原位自组装SmMn2O5-NiMn2O4双相复合阴极的制备及性能研究

doi:10.61558/2993-074X.3615

电化学（中英文） ›› 2026, Vol. 32 ›› Issue (7): 2603211. doi: 10.61558/2993-074X.3615

原位自组装SmMn₂O₅-NiMn₂O₄双相复合阴极的制备及性能研究

夏能楚^a^,^b, 周宇^b, 王琴^a, 张家友^b, 余春^b, 张旸^b, 官万兵^b, 王建新^b^,^*()()

^a 宁波大学材料科学与化学工程学院，浙江宁波， 315211
^b 中国科学院宁波材料技术与工程研究所，全省先进燃料电池与电解池技术重点实验室，浙江宁波， 315201

收稿日期:2026-03-31 修回日期:2026-04-26 接受日期:2026-05-14 发布日期:2026-05-14 出版日期:2026-07-28

Preparation and Performance Study of In-Situ Self-Assembled Biphasic SmMn₂O₅-NiMn₂O₄ Composite Cathode

Neng-Chu Xia^a^,^b, Yu Zhou^b, Qin Wang^a, Jia-You Zhang^b, Chun Yu^b, Yang Zhang^b, Wan-Bing Guan^b, Jian-Xin Wang^b^,^*()()

^a School of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang, 315211, P.R. China
^b Key Laboratory of Advanced Fuel Cells and Electrolyzers Technology of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang, 315201, P.R. China

Received:2026-03-31 Revised:2026-04-26 Accepted:2026-05-14 Online:2026-05-14 Published:2026-07-28
Contact: * Jian-Xin Wang, Email address: jxwang@nimte.ac.cn
About author:Author Contributions
Neng-Chu Xia: Conceptualization, data curation, formal analysis, investigation, and writing-original draft. Yu Zhou: Conceptualization, investigation, and project administration. Qin Wang: Project administration. Jia-You Zhang: Software and supervision. Chun Yu: Supervision and validation. Yang Zhang: Writing-review & editing. Wan-Bing Guan: Funding acquisition, resources, validation, and writing-review & editing. Jian-Xin Wang: Methodology, supervision, project administration, and writing-review & editing. All authors discussed the results, reviewed the manuscript, and approved the final version.

摘要/Abstract

摘要：

莫来石结构氧化物具有优异的氧还原反应（ORR）活性，得益于其独特的晶体结构而表现出较低的热膨胀系数（TEC），且由于不含碱土元素，可避免使用阻挡层并简化制备工艺。因此，它们作为新型固体氧化物燃料电池（SOFC）阴极材料具有广阔的应用前景。本工作通过固-液复合路线一步法合成了莫来石-尖晶石结构的SmMn₂O₅-NiMn₂O₄（SMO-NMO）复合阴极，其原位自组装特性使其在无需阻挡层的情况下即可与电解质实现良好的界面匹配。表征结果表明，当SMO:NMO=5:5（SN55）时，复合阴极通过两相之间的协同作用，克服了单相材料的性能瓶颈-即纯SMO导电性低（800 °C时仅为0.035 S·cm^-1）以及纯NMO氧还原反应（ORR）活性不足的问题。在800 °C下，全电池的峰值功率密度达到1069.82 mW·cm^-2，分别为纯SMO（329.92 mW cm^-2）和纯NMO（890.20 mW·cm^-2）的3.24倍和1.20倍。以SN55为阴极的全电池在750 °C、540 mA·cm^-2条件下恒流放电150 h后，电压衰减约为1.6%，平均衰减率为5.62%/kh，且阴极-电解质界面未出现任何缺陷与元素偏析。本研究为设计无阻挡层固体氧化物燃料电池（SOFC）阴极材料提供了一条新的思路。

关键词: 固体氧化物燃料电池, 阴极, 莫来石结构, 无阻挡层, 原位复合

Abstract:

