前驱体对三元正极材料LiNi0.5Co0.2Mn0.3O2性能的影响

doi:10.61558/2993-074X.2950

电化学（中英文） ›› 2013, Vol. 19 ›› Issue (3): 204-209. doi: 10.61558/2993-074X.2950

• 锂离子和燃料电池近期研究专辑（厦门大学董全峰教授主编） • 上一篇下一篇

前驱体对三元正极材料LiNi_0.5Co_0.2Mn_0.3O₂性能的影响

HU Dong-ge¹, WANG Zhang-zhi¹, LIU Jia-li², HUANG Tao², YU Ai-shui^2*

1. Hangzhou Golden Horse Energy Tecnology Co., Ltd., Hangzhou 311215, China; 2. Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University, Shanghai 200433, China

收稿日期:2012-10-12 修回日期:2012-12-25 出版日期:2013-06-28 发布日期:2012-12-30

The Effect of Precursors on Performance of LiNi_0.5Co_0.2Mn_0.3O₂ Cathode Material

1. 杭州金马能源科技有限公司，浙江杭州 311215；2. 复旦大学上海市分子催化和功能材料重点实验室，复旦大学化学系，新能源研究院，上海 200433

1. Hangzhou Golden Horse Energy Tecnology Co., Ltd., Hangzhou 311215, China; 2. Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University, Shanghai 200433, China

Received:2012-10-12 Revised:2012-12-25 Published:2013-06-28 Online:2012-12-30

摘要/Abstract

摘要： 目前，工业产品的三元正极材料LiNi_0.5Co_0.2Mn_0.3O₂通常使用间接共沉淀和高温固相烧结相结合的方法. 共沉淀制得的氢氧化镍钴锰前驱体，其形貌和粒径分布等直接影响着三元材料LiNi_0.5Co_0.2Mn_0.3O₂的性能. 使用X射线衍射（XRD）、扫描电镜（SEM）表征和观察材料晶体结构和表面形貌，并测试粒径分布、振实密度和电化学性能，考察三种前驱体对制得的三元材料的影响. 研究结果表明，前驱体的粒径分布直接影响材料的物理性能，表面有大量微孔而又致密的球形是较理想的前驱体形貌；焙烧后可得到结晶度高的材料，0.2C全电池放电比容量达到156.4 mAh·g^-1，循环寿命优异，300周期循环其容量基本不衰减，500周期循环后容量保持率高达92%.

关键词:

锂离子电池, 正极材料, LiNi_0.5Co_0.2Mn_0.3O₂, 前驱体

Abstract: Commercial LiNi_0.5Co_0.2Mn_0.3O₂ material is generally prepared by a combination of co-precipitation and solid state reaction method. The particle size distribution and morphology of Ni_0.5Co_0.2Mn_0.3(OH)₂ precursor have a great impact on the electrochemical performance of LiNi_0.5Co_0.2Mn_0.3O₂. In this work, the crystal structure and surface morphology of LiNi_0.5Co_0.2Mn_0.3O₂ prepared by three different precursors were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Particle size distribution, tap density and electrochemical performance were investigated. The results show that the particle size distribution of every precursor has most direct impact on properties of the corresponding LiNi_0.5Co_0.2Mn_0.3O₂. The precursor with micropores on surface results in the best electrochemical performance. The discharge capacity for full cell test was 156.4 mAh·g^-1 (0.2C), meanwhile, the cycling performance is excellent. The capacity fading was limited in the first 300 cycles with up to 92% capacity retention after 500 cycles.

Key words:

lithium ion battery, cathode material, LiNi_0.5Co_0.2Mn_0.3O₂, precursor

中图分类号:

O646

胡东阁, 王张志, 刘佳丽, 黄桃, 余爱水. 前驱体对三元正极材料LiNi_0.5Co_0.2Mn_0.3O₂性能的影响[J]. 电化学（中英文）, 2013, 19(3): 204-209.

HU Dong-Ge, WANG Zhang-Zhi, LIU Jia-Li, HUANG Tao, YU Ai-Shui. The Effect of Precursors on Performance of LiNi_0.5Co_0.2Mn_0.3O₂ Cathode Material[J]. Journal of Electrochemistry, 2013, 19(3): 204-209.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.61558/2993-074X.2950

https://electrochem.xmu.edu.cn/CN/Y2013/V19/I3/204

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前驱体对三元正极材料LiNi_0.5Co_0.2Mn_0.3O₂性能的影响

The Effect of Precursors on Performance of LiNi_0.5Co_0.2Mn_0.3O₂ Cathode Material

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