烟气吸收液中亚硝酸铵的电化学氧化处理技术

doi:10.13208/j.electrochem.120912

电化学（中英文） ›› 2014, Vol. 20 ›› Issue (1): 39-44. doi: 10.13208/j.electrochem.120912

烟气吸收液中亚硝酸铵的电化学氧化处理技术

芦永红，董小波，王丽莎，刘燕，祝陈坚，徐海波^*

中国海洋大学化学化工学院，海洋化学理论与工程技术教育部重点实验室，山东青岛 266100

收稿日期:2012-09-11 修回日期:2012-12-10 出版日期:2014-02-25 发布日期:2014-02-24
通讯作者: 徐海波 E-mail:xuwangri@163.com
基金资助:
国家863计划项目（No. 2012AA0602505）和青岛市科技发展计划项目（No. 12-1-4-1-(28)-jch）资助

Electrochemical Oxidation of Ammonium Nitrite in Absorption Solution of Flue Gas

LU Yong-hong, DONG Xiao-bo, WANG Li-sha, LIU Yan, ZHU Chen-jian, XU Hai-bo^*

Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education; College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, Shandong, China

Received:2012-09-11 Revised:2012-12-10 Published:2014-02-25 Online:2014-02-24
Contact: XU Hai-bo E-mail:xuwangri@163.com

摘要/Abstract

摘要： 为实现燃煤电厂烟气脱硫、硝和汞一体化工艺中吸收液副产物亚硝酸铵的废物利用，采用电化学氧化处理技术将吸收液中亚硝酸铵转化为硝酸铵. 采用极化曲线、循环伏安曲线和恒电流法等多种电化学测试方法评价和选取电极材料，探讨电解液组成的影响，得到优化的电化学氧化工艺参数，并用化学分析法验证了电化学氧化处理效果.

关键词: 电化学氧化, 脱硝, 烟气, 水处理, 碳纤维

Abstract: In order to make full uses of ammonium nitrite in absorption solution from flue gas simultaneous desulfurization, denitrification and demercurization processes, here the electrochemical oxidation method was used to transform ammonium nitrite into ammonium nitrate. By using polarization curve, cyclic voltammogram and galvanostatic methods, suitable electrode materials were evaluated and chosen. The influence of electrolyte composition was discussed and the appropriate process parameters were obtained. Finally, the effect of electrochemical oxidation was confirmed by chemical analysis method. In 0.05 mol·L^-1 NaNO₂ + 0.05 mol·L^-1 (NH4)2SO4 simulated absorption solution (5 L, pH = 7.0) and by using titanium cathode and carbon fiber brush anode, the transformed efficiency of nitrite ion reached 72% after 16 h with the oxidation current of 600 mA.

Key words: electrochemical oxidation, denitrification, flue gas, water treatment, carbon fiber

中图分类号:

O646

芦永红，董小波，王丽莎，刘燕，祝陈坚，徐海波*. 烟气吸收液中亚硝酸铵的电化学氧化处理技术[J]. 电化学（中英文）, 2014, 20(1): 39-44.

LU Yong-hong, DONG Xiao-bo, WANG Li-sha, LIU Yan, ZHU Chen-jian, XU Hai-bo*. Electrochemical Oxidation of Ammonium Nitrite in Absorption Solution of Flue Gas[J]. Journal of Electrochemistry, 2014, 20(1): 39-44.

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烟气吸收液中亚硝酸铵的电化学氧化处理技术

Electrochemical Oxidation of Ammonium Nitrite in Absorption Solution of Flue Gas

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