电化学(中英文) ›› 2022, Vol. 28 ›› Issue (9): 2214007. doi: 10.13208/j.electrochem.2214007
所属专题: “电催化和燃料电池”专题文章
收稿日期:
2022-06-28
修回日期:
2022-07-21
出版日期:
2022-09-28
发布日期:
2022-08-23
Ao Zhou, Wei-Jian Guo, Yue-Qing Wang*(), Jin-Tao Zhang*()
Received:
2022-06-28
Revised:
2022-07-21
Published:
2022-09-28
Online:
2022-08-23
Contact:
*Tel:(86-531)88361011, E-mail: Jin-Tao Zhang, 摘要:
电解水是有效的产氢方式之一, 开发具有高催化活性的电极材料是当前电解水的研究热点,但仍面临诸多挑战。 本研究报告了一种通过焦耳热技术快速制备多金属异质结构, 并将其用作电解水的双功能电催化剂, 展现出优异的电解水催化活性。通过焦耳热处理三种金属前驱涂覆的碳布, Mo2C和CoO/Fe3O4异质结构形成。当其用作析氢(HER)和析氧(OER)的双功能催化剂时, 仅需121 mV和268 mV的过电位,可以实现10 mA·cm-2的电流密度。当用于两电极电解水时, MoC/FeO/CoO/CC作为阳极和阴极催化剂表现出优异的电催化性能和长期稳定性, 仅需1.69 V即可实现10 mA·cm-2的电流密度, 并且展现出25小时的稳定性。本研究通过简单、 快速的焦耳热技术实现了双金属/多金属异质结构的构筑,并应用于高效水电解,为合理设计多金属异质结构提供指导。
周澳, 郭伟健, 王月青, 张进涛. 焦耳热快速合成双功能电催化剂用于高效水分解[J]. 电化学(中英文), 2022, 28(9): 2214007.
Ao Zhou, Wei-Jian Guo, Yue-Qing Wang, Jin-Tao Zhang. The Rapid Preparation of Efficient MoFeCo-Based Bifunctional Electrocatalysts via Joule Heating for Overall Water Splitting[J]. Journal of Electrochemistry, 2022, 28(9): 2214007.
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