不锈钢网阴极微生物燃料电池的产电性能研究

doi:10.13208/j.electrochem.150928

电化学（中英文） ›› 2016, Vol. 22 ›› Issue (1): 75-80. doi: 10.13208/j.electrochem.150928

不锈钢网阴极微生物燃料电池的产电性能研究

代红艳^{1, 2}，杨慧敏¹，刘宪¹，简选¹，宋秀丽^{1, 3}，梁镇海^1*

1. 太原理工大学化学化工学院，太原 030024；2. 太原学院环境工程系，太原 030032；3. 太原师范学院化学系，太原 030031

收稿日期:2015-09-28 修回日期:2015-10-23 出版日期:2016-02-29 发布日期:2015-11-03
通讯作者: 梁镇海 E-mail:liangzhenh@sina.com
基金资助:
国家自然科学基金项目（No. U1261103）资助

Electricity Generation of Microbial Fuel Cell Using Stainless Steel Mesh as Cathode

DAI Hong-yan ^1,2, YANG Hui-min¹, LIU Xian¹, JIAN Xuan¹, SONG Xiu-li ^1,3, LIANG Zhen-hai^1*

1. College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Tai yuan 030024, China; 2. Department of Environmental Engineering, Tai yuan College, Taiyuan 030032, China; 3. Department of Chemistry, Taiyuan Normal University, Taiyuan 030031, China

Received:2015-09-28 Revised:2015-10-23 Published:2016-02-29 Online:2015-11-03
Contact: LIANG Zhen-hai E-mail:liangzhenh@sina.com

摘要/Abstract

摘要：

构建了一个以曝气池污泥为阳极接种微生物、碳毡为阳极、无任何修饰的不锈钢网为阴极的双室微生物燃料电池. 通过输出电压、功率密度以及电化学阻抗等考察了阴极面积对电池产电性能的影响，并对电池的长期运行稳定性进行评价. 研究结果表明，不锈钢网作为微生物燃料电池的阴极性能稳定. 当不锈钢网面积为2 × 2 cm²时，最大输出电压达到0.411 V，功率密度为0.303 W•m^-2，内阻841 Ω，极化内阻80 Ω. 增大阴极面积至2 × 4 cm²，最大输出电压能达到0.499 V，内阻减小至793 Ω. 不锈钢网价格便宜，具有长期运行稳定性，适宜做MFCs的阴极.

关键词: 不锈钢网, 微生物燃料电池, 阴极, 产电, 稳定性

Abstract:

In the present work, a dual-chamber microbial fuel cell (MFC) was constructed with aeration tank sludge as an inoculum, carbon felt as an anode and stainless steel mesh without any modification as a cathode. The influence of the cathode size was investigated in terms of voltage output, power generation and electrochemical impedance. The long-term durability of the stainless steel mesh cathode was also evaluated. Results showed that the stainless steel mesh exhibited satisfactory long-term durability as MFC cathode. When the stainless steel mesh size was 2 × 2 cm², the maximum output voltage, power density, the internal resistance and the polarization resistance were 0.411 V, 0.303 W•m^-2, 841 Ω and 80 Ω, respectively. Increasing the cathode size to 2 × 4 cm², the maximum output voltage could reach 0.499 V, and the internal resistance reduced to 793 Ω. These studies demonstrated that the stainless steel mesh was suitable for MFC cathode because of its durability and low price.

Key words: stainless steel mesh, microbial fuel cells, cathode, electricity generation, durability

中图分类号:

O646

代红艳，杨慧敏，刘宪，简选，宋秀丽，梁镇海. 不锈钢网阴极微生物燃料电池的产电性能研究[J]. 电化学（中英文）, 2016, 22(1): 75-80.

DAI Hong-yan, YANG Hui-min, LIU Xian, JIAN Xuan, SONG Xiu-li, LIANG Zhen-hai*. Electricity Generation of Microbial Fuel Cell Using Stainless Steel Mesh as Cathode[J]. Journal of Electrochemistry, 2016, 22(1): 75-80.

