80-84. doi: 10.13208/j.electrochem.121025

基于叶片状氧化铜纳米材料的无酶葡萄糖传感电极

李艳彩^*，黄富英，李顺兴，陈杰，冯树清，王飞

漳州师范学院化学与环境科学系，福建漳州 363000

收稿日期:2012-10-25 修回日期:2013-01-22 出版日期:2014-02-25 发布日期:2014-02-24
通讯作者: 李艳彩 E-mail:liyancai2000@yahoo.com.cn
基金资助:
国家自然科学基金项目（No. 20977074，No. 21175115）、福建省自然科学基金杰青项目（No. 2010J06005）、福建省自然科学基金重点和青年创新项目（No. 2012Y0065，No. 2012J05031）及漳州师范学院杰青项目（No. SJ1117）资助

A New Nonenzymatic Glucose Sensor Based on the CuO Nanoplatelets

LI Yan-cai^*，HUANG Fu-ying，LI Shun-xing，CHEN Jie，FENG Shu-qing，WANG Fei

Department of Chemistry and Environment Science, Zhangzhou Normal University, Zhangzhou 363000, Fujian, China

Received:2012-10-25 Revised:2013-01-22 Published:2014-02-25 Online:2014-02-24
Contact: LI Yan-cai E-mail:liyancai2000@yahoo.com.cn

摘要/Abstract

摘要： 将Nafion交联剂与纳米材料修饰至玻碳电极基底制备一种无酶葡萄糖传感器，通过循环伏安曲线、时间-电流曲线检测该电极电化学特性. 氧化铜纳米复合膜具有高比表面积和多活性点位的优点. 实验结果表明，氧化铜纳米电极对葡萄糖的检测线性响应范围0.01 ~ 0.3 mmol·L^-1，灵敏度1783.58 μA·L·mmol^-1·cm^-2，检测限0.80 μmol·L^-1 (S/N=3)，稳定性较好，能抵抗抗坏血酸、多巴胺和尿酸干扰.

关键词: 叶片状氧化铜, 纳米材料, 无酶传感器, 葡萄糖

Abstract: The CuO nanoplatelets were synthesized by hydrothermal method. The structure and morphology of the CuO nanoplatelets were characterized by TEM and XRD. A new nonenzymatic glucose sensor was constructed by immobilizing the CuO nanoplatelets on glassy carbon electrode with Nafion. The electrochemical performance of the CuO/Nafion/GCE for the detection of glucose was investigated by cyclic voltammetry and current-time curve. The experiment results showed that the linear dependence of the sensor was 0.01 to 0.3 mmol·L^-1 for glucose with a sensitivity of 1783.58 μA·mmol^-1·L·cm^-2, and the detection limit of the sensor was 0.80 μmol·L^-1 (S/N = 3). Also, the sensor displayed fast response and long-term stability to glucose, and interferences of ascorbic acid, dopamine, and uric acid were effectively avoided.

Key words: CuO platelets, nanomaterials, nonenzymatic sensor, glucose

中图分类号:

O657.1

李艳彩*，黄富英，李顺兴，陈杰，冯树清，王飞. 基于叶片状氧化铜纳米材料的无酶葡萄糖传感电极[J]. 电化学（中英文）, 2014, 20(1): 80-84.

LI Yan-cai*，HUANG Fu-ying，LI Shun-xing，CHEN Jie，FENG Shu-qing，WANG Fei. A New Nonenzymatic Glucose Sensor Based on the CuO Nanoplatelets[J]. Journal of Electrochemistry, 2014, 20(1): 80-84.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.121025

https://electrochem.xmu.edu.cn/CN/Y2014/V20/I1/80

参考文献

[1] Park S, Boo H, Chung T D. Electrochemical non-enzymatic glucose sensors[J]. Analytica Chimica Acta, 2006, 556(1): 46-57.
[2] Li X, Zhu Q Y, Tong S F, et al. Self-assembled microstructure of carbon nanotubes for enzymeless glucose sensor[J]. Sensors and Actuators B, 2009, 136(2): 444-450.
[3] ElKhatib K M, AbdelHameed R M. Development of Cu2O/Carbon Vulcan XC-72 as non-enzymatic sensor for glucose determination[J]. Biosensors and Bioelectronics, 2011, 26(8): 3542-3548.
[4] Luo J, Jiang S S, Zhang H Y, et al. A novel non-enzymatic glucose sensor based on Cu nanoparticle modified graphene sheets electrode[J]. Analytica Chimica Acta, 2012, 709(4): 47-53.
[5] Yang J, Zhang W D, Gunasekarana S. An amperometric non-enzymatic glucose sensor by electrodepositing copper nanocubes onto vertically well-aligned multi-walled carbon nanotube arrays[J]. Biosensors and Bioelectronics, 2010, 26(1): 279-284.
[6] Umar A, Rahman M M, Hajry A A, et al. Enzymatic glucose biosensor based on flower-shaped copper oxide nanostructures composed of thin nanosheets[J]. Electrochemistry Communications, 2009, 11(2): 278-281.
[7] Farrell Sinéad T, Breslin Carmel B. Oxidation and photo-induced oxidation of glucose at a polyaniline film modified by copper particles[J]. Electrochimica Acta, 2004, 49(25): 4497-4503.
[8] Reitz E, Jia W Z, Gentile M, et al. CuO nanospheres based nonenzymatic glucose sensor[J]. Electroanalysis, 2008, 20(22): 2482-2486.
[9] Wang J, Zhang W D. Fabrication of CuO nanoplatelets for highly sensitive enzyme-free determination of glucose[J]. Electrochimica Acta, 2011, 56(22): 7510-7516.
[10] Wei H, Sun J J, Guo L, et al. Highly enhanced electrocatalytic oxidation of glucose and shikimic acid at a disposable electrically heated oxide covered copper electrode[J]. Chemical Communications, 2009, 20: 2842-2844.
[11] Marioli J M, Kuwana T. Electrochemical characterization of carbohydrate oxidation at copper electrodes[J]. Electrochimica Acta, 1992, 37(7): 1187-1197.
[12] Chen J, Zhang W D, Ye J S. Nonenzymatic electrochemical glucose sensor based on MnO2/MWNTs nanocomposite[J]. Electrochemistry Communications, 2008, 10(9): 1268-1271.

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基于叶片状氧化铜纳米材料的无酶葡萄糖传感电极

A New Nonenzymatic Glucose Sensor Based on the CuO Nanoplatelets

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