以掺氢天然气为燃料直接内重整固体氧化物电池堆的稳定性

doi:10.61558/2993-074X.3430

电化学（中英文） ›› 2024, Vol. 30 ›› Issue (1): 2314001. doi: 10.61558/2993-074X.3430

• 论文 • 上一篇

以掺氢天然气为燃料直接内重整固体氧化物电池堆的稳定性

汤亚飞^a, 武安祺^a, 韩贝贝^a, 刘华^b, 包善军^b, 林王林^c, 陈铭^d, 官万兵^a^,^*(), Subhash C. Singhal^a

^a中国科学院宁波材料技术与工程研究所，浙江宁波 315201
^b浙江启明电力集团有限公司，浙江舟山 316099
^c浙江大学舟山海洋研究中心，浙江舟山 316021
^d丹麦技术大学能源转换与储存系，丹麦哥本哈根

收稿日期:2023-08-15 修回日期:2023-10-20 接受日期:2023-10-31 出版日期:2024-01-28 发布日期:2023-11-15
通讯作者: 官万兵 E-mail:wbguan@nimte.ac.cn

Stability of a Solid Oxide Cell Stack under Direct Internal-Reforming of Hydrogen-Blended Methane

Ya-Fei Tang^a, An-Qi Wu^a, Bei-Bei Han^a, Hua Liu^b, Shan-Jun Bao^b, Wang-Lin Lin^c, Ming Chen^d, Wan-Bing Guan^a^,^*(), Subhash C. Singhal^a

^aKey Laboratory of Advanced Fuel Cells and Electrolyzers cell Technology of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, Zhejiang, China
^bZhejiang Qiming Electric Power Group Co. Ltd, Zhoushan 316099, Zhejiang, China
^cOcean Research Center of Zhoushan, Zhejiang University, Zhoushan 316021, Zhejiang, China
^dDepartment of Energy Conversion and Storage, Technical University of Denmark (DTU), Lyngby, Denmark

Received:2023-08-15 Revised:2023-10-20 Accepted:2023-10-31 Published:2024-01-28 Online:2023-11-15
Contact: Wan-Bing Guan E-mail:wbguan@nimte.ac.cn

摘要/Abstract

摘要：

本文研究了掺氢天然气直接内重整平管型固体氧化物电池短堆的长期稳定性和衰减机理。通过约3000小时的实测实验，结果显示，电堆的总体衰减率为2.3% kh^-1，电堆中三个金属连接板的面积比电阻分别增加了0.276 Ω·cm²、0.254 Ω·cm²和0.249 Ω·cm²，但电堆中两个电池的电压反而分别增加了3.38 mV·kh^-1和3.78 mV·kh^-1。电堆衰减主要由金属连接件表层氧化及其与阴极集流层材料反应生成SrCrO₄物质，两者共同作用增大了电池与金属连接体间的界面电阻所致。结果表明，以掺氢天然气为燃料直接内重整平管型固体氧化物燃料电池电堆具有良好的稳定性。本文工作为掺氢天然气在固体氧化物燃料电池堆中的直接内重整应用提供了理论参考与实验依据。

关键词: 掺氢天然气, 内重整, 稳定性, 固体氧化物电堆

Abstract:

In this work, the long-term stability and degradation mechanism of a direct internal-reforming solid oxide fuel cell stack (IR-SOFC stack) using hydrogen-blended methane steam reforming were investigated. An overall degradation rate of 2.3%·kh^-1 was found after the stack was operated for 3000 hours, indicating a good long-term stability. However, the voltages of the two cells in the stack were increased at the rates of 3.38 mV·kh^-1 and 3.78 mV·kh^-1, while the area specific resistances of the three metal interconnects in the stack were increased to 0.276 Ω·cm², 0.254 Ω·cm² and 0.249 Ω·cm². The degradation of the stack might be caused by segregation of chromium on the surface of metal interconnects and the formation of SrCrO₄ insulating phase in the current collecting layer of the cathode, which result in an increase in the interfacial resistance and a decrease in the stack performance. The long-term performance of a flat-tube IR-SOFC stack could be further improved by suitably coating the metal interconnect surface. This work provides theoretical and experimental guideline for the application of hydrogen-blended methane steam reforming in flat-tube IR-SOFC stacks.

Key words: Hydrogen-blended methane steam, Internal-reforming, Stability, Solid oxide fuel cell stack

汤亚飞, 武安祺, 韩贝贝, 刘华, 包善军, 林王林, 陈铭, 官万兵, Subhash C. Singhal. 以掺氢天然气为燃料直接内重整固体氧化物电池堆的稳定性[J]. 电化学（中英文）, 2024, 30(1): 2314001.