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.150928

https://electrochem.xmu.edu.cn/CN/Y2016/V22/I1/75

参考文献

[1] Xie X, Ye M, Hsu P C, et al. Microbial battery for efficient energy recovery[J]. Proceedings of the National Academy of Sciences of the United States of America, 2013, 110(40): 15925-15930.

[2] Lv Z S, Xie D H, Li F S, et al. Microbial fuel cell as a biocapacitor by using pseudo- capacitive anode materials[J]. Journal of Power Sources, 2014, 246: 642-649.

[3] Cusick R D, Kiely P D, Logan B E. A monetary comparison of energy recovered from microbial fuel cells and microbial electrolysis cells fed winery or domestic wastewaters[J]. International Journal of Hydrogen Energy, 2010, 35(17): 8855-8861.

[4] Wang C T, Chen W J, Huang R Y. Influence of growth curve phase on electricity performance of microbial fuel cell by Escherichia coli[J]. International Journal of Hydrogen Energy, 2010, 35(13): 7217-7223.

[5] Morris J M, Jin S, Wang J Q, et al. Lead dioxide as an alternative catalyst to platinum in microbial fuel cells[J]. Electrochemistry Communications, 2007, 9(7): 1730-1734.

[6] Zhao Y, Li P, Wang X B, et al. Influence of initial biofilm growth on electrochemical behavior in dual-chambered mediator microbial fuel cell[J]. Journal of Fuel Chemistry and Technology, 2012, 40(8): 967-972.

[7] Wei L L, Han H L, Shen J Q. Effects of cathodic electron acceptors and potassium ferricyanide concentrations on the performance of microbial fuel cell[J]. International Journal of Hydrogen Energy, 2012, 37(17): 12980-12986.

[8] Freguia S, Rabaey K, Yuan Z, et al. Non-catalyzed cathodic oxygen reduction at graphite granules in microbial fuel cells[J]. Electrochimica Acta, 2007, 53(2): 598-603.

[9] Logen B E, Call D, Cheng S, et al. Microbial electrolysis cells for high yield hydrogen gas production from organic matter[J]. Environmental Science & Technology, 2008, 42(23): 8630-8640.

[10] De Silva Muňoz L, Bergel A, Féron D et al. Hydrogen production by electrolysis of a phosphate solution on a stainless steel cathode[J]. International Journal of Hydrogen Energy, 2010, 35(16): 8561-8568.

[11] Zhang Y P, Sun J, Hu Y Y, et al. Bio-cathode materials evaluation in microbial fuel cells: A comparison of graphite felt, carbon paper and stainless steel mesh materials[J]. International Journal of Hydrogen Energy, 2012, 37(22): 16935-16942.

[12] You S J, Wang X H, Zhang J N, et al. Fabrication of stainless steel mesh gas diffusion electrode for power generation in microbial fuel cell[J]. Biosensors and Bioelectronics, 2011, 26(5): 2142-2146.

[13] Feng C H, Wan Q Y, Lv Z S, et al. One-step fabrication of membraneless microbial fuel cell cathode by electropolymerization of polypyrrole onto stainless steel mesh[J]. Biosensors and Bioelectronics, 2011, 26(9): 3953-3957.

[14] Wei L L, Han H L, Shen J Q. Effects of cathodic electron acceptors and potassium ferricyanide concentrations on the performance of microbial fuel cell[J]. International Journal of Hydrogen Energy, 2012, 37(17): 12980-12986.

[15] Pinto R P, Srinivasan B, Guiot S R, et al. The effect of real-time external resistance optimization on microbial fuel cell performance[J]. Water Research, 2011, 45(4): 1571-1578.

[16] Zhang Y P, Hu Y Y, Li S Z, et al. Manganese dioxide-coated carbon nanotubes as an improved cathodic catalyst for oxygen reduction in a microbial fuel cell[J]. Journal of Power Sources, 2011, 196(22): 9284-9289.

[17] Zhang J N(张金娜), Zhao Q L(赵庆良), You S J(尤世界), et al. Power generation in biocathode microbial fuel cell with different cathode materials[J]. Chemical Journal of Chinese Universities(高等学校化学学报), 2010, 31(1): 162-166.

