球形Sn-SnSb合金纳米粒子制备及其储锂性能

doi:10.13208/j.electrochem.130402

电化学（中英文） ›› 2014, Vol. 20 ›› Issue (4): 360-364. doi: 10.13208/j.electrochem.130402

• 电化学近期研究专辑（厦门大学姜艳霞教授主编） • 上一篇下一篇

球形Sn-SnSb合金纳米粒子制备及其储锂性能

肖尧¹，吴娇红²，王琪¹，黄令^1*，李君涛²，孙世刚¹

1. 厦门大学化学化工学院化学系，福建厦门 361005；2. 厦门大学能源研究院，福建厦门 361005

收稿日期:2013-04-02 修回日期:2013-06-21 出版日期:2014-08-28 发布日期:2013-06-26
通讯作者: 黄令 E-mail:huangl@xmu.edu.cn
基金资助:
国家自然科学基金项目（No. 21273184）、科技部863计划项目（No. 2011AA11A254）和国家重点基础研究发展计划项目（No. 2009CB220102）项目资助

Preparation and Lithium Storage Performance of Sn-SnSb Nanoparticles

XIAO Yao¹, WU Jiao-hong², WANG Qi¹, HUANG Ling^1*, LI Jun-tao², SUN Shi-gang¹

1. Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005; 2. School of Energy Research, Xiamen University, Xiamen 361005

Received:2013-04-02 Revised:2013-06-21 Published:2014-08-28 Online:2013-06-26
Contact: HUANG Ling E-mail:huangl@xmu.edu.cn

摘要/Abstract

摘要： 锂离子电池Sn负极材料有较高的比容量，但其容量随周期循环急剧衰减. 若Sn与Sb形成SnSb合金可以改善其循环性能. 本文采用有机液相还原方法制备了球形Sn-SnSb合金纳米粒子，其首周期循环充电容量1235.9 mAh·g^-1，放电容量为785.9 mAh·g^-1，经过50周的循环之后其放电容量保持在409.2 mAh·g^-1，表现出较好的循环性能.

关键词: 球形Sn-SnSb纳米粒子, 锂离子电池, 负极

Abstract: Tin was widely studied as alternative anode material to carbon for lithium-ion batteries thanks to its much higher theoretical capacity. However, a pure tin electrode suffers severely from its poor cycleability due to mechanical fatigue caused by volume change during lithium insertion and extraction processes. Tin-based alloy may improve the cycleability property of tin electrode. In this article, we report facile synthesis of spherical Sn-SnSb nanopartciles using a simple solvent-thermal approach. It is amazing to find that the spherical Sn-SnSb nanoparticles can circumvent volume changes effectively during charge-discharge process. Electrochemical discharge/charge results show that the spherical Sn-SnSb nanoparticles electrode exhibits much better cycleability than pure Sn electrode, with first charge capacity and discharge capacity of 1235.9 and 785.9 mAh·g^-1, respectively. After 50th cycling, the discharge capacity is 409.2 mAh·g^-1.

Key words: spherical SnSb nanoparticles, lithium ion batteries, negative electrode

中图分类号:

TM912.9

肖尧，吴娇红，王琪，黄令*，李君涛，孙世刚. 球形Sn-SnSb合金纳米粒子制备及其储锂性能[J]. 电化学（中英文）, 2014, 20(4): 360-364.

XIAO Yao, WU Jiao-hong, WANG Qi, HUANG Ling*, LI Jun-tao, SUN Shi-gang. Preparation and Lithium Storage Performance of Sn-SnSb Nanoparticles[J]. Journal of Electrochemistry, 2014, 20(4): 360-364.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.130402