Ya-Fei Tang, An-Qi Wu, Bei-Bei Han, Hua Liu, Shan-Jun Bao, Wang-Lin Lin, Ming Chen, Wan-Bing Guan, Subhash C. Singhal. Stability of a Solid Oxide Cell Stack under Direct Internal-Reforming of Hydrogen-Blended Methane[J]. Journal of Electrochemistry, 2024, 30(1): 2314001.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.61558/2993-074X.3430

https://electrochem.xmu.edu.cn/CN/Y2024/V30/I1/2314001

图/表 11

参考文献 34

[1]	Hanif H B, Motola M, Qayyum S, Rauf S, Khalid A, Li C J, Li C X. Recent advancements, doping strategies and the future perspective of perovskite-based solid oxide fuel cells for energy conversion[J]. Chem. Eng. J., 2022, 428: 132603. doi: 10.1016/j.cej.2021.132603 URL
[2]	Hua B, Li M, Sun Y F, Zhang Y Q, Yan N, Li J, Etsell T, Sarkar P, Luo J L. Grafting doped manganite into nickel anode enables efficient and durable energy conversions in biogas solid oxide fuel cells[J]. Appl. Catal. B-Environ., 2017, 200: 174-181. doi: 10.1016/j.apcatb.2016.07.001 URL
[3]	Zhuang Z C, Li Y H, Yu R H, Xia L X, Yang J R, Lang Z Q, Zhu J X, Huang J Z, Wang J O, Wang Y, Fan L D, Wu J S, Zhao Z, Wang D S, Li Y D. Reversely trapping atoms from a perovskite surface for high-performance and durable fuel cell cathodes[J]. Nat. Catal., 2022, 5: 300-310. doi: 10.1038/s41929-022-00764-9
[4]	Yang Y, Li T, Feng P Z, Wang X X, Wang S R, Li Y H, Shao Z P. Highly efficient conversion of oxygen-bearing low concentration coal-bed methane into power via solid oxide fuel cell integrated with an activated catalyst-modified anode microchannel[J]. Appl. Energy, 2022, 328: 120134. doi: 10.1016/j.apenergy.2022.120134 URL
[5]	Alaedini A H, Tourani H K, Saidi M. A review of waste-to-hydrogen conversion technologies for solid oxide fuel cell (SOFC) applications: Aspect of gasification process and catalyst development[J]. J. Environ. Manage., 2023, 329: 117077. doi: 10.1016/j.jenvman.2022.117077 URL
[6]	Kupecki J, Motylinski K, Milewski J. Dynamic analysis of direct internal reforming in a SOFC stack with electrolyte-supported cells using a quasi-1D model[J]. Appl. Energy, 2018, 227: 198-205. doi: 10.1016/j.apenergy.2017.07.122 URL
[7]	Menon V, Banerjee A, Dailly J, Deutschmann O. Numerical analysis of mass and heat transport in proton-conducting SOFCs with direct internal reforming[J]. Appl. Energy, 2015, 149: 161-175. doi: 10.1016/j.apenergy.2015.03.037 URL
[8]	Sang J K, Liu S, Yang J, Wu T, Luo X, Zhao Y M, Wang J X, Guan W B, Chai M R, Singhal S C. Power generation from flat-tube solid oxide fuel cells by direct internal dry reforming of methanol: A route for simultaneous utilization of CO₂ and biofuels[J]. Chem. Eng. J., 2023, 457: 141189. doi: 10.1016/j.cej.2022.141189 URL
[9]	Fan L Y, Li C E, Aravind P V, Weiwei Cai d, Han M F, Brandon N. Methane reforming in solid oxide fuel cells: Challenges and strategies[J]. J. Power Sources, 2022, 538: 231573. doi: 10.1016/j.jpowsour.2022.231573 URL
[10]	Lee K X, Hu B X, Dubey P K, Anisur M R, Belko S, Aphale A N, Singh P. High-entropy alloy anode for direct internal steam reforming of methane in SOFC[J]. Int. J. Hydrog. Energy, 2022, 47(90): 38372-38385. doi: 10.1016/j.ijhydene.2022.09.018 URL
[11]	Lanzini A, Leone P, Guerra C, Smeacetto F, Brandon N P, Santarelli M. Durability of anode supported solid oxides fuel cells (SOFC) under direct dry-reforming of methane[J]. Chem. Eng. J., 2013, 220: 254-263. doi: 10.1016/j.cej.2013.01.003 URL
[12]	Zhang H, Liu W, Wang J X, Yang J, Chen Y, Guan W B, Singhal S C. Power generation from a symmetric flat-tube solid oxide fuel cell using direct internal dry-reforming of methane[J]. J. Power Sources, 2021, 516: 230662. doi: 10.1016/j.jpowsour.2021.230662 URL
[13]	Niakolas D K, Ouweltjes J P, Rietveld G, Dracopoulos V, Neophytides S G. Au-doped Ni/GDC as a new anode for SOFCs operating under rich CH₄ internal steam reforming[J]. Int. J. Hydrog. Energy, 2010, 35(15): 7898-7904. doi: 10.1016/j.ijhydene.2010.05.038 URL
[14]	Lin Y C, Wei W C J. Porous Cu-Ni-YSZ cermets using CH₄ fuel for SOFC. Int. J. Hydrog. Energy, 2020, 45(46): 24253-24262. doi: 10.1016/j.ijhydene.2020.05.281 URL
[15]	Zhang Y L, Xu N, Fan H, Han M F. La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ nanoparticles modified Ni-based anode for direct methane-fueled SOFCs[J]. Energy Procedia, 2019, 158: 2250-2255. doi: 10.1016/j.egypro.2019.01.179 URL
[16]	Lin K W, Wu H W. Hydrogen-rich syngas production and carbon dioxide formation using aqueous urea solution in biogas steam reforming by thermodynamic analysis[J]. Int. J. Hydrog. Energy, 2020, 45(20): 11593-11604. doi: 10.1016/j.ijhydene.2020.02.127 URL