[18] He Z, Mansfeld F. Exploring the use of electrochemical impedance spectroscopy (EIS) in microbial fuel cell studies[J]. Energy & Environmental Science, 2009, 2(2): 215-219.

不锈钢网阴极微生物燃料电池的产电性能研究

Electricity Generation of Microbial Fuel Cell Using Stainless Steel Mesh as Cathode

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

[1]	汤亚飞, 武安祺, 韩贝贝, 刘华, 包善军, 林王林, 陈铭, 官万兵, Subhash C. Singhal. 以掺氢天然气为燃料直接内重整固体氧化物电池堆的稳定性[J]. 电化学（中英文）, 2024, 30(1): 2314001-.
[2]	陈浩杰, 唐美华, 陈胜利. 质子交换膜燃料电池阴极催化层疏水性优化[J]. 电化学（中英文）, 2023, 29(9): 2207061-.
[3]	倪静, 施兆平, 王显, 王意波, 吴鸿翔, 刘长鹏, 葛君杰, 邢巍. 低铱酸性氧析出电催化剂的研究进展[J]. 电化学（中英文）, 2022, 28(9): 2214010-.
[4]	应方, 许珊珊, 许燕冰, 梁苗苗, 李剑锋. Fe₃O₄磁性纳米颗粒催化电化学降解土霉素的研究[J]. 电化学（中英文）, 2022, 28(4): 2107141-.
[5]	王越, 张立敏, 田阳. 基于电化学分子探针合理设计的高选择性长程活体分析[J]. 电化学（中英文）, 2022, 28(3): 2108451-.
[6]	王睿卿, 隋升. PEMFC阴极催化层结构分析[J]. 电化学（中英文）, 2021, 27(6): 595-604.
[7]	杜立群, 温义奎, 关发龙, 翟科, 叶作彦, 王超. 移动阴极式掩膜电解加工微沟槽阵列均匀性研究[J]. 电化学（中英文）, 2021, 27(6): 658-670.
[8]	李姝谨, 曹志康, 王文凯, 张晓菡, 向兴德. 硫酸盐功能电解液增强水系钠离子电池NaTi₂(PO₄)₃/C负极材料电化学性能的研究[J]. 电化学（中英文）, 2021, 27(6): 605-613.
[9]	董文霞, 温广明, 刘斌, 李忠平. 基于Zr-MOFs光电化学传感用于同型半胱氨酸的检测[J]. 电化学（中英文）, 2021, 27(6): 681-688.
[10]	黄夏敏, 张丽红, 吴顺情, 杨勇, 朱梓忠. ANiN(A = Li, Na, Mg, Ca)的结构、热力学、弹性和电子性质的第一性原理研究[J]. 电化学（中英文）, 2021, 27(3): 339-350.
[11]	俞成荣, 朱建国, 蒋聪盈, 谷宇晨, 周晔欣, 李卓斌, 邬荣敏, 仲政, 官万兵. 基于电-化-热耦合理论对称双阴极固体氧化物燃料电池堆的电流与温度场数值模拟[J]. 电化学（中英文）, 2020, 26(6): 789-796.
[12]	孟全华, 邓雯雯, 李长明. 类石墨烯类活性炭材料的简易合成及其在锂硫电池中的应用研究[J]. 电化学（中英文）, 2020, 26(5): 740-749.
[13]	邓博文, 尹华意, 汪的华. CO₂高效资源化利用的高温熔盐电化学技术研究[J]. 电化学（中英文）, 2020, 26(5): 628-638.
[14]	毛庆, 李冰玉, 景维云, 赵健, 刘松, 黄延强, 杜兆龙. 膜电极构型CO₂还原电解单池的稳定性研究[J]. 电化学（中英文）, 2020, 26(3): 359-369.
[15]	李雪, 龚正良. PEO基聚合物电解质及其锂硫电池性能研究[J]. 电化学（中英文）, 2020, 26(3): 338-346.