Mullite-structured oxides exhibit excellent oxygen reduction reaction activity, possess a low thermal expansion coefficient due to their unique crystal structure, and can eliminate the need for a barrier layer and simplify the preparation process as they contain no alkaline earth elements. Thus, they hold great promise as novel cathode materials for solid oxide fuel cells. In this work, a mullite-spinel-structured SmMn₂O₅-NiMn₂O₄ (SMO-NMO) composite cathode was one-step synthesized via a solid-liquid composite route, and its in-situ self-assembly enabled good compatibility with the electrolyte without any barrier layer. Characterization results showed that the SMO:NMO = 5:5 (SN55)composite cathode overcame the bottlenecks of single-phase materials-namely, the low conductivity of pure SMO (only 0.035 S·cm^-1 at 800 °C) and the insufficient oxygen reduction reaction activity of pure NMO-through a synergistic effect between the two phases. At 800 °C, the single cell delivered a peak power density of 1069.82 mW·cm^-2, which was 3.24-fold and 1.20-fold higher than that of pure SMO (329.92 mW·cm^-2) and NMO (890.20 mW·cm^-2), respectively. Under galvanostatic operation at 750 °C (current density corresponding to 540 mA·cm^-2), the SN55-based cell runs for ~150 h with only 1.6% voltage loss, corresponding to a degradation rate of 5.62%/kh, and no defects appeared at the cathode-electrolyte interface. This study provided a new route for designing barrier-layer-free cathodes for solid oxide fuel cells.

Key words: Solid Oxide Fuel Cell, Cathode, Mullite, Barrier-free, In-situ Composite

夏能楚, 周宇, 王琴, 张家友, 余春, 张旸, 官万兵, 王建新. 原位自组装SmMn₂O₅-NiMn₂O₄双相复合阴极的制备及性能研究[J]. 电化学（中英文）, 2026, 32(7): 2603211.

Neng-Chu Xia, Yu Zhou, Qin Wang, Jia-You Zhang, Chun Yu, Yang Zhang, Wan-Bing Guan, Jian-Xin Wang. Preparation and Performance Study of In-Situ Self-Assembled Biphasic SmMn₂O₅-NiMn₂O₄ Composite Cathode[J]. Journal of Electrochemistry, 2026, 32(7): 2603211.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.61558/2993-074X.3615

https://electrochem.xmu.edu.cn/CN/Y2026/V32/I7/2603211

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参考文献 38

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cathode	800 ℃	750 ℃	700 ℃	650 ℃	600 ℃
SMO	329.92	192.68	101.59	38.94	16.36
NMO	890.20	612.97	253.27	64.69	10.18
SN91	525.02	325.12	190.87	86.56	39.53
SN82	571.19	350.90	200.57	105.66	53.55
SN73	603.54	415.28	253.92	133.76	44.83
SN64	787.12	470.16	214.92	107.93	45.46
SN55	1069.82	725.50	357.44	204.18	78.35
SN46	786.55	483.26	281.16	145.93	64.12

Modification type	Cathode composition	PPD at 800 °C/(W·cm^-2)	Ref.
Ni-doping	Pr_0.5Sr_0.5FeO_3−δ	0.898	[35]
Ni-doping	La_0.6Sr_0.4FeO_3−δ	0.853	[36]
Ni-containing impregnation	LaCo_0.6Ni_0.4O_3-δ-PrBa_0.5Sr_0.5Co_1.5Fe_0.5O_5+δ	0.838	[37]
NiO modification	LSCF-5wt%NiO	1.031	[38]
This work	50wt%SmMn₂O₅-50wt%NiMn₂O₄	1.069	/

原位自组装SmMn₂O₅-NiMn₂O₄双相复合阴极的制备及性能研究

Preparation and Performance Study of In-Situ Self-Assembled Biphasic SmMn₂O₅-NiMn₂O₄ Composite Cathode

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