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电化学(中英文) ›› 2002, Vol. 8 ›› Issue (4): 460-462. 

• 研究论文 • 上一篇    下一篇

提高AB_5型贮氢电极合金低温电化学性能研究

叶辉,吴铸,李志林,张宏   

  1. 中国科学院上海冶金研究所能源室,中国科学院上海冶金研究所能源室,中国科学院上海冶金研究所能源室,中国科学院上海冶金研究所能源室 上海200050 ,上海200050 ,上海200050 ,上海200050
  • 收稿日期:2002-11-28 修回日期:2002-11-28 出版日期:2002-11-28 发布日期:2002-11-28

Improvement of the Low Temperature Electrochemical Performance of AB_5-type Hydrogen Storage Alloy

YE Hui *,WU Zhu,LI Zhi-lin,ZHANG Hong   

  1. (Shanghai Institute of Metallurgy,CAS,SHanghai 200050, China
  • Received:2002-11-28 Revised:2002-11-28 Published:2002-11-28 Online:2002-11-28

摘要: 采用优化稀土成分并添加适量的硼改善AB5型贮氢合金的低温性能 .实验表明 ,含富Ce稀土及添加适量硼的AB5型合金 ,其低温电化学性能优良 ,能满足Ni/MH电池在低至 - 35℃小倍率电流密度放电的要求 .贮氢合金低温性能的改善与合金的微结构、热力学和动力学性能相一致

关键词: 贮氢合金, 电化学性能

Abstract: Optimizing the rare earth composition and doping with boron have been used to improve the low temperature performance of AB 5 hydrogen storage alloy.The results show that Ce-rich alloy with a proper amount of boron is suitable for Ni/MH battery with the lower-limit temperature down to 238 K under smaller current density (120 mA/g). The improvement of low temperature performance of hydrogen storage alloy is well consistent with its microstructure,thermodynamic and kinetic properties.

Key words: Hydrogen storage alloy, Electrochemical performances, Low temperature properties

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