[17]	Kalai D Y, Stangeland K, Jin Y Y, Tucho W M, Yu Z X. Biogas dry reforming for syngas production on La promoted hydrotalcite-derived Ni catalysts[J]. Int. J. Hydrog. Energy, 2018, 43(42): 19438-19450. doi: 10.1016/j.ijhydene.2018.08.181 URL
[18]	Labanca A R C, Cunha A G, Ribeiro R P, Zucolotto C G, Cevolani M B, Schettino M A. Technological solution for distributing vehicular hydrogen using dry plasma reforming of natural gas and biogas[J]. Renew. Energy, 2022, 201: 11-21. doi: 10.1016/j.renene.2022.11.020 URL
[19]	de Souza T A Z, Coronado C J R, Silveira J L, Pint G M. Economic assessment of hydrogen and electricity cogeneration through steam reforming-SOFC system in the Brazilian biodiesel industry[J]. J. Clean Prod., 2021, 279: 123814. doi: 10.1016/j.jclepro.2020.123814 URL
[20]	Chou Y S, Huang M H, Hsu N Y, Jeng K T, Lee R Y, Yen S C. Development of ring-shape supported catalyst for steam reforming of natural gas in small SOFC systems[J]. Int. J. Hydrog. Energy, 2016, 41(30): 12953-12961. doi: 10.1016/j.ijhydene.2016.06.034 URL
[21]	Wu A Q, Li C L, Han B B, Hanson S, Guan W B, Singhal S C. Effect of air addition to the air electrode on the stability and efficiency of carbon dioxide electrolysis by solid oxide cells[J]. Int. J. Hydrog. Energy, 2016, 47(58): 24268-24278. doi: 10.1016/j.ijhydene.2022.05.207 URL
[22]	Wu A Q, Li C L, Han B B, Liu W, Zhang Y, Hanson S, Guan W B, Singhal S C. Pulsed electrolysis of carbon dioxide by large-scale solid oxide electrolytic cells for intermittent renewable energy storage[J]. Carbon Energy, 2023, 5(4): 1-12.
[23]	Li C L, Wu A Q, Xi C Q, Guan W B, Chen L, Singhal S C. High reversible cycling performance of carbon dioxide electrolysis by flat-tube solid oxide cell[J]. Appl. Energy, 2022, 314: 118969. doi: 10.1016/j.apenergy.2022.118969 URL
[24]	Hu Y Z, Gao J T, Li C X, Li C J. Thermally sprayed MCO/FeCr₂₄ interconnector with improved stability for tubular segmented-in-series SOFCs[J]. Appl. Surf. Sci., 2022, 587: 152861. doi: 10.1016/j.apsusc.2022.152861 URL
[25]	Peña-Álvarez M, del Corro E, Langa F, Baonzaa V G, Taravillo M. Morphological changes in carbon nanohorns under stress: a combined Raman spectroscopy and TEM study[J]. RSC Adv., 2016, 6: 49543-49550. doi: 10.1039/C5RA27162B URL
[26]	Tan K H, Rahman H A, Taib H. Coating layer and influence of transition metal for ferritic stainless steel interconnector solid oxide fuel cell: A review[J]. Int. J. Hydrog. Energy, 2016, 44(58): 30591-30605. doi: 10.1016/j.ijhydene.2019.06.155 URL
[27]	Xu Y J, Wang S R, Liu R Z, Wen T L, Wen Z Y. A novel bilayered Sr_0.6La_0.4TiO₃/La_0.8Sr_0.2MnO₃ interconnector for anode-supported tubular solid oxide fuel cell via slurry-brushing and co-sintering process[J]. J. Power Sources, 2011, 196(3): 1338-1341. doi: 10.1016/j.jpowsour.2010.07.088 URL
[28]	Horita T, Kishimoto H, Yamaji K, Xiong Y P, Sakai N, Brito M E, Yokokawa H. Oxide scale formation and stability of Fe-Cr alloy interconnects under dual atmospheres and current flow conditions for SOFCs[J]. J. Electrochem. Soc., 2006, 153: A2007.
[29]	Horita T, Kshimoto H, Yamaji K, Sakai N, Xiong Y P, Brito M E, Yokokawa H. Anomalous oxidation of ferritic interconnects in solid oxide fuel cells[J]. Int. J. Hydrog. Energy, 2008, 33(14): 3962-3969. doi: 10.1016/j.ijhydene.2007.07.058 URL
[30]	Zhao L, Zhang J, Becker T, Jiang S P. Raman spectroscopy study of chromium deposition on La_0.6Sr_0.4Co_0.2Fe_0.8O_3-_δ cathode of solid oxide fuel cells[J]. J. Electrochem. Soc., 2014, 161: F687. doi: 10.1149/2.018406jes URL
[31]	Li X X, Blinn K, Chen D C, Liu M L. In situ and surface-enhanced Raman spectroscopy study of electrode materials in solid oxide fuel cells[J]. Electrochem. Energy Rev., 2018, 1: 433-459. doi: 10.1007/s41918-018-0017-9
[32]	Church B C, Sanders T H, Speyer R F, Cochran J K. Thermal expansion matching and oxidation resistance of Fe-Ni-Cr interconnect alloys[J]. Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 2007, 452: 334-340.
[33]	Wu J W, Liu X B. Recent development of SOFC metallic interconnect[J]. J. Mater. Sci. Technol., 2010, 26(4): 293-305.
[34]	Tkachenko S, Brodnikovskyi D, Cizek J, Komarov P, Brodnikovskyi Y, Tymoshenko Y, Csáki Š, Pinchuk M, Vasylyev O, Čelko L, Gadzyra M, Chráska T. Novel Ti-Si-C composites for SOFC interconnect materials: Production optimization[J]. Ceram. Int., 2022, 48(19): 27785-27798. doi: 10.1016/j.ceramint.2022.06.081 URL

