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电化学(中英文) ›› 2017, Vol. 23 ›› Issue (6): 654-660.  doi: 10.13208/j.electrochem.160928

• 研究论文 • 上一篇    下一篇

PEG包覆涂层对含碳纤维导电剂的锂硫正极材料的影响

谭杰成,田艳红*,张学军,樊开乐   

  1. 北京化工大学材料科学与工程学院教育部碳纤维及功能高分子重点实验室,北京 100029
  • 收稿日期:2016-09-28 修回日期:2016-11-15 出版日期:2017-12-28 发布日期:2016-12-09
  • 通讯作者: 田艳红 E-mail:tianyh@mail.buct.edu.cn
  • 基金资助:

    北京市科委基金项目资助(横向项目)

Effect of PEG-Coating on Properties of Lithium-Sulfur Battery Cathode Material Containing Carbon Fiber Conductive Agent

TAN Jie-cheng, TIAN Yan-hong*, ZHANG Xue-jun, FAN Kai-le   

  1. State Key Laboratory of Organic-Inorganic composite, College of Materials Science and Engineering, Beijing University of Chemical Technology Beijing100029China
  • Received:2016-09-28 Revised:2016-11-15 Published:2017-12-28 Online:2016-12-09
  • Contact: TIAN Yan-hong E-mail:tianyh@mail.buct.edu.cn

摘要:

通过球磨混合及聚乙二醇(PEG)包覆处理制备含有高模量碳纤维(HMCF)的硫基复合材料.采用X射线衍射(XRD)和扫描电子显微镜(SEM)测定材料的结构和形貌,采用X-光电子扫描能谱(XPS)验证了PEG包覆在材料的表面,较系统地研究了PEG含量对含有高模量碳纤维的硫正极比容量、循环稳定性和倍率性能等性能的影响.结果表明:和常用的导电剂乙炔黑(AB)相比,HMCF导电剂具有结晶度高,接触角小,吸液性能好等优点.当PEG涂层量为1.09%时,硫正极初始放电容量为1312.5 mAh·g-1,在电流密度为200 mA·g-1充放电时,50次循环以后可逆容量保持为650 mAh·g-1,和没有PEG涂层相比,循环稳定性提高了39.9%.

关键词: 锂硫电池, 硫正极, 高模量碳纤维, 包覆, 聚乙二醇

Abstract: The composite materials contained high modulus carbon fiber (HMCF) were successfully prepared by employing a ball-milling process based on the coating treatment of polyethylene glycol (PEG), and their structures and morphologies were characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) techniques.The influences of PEG content on sulfur cathode capacity, cycle stability and rate performance were systematically studied. It was found that by the pre-coating of PEG, the cathode exhibited the high initial discharge specific capacity of 1312.5 mAh•g-1 at a current rate of 0.2C, and the reversible discharge capacity of 650 mAh•g-1 was obtained after 50 cycles at a current rate of 200 mA•g-1, showing the remarkably improved cycling stability.

Key words: Lithium-sulfur battery, sulfur cathode, high modulus carbon fiber, coated, polyethyl-ene glycol

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