https://electrochem.xmu.edu.cn/CN/Y2014/V20/I4/360

参考文献

[1] Lee S H, Mathews M, Toghiani H, et al. Fabrication of carbon-encapsulated mono- and bimetallic (Sn and Sn/Sb alloy) nanorods-potential lithium-ion battery anode materials[J]. Chemistry of Materials, 2009, 21(11): 2306-2314.
[2] Guo H, Zhao H L, Jia X D, et al. Synthesis and electrochemical characteristics of Sn-Sb-Ni alloy composite anode for Li-ion rechargeable batteries[J]. Materials Research Bulletin, 2007, 42 (5): 836-843.
[3] Winter M, Besenhard J O. Electrochemical lithiation of tin and tin-based intermetallics and composites[J]. Electrochimica Acta, 1999, 45(1/2): 31-50.
[4] Yang J, Winter M, Besenhard J O. Small particle size multiphase Li-alloy anodes for lithium-ion batteries[J]. Solid State Ionics, 1996, 90(1/4): 281-287.
[5] Yoshinaga H, Kawabata A, Xia Y, et al. New V-Sn alloys prepared by powder metallurgy for lithium battery negative electrode[J]. Journal of the Japan Society of Powder and Powder Metallurgy, 2002 ,49(1): 37-43.
[6] Kim D G, Kim H, Sohn H J, et al. Nanosized Sn-Cu-B alloy anode prepared by chemical reduction for secondary lithium batteries[J]. Journal of Power Sources, 2002, 104(2): 221-225.
[7] Mao O, Dunlap R A, Dahn J R. Mechanically alloyed Sn‐Fe(‐C) powders as anode materials for Li‐ion batteries: I. The Sn2Fe?-C? system[J]. Journal of The Electrochemical Society, 1999, 146(2): 405-413.
[8] Mukaibo H, Momma T, Osaka T. Changes of electro-deposited Sn-Ni alloy thin film for lithium ion battery anodes during charge discharge cycling[J]. Journal of Power Sources, 2005, 146(1/2): 457-463.
[9] Zhao H L, Yin C L, Guo H, et al. Studies of the electrochemical performance of Sn-Sb alloy prepared by solid-state reduction[J]. Journal of Power Sources, 2007, 174(2): 916-920.
[10] Yang J, Takeda Y, Imanishi N, et al. Ultrafine Sn and SnSb0.14 powders for lithium storage matrices in lithium-ion batteries[J]. Journal of The Electrochemical Society, 1999, 146(11): 4009-4013.
[11] ]Wolfenstine J, Campos S, Foster D, et al. Nano-scale Cu6Sn5 anodes[J]. Journal of Power Sources, 2002, 109(1): 230-233.
[12] Mukaibo H, Osaka T, Reale P, et al. Optimized Sn/SnSb lithium storage materials[J]. Journal of Power Sources, 2004, 132(1/2): 225-228.
[13] Trifonova A, Wachtler M, Wagner M R, et al. Influence of the reductive preparation conditions on the morphology and on the electrochemical performance of Sn/SnSb[J]. Solid State Ionics, 2004, 168(1/2): 51-59.
[14] Wachtler M, Winter M, Besenhard J O. Anodic materials for rechargeable Li-batteries[J]. Journal of Power Sources, 2002, 105(2):151-160.
[15] Zhao H L, Zhu Z M, Yin C L, et al. Electrochemical characterization of micro-sized Sb/SnSb composite anode[J]. Materials Chemistry and Physics, 2008, 110(2/3): 201-205.
[16] Rom I, Wachtler M, Papst I, et al. Electron microscopical characterization of Sn/SnSb composite electrodes for lithium-ion batteries[J]. Solid State Ionics, 2001, 143(3/4): 329-336.
[17] Wang Z, Tian W H, Li X G. Synthesis and electrochemistry properties of Sn-Sb ultrafine particles as anode of lithium-ion batteries[J]. Journal of Alloys and Compounds, 2007, 439(1/2): 350-354.
[18] Huang K L (黄可龙), Zhang G (张戈), Liu S Q (刘素琴), et al. Synthesis and eletrochemical performance of Sn-SnSb/graphite composite materials[J]. Chinese Journal of Inorganic Chemistry (无机化学学报), 2006, 22(11): 2076-2079.

球形Sn-SnSb合金纳米粒子制备及其储锂性能

Preparation and Lithium Storage Performance of Sn-SnSb Nanoparticles

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