Composition	Material	Thickness
Supporting layer	NiO-3YSZ (3 mol.% yttria stabilized zirconia)	2.8 mm
Anode	NiO-8YSZ (8 mol.% yttria stabilized zirconia)	10 µm
Electrolyte	8YSZ (8 mol.% yttria stabilized zirconia)	10 µm 2 µm
Barrier layer	GDC (Gd_0.1Ce_0.9O_2-δ)	10 µm 2 µm
Cathode	LSCF (La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ) - GDC	15 µm
Buffer layer	LSC (La_{0. 6}Sr_{0. 4}CoO_3-_δ)	150 µm

Parameter	V_start (V)	V_end (V)	ΔV (mV)	η (mV·kh^-1)
Stack	1.753	1.632	-121	-40.85
Cell-1	0.860	0.870	10.0	3.47
Cell-2	0.906	0.918	11.2	3.82

Interconnect	1	2	3
V_start (V)	0.0094	0.0096	0.0690
V_end (V)	0.0830	0.0773	0.1384
ASR_start(Ω·cm²)	0.0353	0.0356	0.2588
ASR_end (Ω·cm²)	0.3114	0.2894	0.5188
ΔV (mV)	73.6	67.7	69.3
η₁ (mV·kh^-1)	24.81	22.82	23.14
η₂ (Ω·cm²·kh^-1)	0.276	0.254	0.249

以掺氢天然气为燃料直接内重整固体氧化物电池堆的稳定性

Stability of a Solid Oxide Cell Stack under Direct Internal-Reforming of Hydrogen-Blended Methane

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