银在质子交换膜燃料电池空气阴极内促进氧传递研究

电化学（中英文） ›› 2006, Vol. 12 ›› Issue (4): 434-438.

银在质子交换膜燃料电池空气阴极内促进氧传递研究

徐洪峰;董建华;侯向理;

大连交通大学环境与化学工程学院,大连交通大学环境与化学工程学院,大连交通大学环境与化学工程学院辽宁大连116028,辽宁大连116028,辽宁大连116028

收稿日期:2006-11-28 修回日期:2006-11-28 出版日期:2006-11-28 发布日期:2006-11-28

Facilitated Effect of Ag to Oxygen Transportation in PEM Fuel Cell Air Cathodes

XU Hong-feng~*,DONG Jian-hua,HOU Xiang-li

(Dept.of Environmental& Chemical Eng.,Dalian Jiaotong University,Dalian 116028,Liaoning,China

Received:2006-11-28 Revised:2006-11-28 Published:2006-11-28 Online:2006-11-28

摘要/Abstract

摘要： 利用离子交换及随后的氢还原,将单质银负载在质子交换膜(Nafion)孔道内.TEM、XRD表征载银Nafion膜的结构,电化学极限电流法测定氧在载银Nafion膜内的扩散系数.结果表明,因银晶颗粒大于Nafion孔道直径,致使Nafion孔道有所扩张;氧在载银Nafion膜内的扩散系数是无银Nafion膜的4倍.据此,把银引入质子交换膜燃料电池空气阴极催化剂表面的Nafion薄层,则电池的性能在高电流密度下有明显的提高,显示了银对该电极内氧传递的促进作用.

关键词: 质子交换膜, 燃料电池, 银, 促进传递

Abstract: Silver(Ag) was deposited in the pores of Nafion membrane by ion exchange and succedent hydrogen reduction;the structures of Nafion-Ag membrane were measured by TEM and XRD,the diffusion coefficients of oxygen in Nafion-Ag was determined by electrochemical limited current method.The results showed that after deposited silver,the pores in the Nafion were enlarged by silver grains;the oxygen diffusion coefficient was increased about four times.By introducing silver in the thin Nafion film around the cathode catalyst,the performance of PEM fuel cell have a evident increasing in high current density, which shows the facilitated effects of silver to oxygen transportation in PEM fuel cell.

Key words: Proton exchange membrane, Fuel cell, Silver, Facilitated transportation

中图分类号:

TM911.4

徐洪峰;董建华;侯向理;. 银在质子交换膜燃料电池空气阴极内促进氧传递研究[J]. 电化学（中英文）, 2006, 12(4): 434-438.

XU Hong-feng~*,DONG Jian-hua,HOU Xiang-li. Facilitated Effect of Ag to Oxygen Transportation in PEM Fuel Cell Air Cathodes[J]. Journal of Electrochemistry, 2006, 12(4): 434-438.

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链接本文: https://electrochem.xmu.edu.cn/CN/

https://electrochem.xmu.edu.cn/CN/Y2006/V12/I4/434

参考文献

[1]Song G M,Cha S Y,LeeW M.Optim al composition ofpolym er electrolyte fuel cell electrodes determ ined bythe AC impedance m ethdod[J].J.Power Sources,2001,94:78~84. [2]Xu Hongfeng(徐洪峰),L in Zh iyin(林治银),Q iu Yan-ling(邱艳玲),et al.Pt/C electrocatalyst for proton ex-change m embrane fuel cell[J].Ch inese Journal of catal-ysis(in Ch inese),2003,24(2):143~148. [3]XU Z Q,Q i Z G,Kaufm an A.E ffect of oxygen storagem aterial on the perform ance of proton exchange m em-brane fuel cell[J].J.Power Sources,2003,115:40~47. [4]Yu H B,K im J H,Lee H I,et al.Developm ent ofnanophase CeO2-Pt/C cathode catalyst for d irectm etha-nol fuel cell[J].J.Power Sources,2005,140:59~65. [5]Hou X iangli(侯向理),Xu Hongfeng(徐洪峰),DongJianhua(董建华),et al.Oxygen enrichm ent effect ofCeO2to the cathode perform ance of proton exchangem embrane fuel cell[J].E lectrochem istry(in Ch inese),2006,12(1):89~92. [6]Outlaw R A,Sankaran S N,Hofund G B,et al.Oxygentransport through h igh purity large grain Ag[J].J.M a-terial Research,1988,3(6):1378~83. [7]Sungpet A,W ay J D,Koval C A,et al.S ilver dopedNafion-poly(pyrrole)m embranes for fac ilitated perm e-ation of liqu id-phase olefins[J].Journal of M embraneSc ience,2001,189(2):271~79. [8]Sakai T,Takenaka H,Torikai E.Oxygen/n itrogen sep-aration by a nafion-Ag m icrocomposite m embrane[J].Journal ofM embrane Sc ience,1987,31:227~232. [9]Gode P,L indbergh G,Sundholm G.In-situ m easure-m ents of gas perm eab ility in fuel cellm embranes using acylindrical m icroelectrode[J].Journal of E lectroanaly-tical Chem istry,2002,518(4):115~122. [10]Mo Zh ishen(莫志深),Zhang Hongfang(张宏放).Structure of Crystalline Polym ers by X-ray D iffraction(B)[M].Be ijing:Sc ience Press,2003.186~187. [11]W ang Shaoting(王绍亭),Chen Tao(陈涛).Funda-m ental of Chem ical Transport Process(B)[M].Be i-jing:Chem ical Industry Press,1998:207~208.

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